Microstructure and wettability of the micro-laminated Ti6Al4V/304 stainless steel composite fabricated by diffusion bonding

Laminated composites have been extensively researched due to their excellent mechanical properties, but their application in superwetting fields has been rarely reported. In this work, the surfaces with extreme wettability were prepared based on laminated composites. The Ti6Al4V/304 stainless steel...

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Main Authors: Dejun Gao, Chun Li, Chenghao Zhang, Bo Yang, Tong Lin, Lei Chen, Xiaoqing Si, Junlei Qi, Jian Cao
Format: Article
Language:English
Published: Elsevier 2023-11-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785423026686
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author Dejun Gao
Chun Li
Chenghao Zhang
Bo Yang
Tong Lin
Lei Chen
Xiaoqing Si
Junlei Qi
Jian Cao
author_facet Dejun Gao
Chun Li
Chenghao Zhang
Bo Yang
Tong Lin
Lei Chen
Xiaoqing Si
Junlei Qi
Jian Cao
author_sort Dejun Gao
collection DOAJ
description Laminated composites have been extensively researched due to their excellent mechanical properties, but their application in superwetting fields has been rarely reported. In this work, the surfaces with extreme wettability were prepared based on laminated composites. The Ti6Al4V/304 stainless steel (304 SS) micro-laminated composites were fabricated by diffusion bonding the Ti6Al4V foils and 304 SS foils with the thickness of 10–50 μm in vacuum. The typical interfacial microstructure and the effect of diffusion temperature on the microstructure were investigated. The bonded interface of joints is mainly composed of β-Ti, Ti2Ni, FeTi, Fe2Ti, Fe–Cr from the Ti6Al4V side to the 304 SS. The effect of diffusion temperature on the microstructure was researched. Based on the prepared Ti6Al4V/304 SS micro-laminated composites, an array structure with micro grooves was fabricated through the simple chemical etching. The 304 SS foils were etched to form grooves, while Ti6Al4V foils still remained as bulges. Due to surface modification and rough morphology, the etched surfaces exhibited the excellent hydrophobicity. Increasing the width and depth of grooves and decreasing the width of bulges led to the higher water contact angles and improved hydrophobicity. The highest water contact angles of 148.3° has been achieved under the conditions of grooves with a width of 50 μm, a depth of 60 μm, and the bulges with a width of 10 μm. The surfaces exhibited nearly superhydrophobicity and performed self-cleaning property. The processing method of this work could expand the application of laminated composite in extreme wettability fields.
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spelling doaj.art-c1540333437c49c48e7b12a0462350362024-02-21T05:26:51ZengElsevierJournal of Materials Research and Technology2238-78542023-11-012737883796Microstructure and wettability of the micro-laminated Ti6Al4V/304 stainless steel composite fabricated by diffusion bondingDejun Gao0Chun Li1Chenghao Zhang2Bo Yang3Tong Lin4Lei Chen5Xiaoqing Si6Junlei Qi7Jian Cao8State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin, 150001, ChinaCorresponding author.; State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin, 150001, ChinaState Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin, 150001, ChinaState Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin, 150001, ChinaState Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin, 150001, ChinaState Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin, 150001, ChinaState Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin, 150001, ChinaState Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin, 150001, ChinaCorresponding author.; State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin, 150001, ChinaLaminated composites have been extensively researched due to their excellent mechanical properties, but their application in superwetting fields has been rarely reported. In this work, the surfaces with extreme wettability were prepared based on laminated composites. The Ti6Al4V/304 stainless steel (304 SS) micro-laminated composites were fabricated by diffusion bonding the Ti6Al4V foils and 304 SS foils with the thickness of 10–50 μm in vacuum. The typical interfacial microstructure and the effect of diffusion temperature on the microstructure were investigated. The bonded interface of joints is mainly composed of β-Ti, Ti2Ni, FeTi, Fe2Ti, Fe–Cr from the Ti6Al4V side to the 304 SS. The effect of diffusion temperature on the microstructure was researched. Based on the prepared Ti6Al4V/304 SS micro-laminated composites, an array structure with micro grooves was fabricated through the simple chemical etching. The 304 SS foils were etched to form grooves, while Ti6Al4V foils still remained as bulges. Due to surface modification and rough morphology, the etched surfaces exhibited the excellent hydrophobicity. Increasing the width and depth of grooves and decreasing the width of bulges led to the higher water contact angles and improved hydrophobicity. The highest water contact angles of 148.3° has been achieved under the conditions of grooves with a width of 50 μm, a depth of 60 μm, and the bulges with a width of 10 μm. The surfaces exhibited nearly superhydrophobicity and performed self-cleaning property. The processing method of this work could expand the application of laminated composite in extreme wettability fields.http://www.sciencedirect.com/science/article/pii/S2238785423026686Micro-laminated compositeDiffusion bondingTi6Al4V304 stainless steelWettability
spellingShingle Dejun Gao
Chun Li
Chenghao Zhang
Bo Yang
Tong Lin
Lei Chen
Xiaoqing Si
Junlei Qi
Jian Cao
Microstructure and wettability of the micro-laminated Ti6Al4V/304 stainless steel composite fabricated by diffusion bonding
Journal of Materials Research and Technology
Micro-laminated composite
Diffusion bonding
Ti6Al4V
304 stainless steel
Wettability
title Microstructure and wettability of the micro-laminated Ti6Al4V/304 stainless steel composite fabricated by diffusion bonding
title_full Microstructure and wettability of the micro-laminated Ti6Al4V/304 stainless steel composite fabricated by diffusion bonding
title_fullStr Microstructure and wettability of the micro-laminated Ti6Al4V/304 stainless steel composite fabricated by diffusion bonding
title_full_unstemmed Microstructure and wettability of the micro-laminated Ti6Al4V/304 stainless steel composite fabricated by diffusion bonding
title_short Microstructure and wettability of the micro-laminated Ti6Al4V/304 stainless steel composite fabricated by diffusion bonding
title_sort microstructure and wettability of the micro laminated ti6al4v 304 stainless steel composite fabricated by diffusion bonding
topic Micro-laminated composite
Diffusion bonding
Ti6Al4V
304 stainless steel
Wettability
url http://www.sciencedirect.com/science/article/pii/S2238785423026686
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