Effect of Laser Beam Profile on Rotating Lattice Single Crystal Growth in Sb<sub>2</sub>S<sub>3</sub> Model Glass

Laser heating of chalcogenide glasses has successfully produced rotating lattice single crystals through a solid-solid transformation. To better understand the nature of complex, orientation-dependent lattice rotation, we designed heat profiles of the continuous wave laser by beam shaping, fabricate...

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Bibliographic Details
Main Authors: Courtney Au-Yeung, Dmytro Savytskii, Keith Veenhuizen, Volkmar Dierolf, Himanshu Jain
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/11/1/36
Description
Summary:Laser heating of chalcogenide glasses has successfully produced rotating lattice single crystals through a solid-solid transformation. To better understand the nature of complex, orientation-dependent lattice rotation, we designed heat profiles of the continuous wave laser by beam shaping, fabricated larger Sb<sub>2</sub>S<sub>3</sub> crystal dots in Sb<sub>2</sub>S<sub>3</sub> glass, and investigated the lattice rotation where the crystal could grow in all radial directions under a circular thermal gradient. The results show that the rate of lattice rotation is highly anisotropic and depends on crystallographic direction. The nature of this rotation is the same in crystals of different orientation relative to the surface. The growth directions that align with the slip planes show the highest rate of rotation and the rotation rate gradually decreases away from this direction. Additionally, the presence of multiple growth directions results in a complicated rotation system. We suggest that the growth front influences the density of dislocations introduced during growth under confinement and thus affects the lattice rotation rate in these crystals.
ISSN:2073-4352