Ammonium zincates as suitable catalyst for the room temperature cycloaddition of CO2 to epoxides

Ammonium zincates as suitable catalyst for the room temperature cycloaddition of CO2 to epoxides

We have recently shown that simple ammonium ferrates are competent catalyst for the cycloaddition reaction of CO2 to epoxides under moderate reaction conditions (T = 100°C, P(CO2) = 0.8 MPa). We report here that ammonium zincates of general formulae [TBA]2 [ZnX4] (TBA = tetrabutylammonium), simply o...

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Bibliographic Details
Main Authors: Nicola Panza, Matteo Alberti, Caterina Damiano, Alessandro Caselli
Format: Article
Language:English
Published: Frontiers Media S.A. 2022-08-01
Series:Frontiers in Catalysis
Subjects:
homogeneous catalysis
zinc
chemical utilization of CO2
cyclic carbonates
zincates
Online Access:https://www.frontiersin.org/articles/10.3389/fctls.2022.991270/full

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