Terpenoids and Steroids from Trichilia Species
The methanol extract of stems of Trichilia claussenii yielded three new sesquiterpenoids: 14-hydroxyelemol, germacra-10(14)-en-9,11,15-triol and germacra-3,10(14)-dien-9,11-diol-4-carbaldehyde. Two known sesquiterpenoids beta-eudesmol, cryptomeridiol and the triterpenoid 22,25-dihydroxy-9beta,19-cyc...
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| Format: | Article |
| Language: | English |
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Sociedade Brasileira de Química
2002-01-01
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| Series: | Journal of the Brazilian Chemical Society |
| Subjects: | |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000300014 |
| _version_ | 1811275349964619776 |
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| author | Pupo Mônica T. Adorno M. Angela T. Vieira Paulo C. Fernandes João B. Silva M. Fátima das G. F. da Pirani José R. |
| author_facet | Pupo Mônica T. Adorno M. Angela T. Vieira Paulo C. Fernandes João B. Silva M. Fátima das G. F. da Pirani José R. |
| author_sort | Pupo Mônica T. |
| collection | DOAJ |
| description | The methanol extract of stems of Trichilia claussenii yielded three new sesquiterpenoids: 14-hydroxyelemol, germacra-10(14)-en-9,11,15-triol and germacra-3,10(14)-dien-9,11-diol-4-carbaldehyde. Two known sesquiterpenoids beta-eudesmol, cryptomeridiol and the triterpenoid 22,25-dihydroxy-9beta,19-cyclolanost-23-en-3-one were also isolated. The dichloromethane extract from the leaves of T. lepidota afforded a mixture of hydrocarbons (C29H60, C31H64 and C33H68), a mixture of the sesquiterpenes caryophyllene and humulene epoxides, spathulenol, and a series of sterols: 24-methylene-12b-hydroxycholesterol, 24-methyl-12beta-hydroxycholest-4-en-3-one, 24-methylene-12beta-hydroxycholest-5-ene-3-palmitate; a mixture of 24-methylenecholesterol, campesterol, stigmasterol and beta-sitosterol; besides alpha-tocoferol and phytol. From the methanol extract it was isolated N-methyl-4-hydroxyproline. The structures of the isolated compounds were determined on the basis of spectroscopic analysis. |
| first_indexed | 2024-04-12T23:36:18Z |
| format | Article |
| id | doaj.art-c183156c43404107b51e18ff054391e8 |
| institution | Directory Open Access Journal |
| issn | 0103-5053 |
| language | English |
| last_indexed | 2024-04-12T23:36:18Z |
| publishDate | 2002-01-01 |
| publisher | Sociedade Brasileira de Química |
| record_format | Article |
| series | Journal of the Brazilian Chemical Society |
| spelling | doaj.art-c183156c43404107b51e18ff054391e82022-12-22T03:12:07ZengSociedade Brasileira de QuímicaJournal of the Brazilian Chemical Society0103-50532002-01-01133382388Terpenoids and Steroids from Trichilia SpeciesPupo Mônica T.Adorno M. Angela T.Vieira Paulo C.Fernandes João B.Silva M. Fátima das G. F. daPirani José R.The methanol extract of stems of Trichilia claussenii yielded three new sesquiterpenoids: 14-hydroxyelemol, germacra-10(14)-en-9,11,15-triol and germacra-3,10(14)-dien-9,11-diol-4-carbaldehyde. Two known sesquiterpenoids beta-eudesmol, cryptomeridiol and the triterpenoid 22,25-dihydroxy-9beta,19-cyclolanost-23-en-3-one were also isolated. The dichloromethane extract from the leaves of T. lepidota afforded a mixture of hydrocarbons (C29H60, C31H64 and C33H68), a mixture of the sesquiterpenes caryophyllene and humulene epoxides, spathulenol, and a series of sterols: 24-methylene-12b-hydroxycholesterol, 24-methyl-12beta-hydroxycholest-4-en-3-one, 24-methylene-12beta-hydroxycholest-5-ene-3-palmitate; a mixture of 24-methylenecholesterol, campesterol, stigmasterol and beta-sitosterol; besides alpha-tocoferol and phytol. From the methanol extract it was isolated N-methyl-4-hydroxyproline. The structures of the isolated compounds were determined on the basis of spectroscopic analysis.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000300014Trichilia clausseniiTrichilia lepidotaMeliaceaesesquiterpenoidscycloartane triterpenoidsteroids |
| spellingShingle | Pupo Mônica T. Adorno M. Angela T. Vieira Paulo C. Fernandes João B. Silva M. Fátima das G. F. da Pirani José R. Terpenoids and Steroids from Trichilia Species Journal of the Brazilian Chemical Society Trichilia claussenii Trichilia lepidota Meliaceae sesquiterpenoids cycloartane triterpenoid steroids |
| title | Terpenoids and Steroids from Trichilia Species |
| title_full | Terpenoids and Steroids from Trichilia Species |
| title_fullStr | Terpenoids and Steroids from Trichilia Species |
| title_full_unstemmed | Terpenoids and Steroids from Trichilia Species |
| title_short | Terpenoids and Steroids from Trichilia Species |
| title_sort | terpenoids and steroids from trichilia species |
| topic | Trichilia claussenii Trichilia lepidota Meliaceae sesquiterpenoids cycloartane triterpenoid steroids |
| url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000300014 |
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