Removal of Disperse Blue 56 from synthetic textile effluent using ionic flocculation

The textile industry is one of the main generators of industrial effluent due to the large volumes of water containing a wide variety of pollutants, including dyes. Thus, the present study aimed to remove the Disperse Blue 56 dye present in synthetic textile effluent using ionic flocculation through...

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Main Authors: R. P. F. Melo, S. K. S. Carmo, E. L. B. Barros, A. G. Câmara, S. K. S. Nunes, E. L. Barros Neto
Format: Article
Language:English
Published: IWA Publishing 2021-06-01
Series:Water Science and Technology
Subjects:
Online Access:http://wst.iwaponline.com/content/83/11/2714
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author R. P. F. Melo
S. K. S. Carmo
E. L. B. Barros
A. G. Câmara
S. K. S. Nunes
E. L. Barros Neto
author_facet R. P. F. Melo
S. K. S. Carmo
E. L. B. Barros
A. G. Câmara
S. K. S. Nunes
E. L. Barros Neto
author_sort R. P. F. Melo
collection DOAJ
description The textile industry is one of the main generators of industrial effluent due to the large volumes of water containing a wide variety of pollutants, including dyes. Thus, the present study aimed to remove the Disperse Blue 56 dye present in synthetic textile effluent using ionic flocculation through surfactant flocs produced from animal/vegetable fat, assessing the system at different surfactant concentrations and temperatures. The process kinetics, adsorption mechanism and equilibrium were evaluated. The results show that the kinetics was better described by the Elovich model when compared to pseudo-first order and pseudo-second order models, indicating that chemical adsorption occurs during the process. The study of the adsorption mechanism obtained lower outer layer diffusivities than their intra-particle counterparts, demonstrating that the dye transport to the surfactant floc is controlled through the outer layer. The Langmuir isotherm was suitable for equilibrium data and the separation factor calculated showed that the isotherm is classified as favorable. Dye removal efficiency reached 87% after 360 minutes of contact between the effluent and the surfactant flocs, indicating that ionic flocculation is an efficient alternative in the treatment of textile effluent containing disperse dye. HIGHLIGHTS Ionic flocculation was studied for removal of a disperse dye from water.; Surfactants obtained from animal/vegetable fat are used for wastewater treatment.; Kinetic, diffusion mechanism and equilibrium were evaluated.; Temperature does not have considerable influence on the process.; The proposed methodology allows a removal efficiency of 87%.;
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spelling doaj.art-c165db6c32224e4fa2b857a49f8f63442022-12-21T19:19:01ZengIWA PublishingWater Science and Technology0273-12231996-97322021-06-0183112714272310.2166/wst.2021.173173Removal of Disperse Blue 56 from synthetic textile effluent using ionic flocculationR. P. F. Melo0S. K. S. Carmo1E. L. B. Barros2A. G. Câmara3S. K. S. Nunes4E. L. Barros Neto5 Universidade Federal Rural do Semi-Árido, Campus Pau dos Ferros, Road BR-226, no number, Pau dos Ferros – RN, 59900-000, Brazil Universidade Federal Rural do Semi-Árido, Campus Pau dos Ferros, Road BR-226, no number, Pau dos Ferros – RN, 59900-000, Brazil Centro de Tecnologia – Departamento de Engenharia Química, Programa de Pós-Graduação em Engenharia Química, Universidade Federal do Rio Grande do Norte, Campus Universitário, Av. Senador Salgado Filho 3000, Natal-RN, 59072-970, Brazil Centro de Tecnologia – Departamento de Engenharia Química, Programa de Pós-Graduação em Engenharia Química, Universidade Federal do Rio Grande do Norte, Campus Universitário, Av. Senador Salgado Filho 3000, Natal-RN, 59072-970, Brazil Centro de Tecnologia – Departamento de Engenharia Química, Programa de Pós-Graduação em Engenharia Química, Universidade Federal do Rio Grande do Norte, Campus Universitário, Av. Senador Salgado Filho 3000, Natal-RN, 59072-970, Brazil Centro de Tecnologia – Departamento de Engenharia Química, Programa de Pós-Graduação em Engenharia Química, Universidade Federal do Rio Grande do Norte, Campus Universitário, Av. Senador Salgado Filho 3000, Natal-RN, 59072-970, Brazil The textile industry is one of the main generators of industrial effluent due to the large volumes of water containing a wide variety of pollutants, including dyes. Thus, the present study aimed to remove the Disperse Blue 56 dye present in synthetic textile effluent using ionic flocculation through surfactant flocs produced from animal/vegetable fat, assessing the system at different surfactant concentrations and temperatures. The process kinetics, adsorption mechanism and equilibrium were evaluated. The results show that the kinetics was better described by the Elovich model when compared to pseudo-first order and pseudo-second order models, indicating that chemical adsorption occurs during the process. The study of the adsorption mechanism obtained lower outer layer diffusivities than their intra-particle counterparts, demonstrating that the dye transport to the surfactant floc is controlled through the outer layer. The Langmuir isotherm was suitable for equilibrium data and the separation factor calculated showed that the isotherm is classified as favorable. Dye removal efficiency reached 87% after 360 minutes of contact between the effluent and the surfactant flocs, indicating that ionic flocculation is an efficient alternative in the treatment of textile effluent containing disperse dye. HIGHLIGHTS Ionic flocculation was studied for removal of a disperse dye from water.; Surfactants obtained from animal/vegetable fat are used for wastewater treatment.; Kinetic, diffusion mechanism and equilibrium were evaluated.; Temperature does not have considerable influence on the process.; The proposed methodology allows a removal efficiency of 87%.;http://wst.iwaponline.com/content/83/11/2714adsorption mechanism evaluationenvironmentally friendly surfactantionic flocculationkinetics and equilibrium adsorptiontextile effluent treatment
spellingShingle R. P. F. Melo
S. K. S. Carmo
E. L. B. Barros
A. G. Câmara
S. K. S. Nunes
E. L. Barros Neto
Removal of Disperse Blue 56 from synthetic textile effluent using ionic flocculation
Water Science and Technology
adsorption mechanism evaluation
environmentally friendly surfactant
ionic flocculation
kinetics and equilibrium adsorption
textile effluent treatment
title Removal of Disperse Blue 56 from synthetic textile effluent using ionic flocculation
title_full Removal of Disperse Blue 56 from synthetic textile effluent using ionic flocculation
title_fullStr Removal of Disperse Blue 56 from synthetic textile effluent using ionic flocculation
title_full_unstemmed Removal of Disperse Blue 56 from synthetic textile effluent using ionic flocculation
title_short Removal of Disperse Blue 56 from synthetic textile effluent using ionic flocculation
title_sort removal of disperse blue 56 from synthetic textile effluent using ionic flocculation
topic adsorption mechanism evaluation
environmentally friendly surfactant
ionic flocculation
kinetics and equilibrium adsorption
textile effluent treatment
url http://wst.iwaponline.com/content/83/11/2714
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