The impact of minor Cr additions in low alloy steel on corrosion behavior in simulated well environment

Abstract Low alloy steel samples with different Cr content (0‒3 wt%) have been exposed to simulated well environment. It is revealed that the 3%Cr sample initially has the highest corrosion resistance. However, due to faster formation of a FexCayCO3 protective scale in the 0%Cr sample, this sample d...

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Main Authors: Kapil K. Gupta, Saber Haratian, Oleg V. Mishin, Rajan Ambat
Format: Article
Language:English
Published: Nature Portfolio 2023-08-01
Series:npj Materials Degradation
Online Access:https://doi.org/10.1038/s41529-023-00393-y
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author Kapil K. Gupta
Saber Haratian
Oleg V. Mishin
Rajan Ambat
author_facet Kapil K. Gupta
Saber Haratian
Oleg V. Mishin
Rajan Ambat
author_sort Kapil K. Gupta
collection DOAJ
description Abstract Low alloy steel samples with different Cr content (0‒3 wt%) have been exposed to simulated well environment. It is revealed that the 3%Cr sample initially has the highest corrosion resistance. However, due to faster formation of a FexCayCO3 protective scale in the 0%Cr sample, this sample demonstrates the highest corrosion resistance after 2 days of exposure. While the FexCayCO3 scale is also formed in the 1%Cr sample, the scale is weakly adhered and porous, which does not enable good corrosion resistance. Although the scale formation is delayed in a sample with 3 wt%Cr, once it is formed, the presence of Cr-rich phase in this scale provides greater long-term corrosion protection. Localized corrosion attack is observed in the samples with 0% Cr and 1%Cr, whereas the 3%Cr sample shows no sign of localized attack due to initial pre-passivation and the ability to rebuild the protective scale.
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spelling doaj.art-c157c36385854049b28aac1f133b73ea2023-11-20T10:26:10ZengNature Portfolionpj Materials Degradation2397-21062023-08-017111210.1038/s41529-023-00393-yThe impact of minor Cr additions in low alloy steel on corrosion behavior in simulated well environmentKapil K. Gupta0Saber Haratian1Oleg V. Mishin2Rajan Ambat3Section of Materials and Surface Engineering, Department of Civil and Mechanical Engineering, Technical University of DenmarkSection of Materials and Surface Engineering, Department of Civil and Mechanical Engineering, Technical University of DenmarkSection of Materials and Surface Engineering, Department of Civil and Mechanical Engineering, Technical University of DenmarkSection of Materials and Surface Engineering, Department of Civil and Mechanical Engineering, Technical University of DenmarkAbstract Low alloy steel samples with different Cr content (0‒3 wt%) have been exposed to simulated well environment. It is revealed that the 3%Cr sample initially has the highest corrosion resistance. However, due to faster formation of a FexCayCO3 protective scale in the 0%Cr sample, this sample demonstrates the highest corrosion resistance after 2 days of exposure. While the FexCayCO3 scale is also formed in the 1%Cr sample, the scale is weakly adhered and porous, which does not enable good corrosion resistance. Although the scale formation is delayed in a sample with 3 wt%Cr, once it is formed, the presence of Cr-rich phase in this scale provides greater long-term corrosion protection. Localized corrosion attack is observed in the samples with 0% Cr and 1%Cr, whereas the 3%Cr sample shows no sign of localized attack due to initial pre-passivation and the ability to rebuild the protective scale.https://doi.org/10.1038/s41529-023-00393-y
spellingShingle Kapil K. Gupta
Saber Haratian
Oleg V. Mishin
Rajan Ambat
The impact of minor Cr additions in low alloy steel on corrosion behavior in simulated well environment
npj Materials Degradation
title The impact of minor Cr additions in low alloy steel on corrosion behavior in simulated well environment
title_full The impact of minor Cr additions in low alloy steel on corrosion behavior in simulated well environment
title_fullStr The impact of minor Cr additions in low alloy steel on corrosion behavior in simulated well environment
title_full_unstemmed The impact of minor Cr additions in low alloy steel on corrosion behavior in simulated well environment
title_short The impact of minor Cr additions in low alloy steel on corrosion behavior in simulated well environment
title_sort impact of minor cr additions in low alloy steel on corrosion behavior in simulated well environment
url https://doi.org/10.1038/s41529-023-00393-y
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