Wet digestion and differential pulse stripping voltammetry determination of total chromium in the millet
The chromium content of millet is measured by HNO3-H2O2 digestion and electrochemical method. In the DTPA-HAc-NaAc system, the oxidation peak current of amalgam formed by hexavalent chrome ion is obtained in the plating mercury electrode, and the pre-treatment technology of wet digestion can meet th...
| Main Authors: | , , |
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| Format: | Article |
| Language: | zho |
| Published: |
Hebei University of Science and Technology
2015-06-01
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| Series: | Journal of Hebei University of Science and Technology |
| Subjects: | |
| Online Access: | http://xuebao.hebust.edu.cn/hbkjdx/ch/reader/create_pdf.aspx?file_no=b201503015&flag=1&journal_ |
| Summary: | The chromium content of millet is measured by HNO3-H2O2 digestion and electrochemical method. In the DTPA-HAc-NaAc system, the oxidation peak current of amalgam formed by hexavalent chrome ion is obtained in the plating mercury electrode, and the pre-treatment technology of wet digestion can meet the electrochemical determination. The optimized detection condition of electrochemical method for hexavalent chrome ion is 130 ℃ of digestion solution, 10 mL hydrogen peroxide, 38 mL nitric acid, and neutral of pH. The linear correlation coefficient of electrochemical method is 0.99, and the recovery of standard addition is 90%~110%. This method can be used to trace chromium (Ⅵ) determination in millet. |
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| ISSN: | 1008-1542 |