The Phase and Morphology of CuInSe2 Film Prepared by One-Step electrodeposition

<p>CuInSe<sub>2</sub> with chalcopyrite structure has become one of the most promising photoelectric materials for its high optical absorption coefficient and conversion efficiency. Electrodeposition has the advantages of low cost and easy operation. CuInSe<sub>2</sub>...

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Main Authors: Kegao LIU, Chao XU, Hong LIU, Yong HU, Ludan SHI
Format: Article
Language:English
Published: Kaunas University of Technology 2017-11-01
Series:Medžiagotyra
Subjects:
Online Access:http://matsc.ktu.lt/index.php/MatSc/article/view/17447
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author Kegao LIU
Chao XU
Hong LIU
Yong HU
Ludan SHI
author_facet Kegao LIU
Chao XU
Hong LIU
Yong HU
Ludan SHI
author_sort Kegao LIU
collection DOAJ
description <p>CuInSe<sub>2</sub> with chalcopyrite structure has become one of the most promising photoelectric materials for its high optical absorption coefficient and conversion efficiency. Electrodeposition has the advantages of low cost and easy operation. CuInSe<sub>2</sub> thin films were prepared by one-step electrodeposition with CuC1<sub>2</sub>·2H<sub>2</sub>O, InC1<sub>3</sub>, SeO<sub>2</sub> as raw materials. Cyclic voltammetry curves of the solutions were tested by electrochemical workstation. The phases of product thin films were analyzed by X-ray diffraction (XRD) and the surface morphology was characterized by scanning electron microscope (SEM). Experimental results show that the continuous, uniform and dense CuInSe<sub>2</sub> thin films can be obtained under conditions of deposition potential -0.5 V and sodium citrate as complexing agent with concentration of 5mmol/L. The XRD diffraction peaks of CuInSe<sub>2</sub> thin film are corresponding to the crystal planes of (112), (220) and (312) respectively.</p><p>DOI: <a href="http://dx.doi.org/10.5755/j01.ms.23.4.17447">http://dx.doi.org/10.5755/j01.ms.23.4.17447</a></p>
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spelling doaj.art-c0d55e3ade3a4f4499e73a77a6636e6e2022-12-22T00:16:03ZengKaunas University of TechnologyMedžiagotyra1392-13202029-72892017-11-0123431331610.5755/j01.ms.23.4.174478731The Phase and Morphology of CuInSe2 Film Prepared by One-Step electrodepositionKegao LIU0Chao XUHong LIUYong HULudan SHIShandong Jianzhu University<p>CuInSe<sub>2</sub> with chalcopyrite structure has become one of the most promising photoelectric materials for its high optical absorption coefficient and conversion efficiency. Electrodeposition has the advantages of low cost and easy operation. CuInSe<sub>2</sub> thin films were prepared by one-step electrodeposition with CuC1<sub>2</sub>·2H<sub>2</sub>O, InC1<sub>3</sub>, SeO<sub>2</sub> as raw materials. Cyclic voltammetry curves of the solutions were tested by electrochemical workstation. The phases of product thin films were analyzed by X-ray diffraction (XRD) and the surface morphology was characterized by scanning electron microscope (SEM). Experimental results show that the continuous, uniform and dense CuInSe<sub>2</sub> thin films can be obtained under conditions of deposition potential -0.5 V and sodium citrate as complexing agent with concentration of 5mmol/L. The XRD diffraction peaks of CuInSe<sub>2</sub> thin film are corresponding to the crystal planes of (112), (220) and (312) respectively.</p><p>DOI: <a href="http://dx.doi.org/10.5755/j01.ms.23.4.17447">http://dx.doi.org/10.5755/j01.ms.23.4.17447</a></p>http://matsc.ktu.lt/index.php/MatSc/article/view/17447CuInSe2thin filmphotoelectricone-step electrodeposition
spellingShingle Kegao LIU
Chao XU
Hong LIU
Yong HU
Ludan SHI
The Phase and Morphology of CuInSe2 Film Prepared by One-Step electrodeposition
Medžiagotyra
CuInSe2
thin film
photoelectric
one-step electrodeposition
title The Phase and Morphology of CuInSe2 Film Prepared by One-Step electrodeposition
title_full The Phase and Morphology of CuInSe2 Film Prepared by One-Step electrodeposition
title_fullStr The Phase and Morphology of CuInSe2 Film Prepared by One-Step electrodeposition
title_full_unstemmed The Phase and Morphology of CuInSe2 Film Prepared by One-Step electrodeposition
title_short The Phase and Morphology of CuInSe2 Film Prepared by One-Step electrodeposition
title_sort phase and morphology of cuinse2 film prepared by one step electrodeposition
topic CuInSe2
thin film
photoelectric
one-step electrodeposition
url http://matsc.ktu.lt/index.php/MatSc/article/view/17447
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