Spontaneous Ignition of Cryo-Compressed Hydrogen in a T-Shaped Channel System

Sudden releases of pressurised hydrogen may spontaneously ignite by the so-called “diffusion ignition” mechanism. Several experimental and numerical studies have been performed on spontaneous ignition for compressed hydrogen at ambient temperature. However, there is no knowledge of the phenomenon fo...

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Main Authors: Donatella Cirrone, Dmitriy Makarov, Vladimir Molkov
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Hydrogen
Subjects:
Online Access:https://www.mdpi.com/2673-4141/3/3/21
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author Donatella Cirrone
Dmitriy Makarov
Vladimir Molkov
author_facet Donatella Cirrone
Dmitriy Makarov
Vladimir Molkov
author_sort Donatella Cirrone
collection DOAJ
description Sudden releases of pressurised hydrogen may spontaneously ignite by the so-called “diffusion ignition” mechanism. Several experimental and numerical studies have been performed on spontaneous ignition for compressed hydrogen at ambient temperature. However, there is no knowledge of the phenomenon for compressed hydrogen at cryogenic temperatures. The study aims to close this knowledge gap by performing numerical experiments using a computational fluid dynamics model, validated previously against experiments at atmospheric temperatures, to assess the effect of temperature decrease from ambient 300 K to cryogenic 80 K. The ignition dynamics is analysed for a T-shaped channel system. The cryo-compressed hydrogen is initially separated from the air in the T-shaped channel system by a burst disk (diaphragm). The inertia of the burst disk is accounted for in the simulations. The numerical experiments were carried out to determine the hydrogen storage pressure limit leading to spontaneous ignition in the configuration under investigation. It is found that the pressure limit for spontaneous ignition of the cryo-compressed hydrogen at temperature 80 K is 9.4 MPa. This is more than 3 times larger than pressure limit for spontaneous ignition of 2.9 MPa in the same setup at ambient temperature of 300 K.
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spelling doaj.art-c0e3ec86f23e4933b0519aba5180b0d62023-11-23T16:34:49ZengMDPI AGHydrogen2673-41412022-08-013334836010.3390/hydrogen3030021Spontaneous Ignition of Cryo-Compressed Hydrogen in a T-Shaped Channel SystemDonatella Cirrone0Dmitriy Makarov1Vladimir Molkov2Hydrogen Safety Engineering and Research Centre (HySAFER), Ulster University, Shore Road, Newtownabbey BT37 0QB, UKHydrogen Safety Engineering and Research Centre (HySAFER), Ulster University, Shore Road, Newtownabbey BT37 0QB, UKHydrogen Safety Engineering and Research Centre (HySAFER), Ulster University, Shore Road, Newtownabbey BT37 0QB, UKSudden releases of pressurised hydrogen may spontaneously ignite by the so-called “diffusion ignition” mechanism. Several experimental and numerical studies have been performed on spontaneous ignition for compressed hydrogen at ambient temperature. However, there is no knowledge of the phenomenon for compressed hydrogen at cryogenic temperatures. The study aims to close this knowledge gap by performing numerical experiments using a computational fluid dynamics model, validated previously against experiments at atmospheric temperatures, to assess the effect of temperature decrease from ambient 300 K to cryogenic 80 K. The ignition dynamics is analysed for a T-shaped channel system. The cryo-compressed hydrogen is initially separated from the air in the T-shaped channel system by a burst disk (diaphragm). The inertia of the burst disk is accounted for in the simulations. The numerical experiments were carried out to determine the hydrogen storage pressure limit leading to spontaneous ignition in the configuration under investigation. It is found that the pressure limit for spontaneous ignition of the cryo-compressed hydrogen at temperature 80 K is 9.4 MPa. This is more than 3 times larger than pressure limit for spontaneous ignition of 2.9 MPa in the same setup at ambient temperature of 300 K.https://www.mdpi.com/2673-4141/3/3/21diffusion ignition mechanismspontaneous ignitioncryo-compressed hydrogencomputational fluid dynamicspressure limit for spontaneous ignitionhydrogen safety engineering
spellingShingle Donatella Cirrone
Dmitriy Makarov
Vladimir Molkov
Spontaneous Ignition of Cryo-Compressed Hydrogen in a T-Shaped Channel System
Hydrogen
diffusion ignition mechanism
spontaneous ignition
cryo-compressed hydrogen
computational fluid dynamics
pressure limit for spontaneous ignition
hydrogen safety engineering
title Spontaneous Ignition of Cryo-Compressed Hydrogen in a T-Shaped Channel System
title_full Spontaneous Ignition of Cryo-Compressed Hydrogen in a T-Shaped Channel System
title_fullStr Spontaneous Ignition of Cryo-Compressed Hydrogen in a T-Shaped Channel System
title_full_unstemmed Spontaneous Ignition of Cryo-Compressed Hydrogen in a T-Shaped Channel System
title_short Spontaneous Ignition of Cryo-Compressed Hydrogen in a T-Shaped Channel System
title_sort spontaneous ignition of cryo compressed hydrogen in a t shaped channel system
topic diffusion ignition mechanism
spontaneous ignition
cryo-compressed hydrogen
computational fluid dynamics
pressure limit for spontaneous ignition
hydrogen safety engineering
url https://www.mdpi.com/2673-4141/3/3/21
work_keys_str_mv AT donatellacirrone spontaneousignitionofcryocompressedhydrogeninatshapedchannelsystem
AT dmitriymakarov spontaneousignitionofcryocompressedhydrogeninatshapedchannelsystem
AT vladimirmolkov spontaneousignitionofcryocompressedhydrogeninatshapedchannelsystem