Aquacarbonyl(ferrocenyldithiophosphonato-κ2S,S′)bis(triphenylphosphane-κP)ruthenium(II) dichloromethane monosolvate
The structure of the title complex, [FeRu(C5H5)(C5H4OPS2)(CO)(C18H15P)2(H2O)]·CH2Cl2, consists of one neutral [{FcP(O)S2}Ru(CO)(H2O)(PPh3)2] complex [Fc = Fe(η5-C5H4)(η5-C5H5)] and one CH2Cl2 solvent molecule. The geometry around the RuII atom is pseudo-octahedral, with tw...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813014311 |
| _version_ | 1818958178315927552 |
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| author | Hang Zhu Qing Ma Hua-Tian Shi Qun Chen Qian-Feng Zhang |
| author_facet | Hang Zhu Qing Ma Hua-Tian Shi Qun Chen Qian-Feng Zhang |
| author_sort | Hang Zhu |
| collection | DOAJ |
| description | The structure of the title complex, [FeRu(C5H5)(C5H4OPS2)(CO)(C18H15P)2(H2O)]·CH2Cl2, consists of one neutral [{FcP(O)S2}Ru(CO)(H2O)(PPh3)2] complex [Fc = Fe(η5-C5H4)(η5-C5H5)] and one CH2Cl2 solvent molecule. The geometry around the RuII atom is pseudo-octahedral, with two cis-binding PPh3 ligands and one chelating bidentate [Fc(O)PS2]2− ligand via two S atoms. The average Ru—S and Ru—P bond lengths are 2.434 (1) and 2.398 (1) Å, and the Ru—O and Ru—C bond lengths are 2.157 (3) and 1.826 (4) Å, respectively. In the crystal, pairs of O—H...O hydrogen bonds link adjacent molecules into dimers. |
| first_indexed | 2024-12-20T11:21:37Z |
| format | Article |
| id | doaj.art-c0b671920c894576839fd9e6487b9441 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:21:37Z |
| publishDate | 2013-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c0b671920c894576839fd9e6487b94412022-12-21T19:42:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-06-01696m343m34310.1107/S1600536813014311Aquacarbonyl(ferrocenyldithiophosphonato-κ2S,S′)bis(triphenylphosphane-κP)ruthenium(II) dichloromethane monosolvateHang ZhuQing MaHua-Tian ShiQun ChenQian-Feng ZhangThe structure of the title complex, [FeRu(C5H5)(C5H4OPS2)(CO)(C18H15P)2(H2O)]·CH2Cl2, consists of one neutral [{FcP(O)S2}Ru(CO)(H2O)(PPh3)2] complex [Fc = Fe(η5-C5H4)(η5-C5H5)] and one CH2Cl2 solvent molecule. The geometry around the RuII atom is pseudo-octahedral, with two cis-binding PPh3 ligands and one chelating bidentate [Fc(O)PS2]2− ligand via two S atoms. The average Ru—S and Ru—P bond lengths are 2.434 (1) and 2.398 (1) Å, and the Ru—O and Ru—C bond lengths are 2.157 (3) and 1.826 (4) Å, respectively. In the crystal, pairs of O—H...O hydrogen bonds link adjacent molecules into dimers.http://scripts.iucr.org/cgi-bin/paper?S1600536813014311 |
| spellingShingle | Hang Zhu Qing Ma Hua-Tian Shi Qun Chen Qian-Feng Zhang Aquacarbonyl(ferrocenyldithiophosphonato-κ2S,S′)bis(triphenylphosphane-κP)ruthenium(II) dichloromethane monosolvate Acta Crystallographica Section E |
| title | Aquacarbonyl(ferrocenyldithiophosphonato-κ2S,S′)bis(triphenylphosphane-κP)ruthenium(II) dichloromethane monosolvate |
| title_full | Aquacarbonyl(ferrocenyldithiophosphonato-κ2S,S′)bis(triphenylphosphane-κP)ruthenium(II) dichloromethane monosolvate |
| title_fullStr | Aquacarbonyl(ferrocenyldithiophosphonato-κ2S,S′)bis(triphenylphosphane-κP)ruthenium(II) dichloromethane monosolvate |
| title_full_unstemmed | Aquacarbonyl(ferrocenyldithiophosphonato-κ2S,S′)bis(triphenylphosphane-κP)ruthenium(II) dichloromethane monosolvate |
| title_short | Aquacarbonyl(ferrocenyldithiophosphonato-κ2S,S′)bis(triphenylphosphane-κP)ruthenium(II) dichloromethane monosolvate |
| title_sort | aquacarbonyl ferrocenyldithiophosphonato 954 2s s 8242 bis triphenylphosphane 954 p ruthenium ii dichloromethane monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813014311 |
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