Reliability of Biodegradation Measurements for Inhibitive Industrial Wastewaters

Industrial wastewaters may contain toxic or highly inhibitive compounds, which makes the measurement of biological oxygen demand (BOD) challenging. Due to the high concentration of organic compounds within them, industrial wastewater samples must be diluted to perform BOD measurements. This study fo...

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Main Authors: Hanna Prokkola, Anne Heponiemi, Janne Pesonen, Toivo Kuokkanen, Ulla Lassi
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:ChemEngineering
Subjects:
Online Access:https://www.mdpi.com/2305-7084/6/1/15
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author Hanna Prokkola
Anne Heponiemi
Janne Pesonen
Toivo Kuokkanen
Ulla Lassi
author_facet Hanna Prokkola
Anne Heponiemi
Janne Pesonen
Toivo Kuokkanen
Ulla Lassi
author_sort Hanna Prokkola
collection DOAJ
description Industrial wastewaters may contain toxic or highly inhibitive compounds, which makes the measurement of biological oxygen demand (BOD) challenging. Due to the high concentration of organic compounds within them, industrial wastewater samples must be diluted to perform BOD measurements. This study focused on determining the reliability of wastewater BOD measurement using two different types of industrial wastewater, namely pharmaceutical wastewater containing a total organic carbon (TOC) value of 34,000 mg(C)/L and industrial paper manufacturing wastewater containing a corresponding TOC value of 30 mg(C)/L. Both manometric respirometry and the closed-bottle method were used in the study, and the results were compared. It was found that the dilution wastewaters containing inhibitive compounds affected BOD values, which increased due to the decreased inhibiting effect of wastewater pollutants. Therefore, the correct BOD for effluents should be measured from undiluted samples, while the diluted value is appropriate for determining the maximum value for biodegradable organic material in the effluent. The accuracy of the results from the blank samples was also examined, and it was found that the readings of these were different to those from the samples. Therefore, the blank value that must be subtracted may differ depending on the sample.
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spelling doaj.art-c17cf75c0905465382817f2b8203181b2023-11-23T19:16:49ZengMDPI AGChemEngineering2305-70842022-02-01611510.3390/chemengineering6010015Reliability of Biodegradation Measurements for Inhibitive Industrial WastewatersHanna Prokkola0Anne Heponiemi1Janne Pesonen2Toivo Kuokkanen3Ulla Lassi4Research Unit of Sustainable Chemistry, University of Oulu, P.O. Box 4300, FI-90014 Oulu, FinlandResearch Unit of Sustainable Chemistry, University of Oulu, P.O. Box 4300, FI-90014 Oulu, FinlandResearch Unit of Sustainable Chemistry, University of Oulu, P.O. Box 4300, FI-90014 Oulu, FinlandResearch Unit of Sustainable Chemistry, University of Oulu, P.O. Box 4300, FI-90014 Oulu, FinlandResearch Unit of Sustainable Chemistry, University of Oulu, P.O. Box 4300, FI-90014 Oulu, FinlandIndustrial wastewaters may contain toxic or highly inhibitive compounds, which makes the measurement of biological oxygen demand (BOD) challenging. Due to the high concentration of organic compounds within them, industrial wastewater samples must be diluted to perform BOD measurements. This study focused on determining the reliability of wastewater BOD measurement using two different types of industrial wastewater, namely pharmaceutical wastewater containing a total organic carbon (TOC) value of 34,000 mg(C)/L and industrial paper manufacturing wastewater containing a corresponding TOC value of 30 mg(C)/L. Both manometric respirometry and the closed-bottle method were used in the study, and the results were compared. It was found that the dilution wastewaters containing inhibitive compounds affected BOD values, which increased due to the decreased inhibiting effect of wastewater pollutants. Therefore, the correct BOD for effluents should be measured from undiluted samples, while the diluted value is appropriate for determining the maximum value for biodegradable organic material in the effluent. The accuracy of the results from the blank samples was also examined, and it was found that the readings of these were different to those from the samples. Therefore, the blank value that must be subtracted may differ depending on the sample.https://www.mdpi.com/2305-7084/6/1/15biodegradationBOD measurementsmanometric respirometryinhibitionwastewaterblank
spellingShingle Hanna Prokkola
Anne Heponiemi
Janne Pesonen
Toivo Kuokkanen
Ulla Lassi
Reliability of Biodegradation Measurements for Inhibitive Industrial Wastewaters
ChemEngineering
biodegradation
BOD measurements
manometric respirometry
inhibition
wastewater
blank
title Reliability of Biodegradation Measurements for Inhibitive Industrial Wastewaters
title_full Reliability of Biodegradation Measurements for Inhibitive Industrial Wastewaters
title_fullStr Reliability of Biodegradation Measurements for Inhibitive Industrial Wastewaters
title_full_unstemmed Reliability of Biodegradation Measurements for Inhibitive Industrial Wastewaters
title_short Reliability of Biodegradation Measurements for Inhibitive Industrial Wastewaters
title_sort reliability of biodegradation measurements for inhibitive industrial wastewaters
topic biodegradation
BOD measurements
manometric respirometry
inhibition
wastewater
blank
url https://www.mdpi.com/2305-7084/6/1/15
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AT anneheponiemi reliabilityofbiodegradationmeasurementsforinhibitiveindustrialwastewaters
AT jannepesonen reliabilityofbiodegradationmeasurementsforinhibitiveindustrialwastewaters
AT toivokuokkanen reliabilityofbiodegradationmeasurementsforinhibitiveindustrialwastewaters
AT ullalassi reliabilityofbiodegradationmeasurementsforinhibitiveindustrialwastewaters