Enhanced electroresistance endurance of capped Hf0.5Zr0.5O2 ultrathin epitaxial tunnel barriers

Electroresistance in ultrathin Hf0.5Zr0.5O2 (HZO) films is pivotal toward the implementation of hafnia-based ferroelectrics in electronics. Here, we show that the electroresistance yield and endurance of large capacitors (∼314 µm2) of epitaxial HZO films only 2.2 nm thick grown on SrTiO3 or GdScO3 c...

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Bibliographic Details
Main Authors: Xiao Long, Huan Tan, Saúl Estandía, Jaume Gazquez, Florencio Sánchez, Ignasi Fina, Josep Fontcuberta
Format: Article
Language:English
Published: AIP Publishing LLC 2022-03-01
Series:APL Materials
Online Access:http://dx.doi.org/10.1063/5.0076865
Description
Summary:Electroresistance in ultrathin Hf0.5Zr0.5O2 (HZO) films is pivotal toward the implementation of hafnia-based ferroelectrics in electronics. Here, we show that the electroresistance yield and endurance of large capacitors (∼314 µm2) of epitaxial HZO films only 2.2 nm thick grown on SrTiO3 or GdScO3 can be improved using 1 nm SrTiO3 capping layers. It is argued that the main role of the capping layer is to minimize charge transport along grain boundaries, and, thus, a similar strategy can be explored in polycrystalline films.
ISSN:2166-532X