Methyl 3′-(2,5-dimethylbenzyl)-1′-methyl-2-oxo-4′-phenylspiro[indoline-3,2′-pyrrolidine]-3′-carboxylate chloroform monosolvate
In the title solvate, C29H30N2O3·CHCl3, the dihedral angle between the indole ring system (r.m.s. deviation = 0.050 Å) and the 4-methylpyrrolidine ring is 88.88 (8)°. The latter ring adopts an envelope conformation with the N atom as the flap. Its mean plane makes dihedral angles of 86.94 (11) and 4...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814004073 |
| _version_ | 1828142804368359424 |
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| author | S. Karthikeyan P. Narayanan K. Sethusankar Anthonisamy Devaraj Manickam Bakthadoss |
| author_facet | S. Karthikeyan P. Narayanan K. Sethusankar Anthonisamy Devaraj Manickam Bakthadoss |
| author_sort | S. Karthikeyan |
| collection | DOAJ |
| description | In the title solvate, C29H30N2O3·CHCl3, the dihedral angle between the indole ring system (r.m.s. deviation = 0.050 Å) and the 4-methylpyrrolidine ring is 88.88 (8)°. The latter ring adopts an envelope conformation with the N atom as the flap. Its mean plane makes dihedral angles of 86.94 (11) and 42.08 (9)° with the phenyl and dimethylbenzene rings, respectively. The molecular conformation is stabilized by intramolecular C—H...O hydrogen bonds, which generate S(6) and S(9) ring motifs. The chloroform solvent molecule is linked to the organic molecule by a C—H...O hydrogen bond involving the carbonyl O atom of the carboxylate group. In the crystal, molecules are linked via bifurcated N—H...(N,O) and C—H...O hydrogen bonds, forming chains propagating along [001]. |
| first_indexed | 2024-04-11T19:47:27Z |
| format | Article |
| id | doaj.art-c0a7bd54c48a47d99a437cd631d844c3 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T19:47:27Z |
| publishDate | 2014-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c0a7bd54c48a47d99a437cd631d844c32022-12-22T04:06:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-03-01703o377o37810.1107/S1600536814004073su2703Methyl 3′-(2,5-dimethylbenzyl)-1′-methyl-2-oxo-4′-phenylspiro[indoline-3,2′-pyrrolidine]-3′-carboxylate chloroform monosolvateS. Karthikeyan0P. Narayanan1K. Sethusankar2Anthonisamy Devaraj3Manickam Bakthadoss4Department of Physics, RKM Vivekananda College (Autonomous), Chennai 600 004, IndiaDepartment of Physics, RKM Vivekananda College (Autonomous), Chennai 600 004, IndiaDepartment of Physics, RKM Vivekananda College (Autonomous), Chennai 600 004, IndiaDepartment of Organic Chemistry, University of Madras, Maraimalai Campus, Chennai 600 025, IndiaDepartment of Organic Chemistry, University of Madras, Maraimalai Campus, Chennai 600 025, IndiaIn the title solvate, C29H30N2O3·CHCl3, the dihedral angle between the indole ring system (r.m.s. deviation = 0.050 Å) and the 4-methylpyrrolidine ring is 88.88 (8)°. The latter ring adopts an envelope conformation with the N atom as the flap. Its mean plane makes dihedral angles of 86.94 (11) and 42.08 (9)° with the phenyl and dimethylbenzene rings, respectively. The molecular conformation is stabilized by intramolecular C—H...O hydrogen bonds, which generate S(6) and S(9) ring motifs. The chloroform solvent molecule is linked to the organic molecule by a C—H...O hydrogen bond involving the carbonyl O atom of the carboxylate group. In the crystal, molecules are linked via bifurcated N—H...(N,O) and C—H...O hydrogen bonds, forming chains propagating along [001].http://scripts.iucr.org/cgi-bin/paper?S1600536814004073 |
| spellingShingle | S. Karthikeyan P. Narayanan K. Sethusankar Anthonisamy Devaraj Manickam Bakthadoss Methyl 3′-(2,5-dimethylbenzyl)-1′-methyl-2-oxo-4′-phenylspiro[indoline-3,2′-pyrrolidine]-3′-carboxylate chloroform monosolvate Acta Crystallographica Section E |
| title | Methyl 3′-(2,5-dimethylbenzyl)-1′-methyl-2-oxo-4′-phenylspiro[indoline-3,2′-pyrrolidine]-3′-carboxylate chloroform monosolvate |
| title_full | Methyl 3′-(2,5-dimethylbenzyl)-1′-methyl-2-oxo-4′-phenylspiro[indoline-3,2′-pyrrolidine]-3′-carboxylate chloroform monosolvate |
| title_fullStr | Methyl 3′-(2,5-dimethylbenzyl)-1′-methyl-2-oxo-4′-phenylspiro[indoline-3,2′-pyrrolidine]-3′-carboxylate chloroform monosolvate |
| title_full_unstemmed | Methyl 3′-(2,5-dimethylbenzyl)-1′-methyl-2-oxo-4′-phenylspiro[indoline-3,2′-pyrrolidine]-3′-carboxylate chloroform monosolvate |
| title_short | Methyl 3′-(2,5-dimethylbenzyl)-1′-methyl-2-oxo-4′-phenylspiro[indoline-3,2′-pyrrolidine]-3′-carboxylate chloroform monosolvate |
| title_sort | methyl 3 2 5 dimethylbenzyl 1 methyl 2 oxo 4 phenylspiro indoline 3 2 pyrrolidine 3 carboxylate chloroform monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814004073 |
| work_keys_str_mv | AT skarthikeyan methyl325dimethylbenzyl1methyl2oxo4phenylspiroindoline32pyrrolidine3carboxylatechloroformmonosolvate AT pnarayanan methyl325dimethylbenzyl1methyl2oxo4phenylspiroindoline32pyrrolidine3carboxylatechloroformmonosolvate AT ksethusankar methyl325dimethylbenzyl1methyl2oxo4phenylspiroindoline32pyrrolidine3carboxylatechloroformmonosolvate AT anthonisamydevaraj methyl325dimethylbenzyl1methyl2oxo4phenylspiroindoline32pyrrolidine3carboxylatechloroformmonosolvate AT manickambakthadoss methyl325dimethylbenzyl1methyl2oxo4phenylspiroindoline32pyrrolidine3carboxylatechloroformmonosolvate |