Synthesis and Properties of Water-Soluble Blue-Emitting Mn-Alloyed CdTe Quantum Dots
Abstract In this work, we prepared CdTe quantum dots, and series of Cd1-xMnxTe-alloyed quantum dots with narrow size distribution by an ion-exchange reaction in water solution. We found that the photoluminescence peaks are shifted to higher energies with the increasing Mn2+ content. So far, this is...
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Format: | Article |
Language: | English |
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SpringerOpen
2018-05-01
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Series: | Nanoscale Research Letters |
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Online Access: | http://link.springer.com/article/10.1186/s11671-018-2529-y |
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author | Olena Tynkevych Volodymyr Karavan Igor Vorona Svitlana Filonenko Yuriy Khalavka |
author_facet | Olena Tynkevych Volodymyr Karavan Igor Vorona Svitlana Filonenko Yuriy Khalavka |
author_sort | Olena Tynkevych |
collection | DOAJ |
description | Abstract In this work, we prepared CdTe quantum dots, and series of Cd1-xMnxTe-alloyed quantum dots with narrow size distribution by an ion-exchange reaction in water solution. We found that the photoluminescence peaks are shifted to higher energies with the increasing Mn2+ content. So far, this is the first report of blue-emitting CdTe-based quantum dots. By means of cyclic voltammetry, we detected features of electrochemical activity of manganese energy levels formed inside the Cd1-xMnxTe-alloyed quantum dot band gap. This allowed us to estimate their energy position. We also demonstrate paramagnetic behavior for Cd1-xMnxTe-alloyed quantum dots which confirmed the successful ion-exchange reaction. |
first_indexed | 2024-03-12T10:53:49Z |
format | Article |
id | doaj.art-c0d4ed2e5295461297ce95f24f0439ec |
institution | Directory Open Access Journal |
issn | 1931-7573 1556-276X |
language | English |
last_indexed | 2024-03-12T10:53:49Z |
publishDate | 2018-05-01 |
publisher | SpringerOpen |
record_format | Article |
series | Nanoscale Research Letters |
spelling | doaj.art-c0d4ed2e5295461297ce95f24f0439ec2023-09-02T06:37:57ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2018-05-011311610.1186/s11671-018-2529-ySynthesis and Properties of Water-Soluble Blue-Emitting Mn-Alloyed CdTe Quantum DotsOlena Tynkevych0Volodymyr Karavan1Igor Vorona2Svitlana Filonenko3Yuriy Khalavka4Yuriy Fedkovych Chernivtsi National UniversityThe Scientific Center of Preventive Toxicology, Food and Chemical SafetyV. Lashkaryov Institute of Semiconductor Physics of National Academy of Sciences of UkraineL. V. Pisarzhevskii Institute of Physical Chemistry of National Academy of Sciences of UkraineYuriy Fedkovych Chernivtsi National UniversityAbstract In this work, we prepared CdTe quantum dots, and series of Cd1-xMnxTe-alloyed quantum dots with narrow size distribution by an ion-exchange reaction in water solution. We found that the photoluminescence peaks are shifted to higher energies with the increasing Mn2+ content. So far, this is the first report of blue-emitting CdTe-based quantum dots. By means of cyclic voltammetry, we detected features of electrochemical activity of manganese energy levels formed inside the Cd1-xMnxTe-alloyed quantum dot band gap. This allowed us to estimate their energy position. We also demonstrate paramagnetic behavior for Cd1-xMnxTe-alloyed quantum dots which confirmed the successful ion-exchange reaction.http://link.springer.com/article/10.1186/s11671-018-2529-yQuantum dotsCadmium tellurideManganeseAlloyingThioglycolic acid |
spellingShingle | Olena Tynkevych Volodymyr Karavan Igor Vorona Svitlana Filonenko Yuriy Khalavka Synthesis and Properties of Water-Soluble Blue-Emitting Mn-Alloyed CdTe Quantum Dots Nanoscale Research Letters Quantum dots Cadmium telluride Manganese Alloying Thioglycolic acid |
title | Synthesis and Properties of Water-Soluble Blue-Emitting Mn-Alloyed CdTe Quantum Dots |
title_full | Synthesis and Properties of Water-Soluble Blue-Emitting Mn-Alloyed CdTe Quantum Dots |
title_fullStr | Synthesis and Properties of Water-Soluble Blue-Emitting Mn-Alloyed CdTe Quantum Dots |
title_full_unstemmed | Synthesis and Properties of Water-Soluble Blue-Emitting Mn-Alloyed CdTe Quantum Dots |
title_short | Synthesis and Properties of Water-Soluble Blue-Emitting Mn-Alloyed CdTe Quantum Dots |
title_sort | synthesis and properties of water soluble blue emitting mn alloyed cdte quantum dots |
topic | Quantum dots Cadmium telluride Manganese Alloying Thioglycolic acid |
url | http://link.springer.com/article/10.1186/s11671-018-2529-y |
work_keys_str_mv | AT olenatynkevych synthesisandpropertiesofwatersolubleblueemittingmnalloyedcdtequantumdots AT volodymyrkaravan synthesisandpropertiesofwatersolubleblueemittingmnalloyedcdtequantumdots AT igorvorona synthesisandpropertiesofwatersolubleblueemittingmnalloyedcdtequantumdots AT svitlanafilonenko synthesisandpropertiesofwatersolubleblueemittingmnalloyedcdtequantumdots AT yuriykhalavka synthesisandpropertiesofwatersolubleblueemittingmnalloyedcdtequantumdots |