Validation of methane and carbon monoxide from Sentinel-5 Precursor using TCCON and NDACC-IRWG stations

<p>The Sentinel-5 Precursor (S5P) mission with the TROPOspheric Monitoring Instrument (TROPOMI) on board has been measuring solar radiation backscattered by the Earth's atmosphere and surface since its launch on 13 October 2017. In this paper, we present for the first time the S5P operati...

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Main Authors: M. K. Sha, B. Langerock, J.-F. L. Blavier, T. Blumenstock, T. Borsdorff, M. Buschmann, A. Dehn, M. De Mazière, N. M. Deutscher, D. G. Feist, O. E. García, D. W. T. Griffith, M. Grutter, J. W. Hannigan, F. Hase, P. Heikkinen, C. Hermans, L. T. Iraci, P. Jeseck, N. Jones, R. Kivi, N. Kumps, J. Landgraf, A. Lorente, E. Mahieu, M. V. Makarova, J. Mellqvist, J.-M. Metzger, I. Morino, T. Nagahama, J. Notholt, H. Ohyama, I. Ortega, M. Palm, C. Petri, D. F. Pollard, M. Rettinger, J. Robinson, S. Roche, C. M. Roehl, A. N. Röhling, C. Rousogenous, M. Schneider, K. Shiomi, D. Smale, W. Stremme, K. Strong, R. Sussmann, Y. Té, O. Uchino, V. A. Velazco, C. Vigouroux, M. Vrekoussis, P. Wang, T. Warneke, T. Wizenberg, D. Wunch, S. Yamanouchi, Y. Yang, M. Zhou
Format: Article
Language:English
Published: Copernicus Publications 2021-09-01
Series:Atmospheric Measurement Techniques
Online Access:https://amt.copernicus.org/articles/14/6249/2021/amt-14-6249-2021.pdf
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author M. K. Sha
B. Langerock
J.-F. L. Blavier
T. Blumenstock
T. Borsdorff
M. Buschmann
A. Dehn
M. De Mazière
N. M. Deutscher
D. G. Feist
D. G. Feist
D. G. Feist
O. E. García
D. W. T. Griffith
M. Grutter
J. W. Hannigan
F. Hase
P. Heikkinen
C. Hermans
L. T. Iraci
P. Jeseck
N. Jones
R. Kivi
N. Kumps
J. Landgraf
A. Lorente
E. Mahieu
M. V. Makarova
J. Mellqvist
J.-M. Metzger
I. Morino
T. Nagahama
J. Notholt
H. Ohyama
I. Ortega
M. Palm
C. Petri
D. F. Pollard
M. Rettinger
J. Robinson
S. Roche
C. M. Roehl
A. N. Röhling
C. Rousogenous
M. Schneider
K. Shiomi
D. Smale
W. Stremme
K. Strong
R. Sussmann
Y. Té
O. Uchino
V. A. Velazco
C. Vigouroux
M. Vrekoussis
M. Vrekoussis
P. Wang
P. Wang
T. Warneke
T. Wizenberg
D. Wunch
S. Yamanouchi
Y. Yang
Y. Yang
Y. Yang
M. Zhou
author_facet M. K. Sha
B. Langerock
J.-F. L. Blavier
T. Blumenstock
T. Borsdorff
M. Buschmann
A. Dehn
M. De Mazière
N. M. Deutscher
D. G. Feist
D. G. Feist
D. G. Feist
O. E. García
D. W. T. Griffith
M. Grutter
J. W. Hannigan
F. Hase
P. Heikkinen
C. Hermans
L. T. Iraci
P. Jeseck
N. Jones
R. Kivi
N. Kumps
J. Landgraf
A. Lorente
E. Mahieu
M. V. Makarova
J. Mellqvist
J.-M. Metzger
I. Morino
T. Nagahama
J. Notholt
H. Ohyama
I. Ortega
M. Palm
C. Petri
D. F. Pollard
M. Rettinger
J. Robinson
S. Roche
C. M. Roehl
A. N. Röhling
C. Rousogenous
M. Schneider
K. Shiomi
D. Smale
W. Stremme
K. Strong
R. Sussmann
Y. Té
O. Uchino
V. A. Velazco
C. Vigouroux
M. Vrekoussis
M. Vrekoussis
P. Wang
P. Wang
T. Warneke
T. Wizenberg
D. Wunch
S. Yamanouchi
Y. Yang
Y. Yang
Y. Yang
M. Zhou
author_sort M. K. Sha
collection DOAJ
description <p>The Sentinel-5 Precursor (S5P) mission with the TROPOspheric Monitoring Instrument (TROPOMI) on board has been measuring solar radiation backscattered by the Earth's atmosphere and surface since its launch on 13 October 2017. In this paper, we present for the first time the S5P operational methane (<span class="inline-formula">CH<sub>4</sub></span>) and carbon monoxide (CO) products' validation results covering a period of about 3 years using global Total Carbon Column Observing Network (TCCON) and Infrared Working Group of the Network for the Detection of Atmospheric Composition Change (NDACC-IRWG) network data, accounting for a priori alignment and smoothing uncertainties in the validation, and testing the sensitivity of validation results towards the application of advanced co-location criteria. We found that the S5P standard and bias-corrected <span class="inline-formula">CH<sub>4</sub></span> data over land surface for the recommended quality filtering fulfil the mission requirements. The systematic difference of the bias-corrected total column-averaged dry air mole fraction of methane (<span class="inline-formula">XCH<sub>4</sub></span>) data with respect to TCCON data is <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M5" display="inline" overflow="scroll" dspmath="mathml"><mrow><mo>-</mo><mn mathvariant="normal">0.26</mn><mo>±</mo><mn mathvariant="normal">0.56</mn></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="64pt" height="10pt" class="svg-formula" dspmath="mathimg" md5hash="cf12f1ebda09b23099609c4f56d721cb"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="amt-14-6249-2021-ie00001.svg" width="64pt" height="10pt" src="amt-14-6249-2021-ie00001.png"/></svg:svg></span></span> % in comparison to <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M6" display="inline" overflow="scroll" dspmath="mathml"><mrow><mo>-</mo><mn mathvariant="normal">0.68</mn><mo>±</mo><mn mathvariant="normal">0.74</mn></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="64pt" height="10pt" class="svg-formula" dspmath="mathimg" md5hash="9ae74d02ec25319b16974d15a6879a7e"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="amt-14-6249-2021-ie00002.svg" width="64pt" height="10pt" src="amt-14-6249-2021-ie00002.png"/></svg:svg></span></span> % for the standard <span class="inline-formula">XCH<sub>4</sub></span> data, with a correlation of 0.6 for most stations. The bias shows a seasonal dependence. We found that the S5P CO data over all surfaces for the recommended quality filtering generally fulfil the missions requirements, with a few exceptions, which are mostly due to co-location mismatches and limited availability of data. The systematic difference between the S5P total column-averaged dry air mole fraction of carbon monoxide (XCO) and the TCCON data is on average <span class="inline-formula">9.22±3.45</span> % (standard TCCON XCO) and <span class="inline-formula">2.45±3.38</span> % (unscaled TCCON XCO). We found that the systematic difference between the S5P CO column and NDACC CO column (excluding two outlier stations) is on average <span class="inline-formula">6.5±3.54</span> %. We found a correlation of above 0.9 for most TCCON and NDACC stations. The study shows the high quality of S5P <span class="inline-formula">CH<sub>4</sub></span> and CO data by validating the products against reference global TCCON and NDACC stations covering a wide range of latitudinal bands, atmospheric conditions and surface conditions.</p>
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spelling doaj.art-c0f00d5f51ee4cffa2ef0c48aa29c1122022-12-21T22:08:06ZengCopernicus PublicationsAtmospheric Measurement Techniques1867-13811867-85482021-09-01146249630410.5194/amt-14-6249-2021Validation of methane and carbon monoxide from Sentinel-5 Precursor using TCCON and NDACC-IRWG stationsM. K. Sha0B. Langerock1J.-F. L. Blavier2T. Blumenstock3T. Borsdorff4M. Buschmann5A. Dehn6M. De Mazière7N. M. Deutscher8D. G. Feist9D. G. Feist10D. G. Feist11O. E. García12D. W. T. Griffith13M. Grutter14J. W. Hannigan15F. Hase16P. Heikkinen17C. Hermans18L. T. Iraci19P. Jeseck20N. Jones21R. Kivi22N. Kumps23J. Landgraf24A. Lorente25E. Mahieu26M. V. Makarova27J. Mellqvist28J.-M. Metzger29I. Morino30T. Nagahama31J. Notholt32H. Ohyama33I. Ortega34M. Palm35C. Petri36D. F. Pollard37M. Rettinger38J. Robinson39S. Roche40C. M. Roehl41A. N. Röhling42C. Rousogenous43M. Schneider44K. Shiomi45D. Smale46W. Stremme47K. Strong48R. Sussmann49Y. Té50O. Uchino51V. A. Velazco52C. Vigouroux53M. Vrekoussis54M. Vrekoussis55P. Wang56P. Wang57T. Warneke58T. Wizenberg59D. Wunch60S. Yamanouchi61Y. Yang62Y. Yang63Y. Yang64M. Zhou65Royal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, BelgiumRoyal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, BelgiumJet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, USAKarlsruhe Institute of Technology, IMK-ASF, Karlsruhe, GermanySRON Netherlands Institute for Space Research, Utrecht, the NetherlandsInstitute of Environmental Physics, University of Bremen, Bremen, GermanyEuropean Space Agency, ESA/ESRIN, Frascati, ItalyRoyal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, BelgiumCentre for Atmospheric Chemistry, School of Earth, Atmospheric and Life Sciences, University of Wollongong, Wollongong, AustraliaLudwig-Maximilians-Universität München, Lehrstuhl für Physik der Atmosphäre, Munich, GermanyDeutsches Zentrum für Luft- und Raumfahrt, Institut für Physik der Atmosphäre, Oberpfaffenhofen, GermanyMax Planck Institute for Biogeochemistry, Jena, GermanyIzaña Atmospheric Research Centre (IARC), State Meteorological Agency of Spain (AEMET), Santa Cruz de Tenerife, SpainCentre for Atmospheric Chemistry, School of Earth, Atmospheric and Life Sciences, University of Wollongong, Wollongong, AustraliaCentro de Ciencias de la Atmósfera, Universidad Nacional Autonoma de Mexico, UNAM, Mexico City, MexicoNational Center for Atmospheric Research, Boulder, CO, USAKarlsruhe Institute of Technology, IMK-ASF, Karlsruhe, GermanyFinnish Meteorological Institute, FMI, Sodankylä, FinlandRoyal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, BelgiumNASA Ames Research Center, Moffett Field, CA, USALERMA-IPSL, Sorbonne Université, CNRS, Observatoire de Paris, PSL Université, Paris, FranceCentre for Atmospheric Chemistry, School of Earth, Atmospheric and Life Sciences, University of Wollongong, Wollongong, AustraliaFinnish Meteorological Institute, FMI, Sodankylä, FinlandRoyal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, BelgiumSRON Netherlands Institute for Space Research, Utrecht, the NetherlandsSRON Netherlands Institute for Space Research, Utrecht, the NetherlandsInstitut d'Astrophysique et de Géophysique, Université de Liège, Liège, BelgiumDepartment of Atmospheric Physics, Faculty of Physics, St. Petersburg State University, Saint Petersburg, RussiaEarth and Space Sciences, Chalmers University of Technology, Gothenburg, SwedenUAR 3365 – OSU Réunion, Université de La Réunion, Saint-Denis, Réunion, FranceNational Institute for Environmental Studies (NIES), Tsukuba, JapanInstitute for Space-Earth Environmental Research (ISEE), Nagoya University, Nagoya, JapanInstitute of Environmental Physics, University of Bremen, Bremen, GermanyNational Institute for Environmental Studies (NIES), Tsukuba, JapanNational Center for Atmospheric Research, Boulder, CO, USAInstitute of Environmental Physics, University of Bremen, Bremen, GermanyInstitute of Environmental Physics, University of Bremen, Bremen, GermanyNational Institute of Water and Atmospheric Research Ltd (NIWA), Lauder, New ZealandKarlsruhe Institute of Technology, IMK-IFU, Garmisch-Partenkirchen, GermanyNational Institute of Water and Atmospheric Research Ltd (NIWA), Lauder, New ZealandDepartment of Physics, University of Toronto, Toronto, Ontario, CanadaDivision of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA, USAKarlsruhe Institute of Technology, IMK-ASF, Karlsruhe, GermanyClimate and Atmosphere Research Center (CARE-C), the Cyprus Institute, Nicosia, CyprusKarlsruhe Institute of Technology, IMK-ASF, Karlsruhe, GermanyEarth Observation Research Center (EORC), Japan Aerospace Exploration Agency (JAXA), Tsukuba, JapanNational Institute of Water and Atmospheric Research Ltd (NIWA), Lauder, New ZealandCentro de Ciencias de la Atmósfera, Universidad Nacional Autonoma de Mexico, UNAM, Mexico City, MexicoDepartment of Physics, University of Toronto, Toronto, Ontario, CanadaKarlsruhe Institute of Technology, IMK-IFU, Garmisch-Partenkirchen, GermanyLERMA-IPSL, Sorbonne Université, CNRS, Observatoire de Paris, PSL Université, Paris, FranceNational Institute for Environmental Studies (NIES), Tsukuba, JapanCentre for Atmospheric Chemistry, School of Earth, Atmospheric and Life Sciences, University of Wollongong, Wollongong, AustraliaRoyal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, BelgiumInstitute of Environmental Physics, University of Bremen, Bremen, GermanyClimate and Atmosphere Research Center (CARE-C), the Cyprus Institute, Nicosia, CyprusLAGEO, the Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, ChinaUniversity of Chinese Academy of Sciences, Beijing, ChinaInstitute of Environmental Physics, University of Bremen, Bremen, GermanyDepartment of Physics, University of Toronto, Toronto, Ontario, CanadaDepartment of Physics, University of Toronto, Toronto, Ontario, CanadaDepartment of Physics, University of Toronto, Toronto, Ontario, CanadaRoyal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, BelgiumLAGEO, the Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, ChinaShanghai Ecological Forecasting and Remote Sensing Center, Shanghai, ChinaRoyal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, Belgium<p>The Sentinel-5 Precursor (S5P) mission with the TROPOspheric Monitoring Instrument (TROPOMI) on board has been measuring solar radiation backscattered by the Earth's atmosphere and surface since its launch on 13 October 2017. In this paper, we present for the first time the S5P operational methane (<span class="inline-formula">CH<sub>4</sub></span>) and carbon monoxide (CO) products' validation results covering a period of about 3 years using global Total Carbon Column Observing Network (TCCON) and Infrared Working Group of the Network for the Detection of Atmospheric Composition Change (NDACC-IRWG) network data, accounting for a priori alignment and smoothing uncertainties in the validation, and testing the sensitivity of validation results towards the application of advanced co-location criteria. We found that the S5P standard and bias-corrected <span class="inline-formula">CH<sub>4</sub></span> data over land surface for the recommended quality filtering fulfil the mission requirements. The systematic difference of the bias-corrected total column-averaged dry air mole fraction of methane (<span class="inline-formula">XCH<sub>4</sub></span>) data with respect to TCCON data is <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M5" display="inline" overflow="scroll" dspmath="mathml"><mrow><mo>-</mo><mn mathvariant="normal">0.26</mn><mo>±</mo><mn mathvariant="normal">0.56</mn></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="64pt" height="10pt" class="svg-formula" dspmath="mathimg" md5hash="cf12f1ebda09b23099609c4f56d721cb"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="amt-14-6249-2021-ie00001.svg" width="64pt" height="10pt" src="amt-14-6249-2021-ie00001.png"/></svg:svg></span></span> % in comparison to <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M6" display="inline" overflow="scroll" dspmath="mathml"><mrow><mo>-</mo><mn mathvariant="normal">0.68</mn><mo>±</mo><mn mathvariant="normal">0.74</mn></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="64pt" height="10pt" class="svg-formula" dspmath="mathimg" md5hash="9ae74d02ec25319b16974d15a6879a7e"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="amt-14-6249-2021-ie00002.svg" width="64pt" height="10pt" src="amt-14-6249-2021-ie00002.png"/></svg:svg></span></span> % for the standard <span class="inline-formula">XCH<sub>4</sub></span> data, with a correlation of 0.6 for most stations. The bias shows a seasonal dependence. We found that the S5P CO data over all surfaces for the recommended quality filtering generally fulfil the missions requirements, with a few exceptions, which are mostly due to co-location mismatches and limited availability of data. The systematic difference between the S5P total column-averaged dry air mole fraction of carbon monoxide (XCO) and the TCCON data is on average <span class="inline-formula">9.22±3.45</span> % (standard TCCON XCO) and <span class="inline-formula">2.45±3.38</span> % (unscaled TCCON XCO). We found that the systematic difference between the S5P CO column and NDACC CO column (excluding two outlier stations) is on average <span class="inline-formula">6.5±3.54</span> %. We found a correlation of above 0.9 for most TCCON and NDACC stations. The study shows the high quality of S5P <span class="inline-formula">CH<sub>4</sub></span> and CO data by validating the products against reference global TCCON and NDACC stations covering a wide range of latitudinal bands, atmospheric conditions and surface conditions.</p>https://amt.copernicus.org/articles/14/6249/2021/amt-14-6249-2021.pdf
spellingShingle M. K. Sha
B. Langerock
J.-F. L. Blavier
T. Blumenstock
T. Borsdorff
M. Buschmann
A. Dehn
M. De Mazière
N. M. Deutscher
D. G. Feist
D. G. Feist
D. G. Feist
O. E. García
D. W. T. Griffith
M. Grutter
J. W. Hannigan
F. Hase
P. Heikkinen
C. Hermans
L. T. Iraci
P. Jeseck
N. Jones
R. Kivi
N. Kumps
J. Landgraf
A. Lorente
E. Mahieu
M. V. Makarova
J. Mellqvist
J.-M. Metzger
I. Morino
T. Nagahama
J. Notholt
H. Ohyama
I. Ortega
M. Palm
C. Petri
D. F. Pollard
M. Rettinger
J. Robinson
S. Roche
C. M. Roehl
A. N. Röhling
C. Rousogenous
M. Schneider
K. Shiomi
D. Smale
W. Stremme
K. Strong
R. Sussmann
Y. Té
O. Uchino
V. A. Velazco
C. Vigouroux
M. Vrekoussis
M. Vrekoussis
P. Wang
P. Wang
T. Warneke
T. Wizenberg
D. Wunch
S. Yamanouchi
Y. Yang
Y. Yang
Y. Yang
M. Zhou
Validation of methane and carbon monoxide from Sentinel-5 Precursor using TCCON and NDACC-IRWG stations
Atmospheric Measurement Techniques
title Validation of methane and carbon monoxide from Sentinel-5 Precursor using TCCON and NDACC-IRWG stations
title_full Validation of methane and carbon monoxide from Sentinel-5 Precursor using TCCON and NDACC-IRWG stations
title_fullStr Validation of methane and carbon monoxide from Sentinel-5 Precursor using TCCON and NDACC-IRWG stations
title_full_unstemmed Validation of methane and carbon monoxide from Sentinel-5 Precursor using TCCON and NDACC-IRWG stations
title_short Validation of methane and carbon monoxide from Sentinel-5 Precursor using TCCON and NDACC-IRWG stations
title_sort validation of methane and carbon monoxide from sentinel 5 precursor using tccon and ndacc irwg stations
url https://amt.copernicus.org/articles/14/6249/2021/amt-14-6249-2021.pdf
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AT mvrekoussis validationofmethaneandcarbonmonoxidefromsentinel5precursorusingtcconandndaccirwgstations
AT pwang validationofmethaneandcarbonmonoxidefromsentinel5precursorusingtcconandndaccirwgstations
AT pwang validationofmethaneandcarbonmonoxidefromsentinel5precursorusingtcconandndaccirwgstations
AT twarneke validationofmethaneandcarbonmonoxidefromsentinel5precursorusingtcconandndaccirwgstations
AT twizenberg validationofmethaneandcarbonmonoxidefromsentinel5precursorusingtcconandndaccirwgstations
AT dwunch validationofmethaneandcarbonmonoxidefromsentinel5precursorusingtcconandndaccirwgstations
AT syamanouchi validationofmethaneandcarbonmonoxidefromsentinel5precursorusingtcconandndaccirwgstations
AT yyang validationofmethaneandcarbonmonoxidefromsentinel5precursorusingtcconandndaccirwgstations
AT yyang validationofmethaneandcarbonmonoxidefromsentinel5precursorusingtcconandndaccirwgstations
AT yyang validationofmethaneandcarbonmonoxidefromsentinel5precursorusingtcconandndaccirwgstations
AT mzhou validationofmethaneandcarbonmonoxidefromsentinel5precursorusingtcconandndaccirwgstations