Preliminary assessment of new single and blended volatile binding media for temporary consolidation of cultural heritage

Abstract Volatile Binding Media (VBM) are waxy solids that can be used for temporary consolidation of heritage artifacts and architectural surfaces thanks to their spontaneous sublimation at room temperature. They are used to temporary shelter, consolidate or protect materials during high-risk opera...

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Main Authors: Hamada Sadek Kotb, Andrea Saccani, Jean-Marc Vallet, Elisa Franzoni
Format: Article
Language:English
Published: Nature Portfolio 2024-03-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-024-53828-0
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author Hamada Sadek Kotb
Andrea Saccani
Jean-Marc Vallet
Elisa Franzoni
author_facet Hamada Sadek Kotb
Andrea Saccani
Jean-Marc Vallet
Elisa Franzoni
author_sort Hamada Sadek Kotb
collection DOAJ
description Abstract Volatile Binding Media (VBM) are waxy solids that can be used for temporary consolidation of heritage artifacts and architectural surfaces thanks to their spontaneous sublimation at room temperature. They are used to temporary shelter, consolidate or protect materials during high-risk operation, such as excavation, transportation, water-based treatments, etc. Although they are employed since the 1990s, research focused almost entirely on one of them, cyclododecane (CDD), which is by far the most used in onsite applications. However, CDD exhibits some drawbacks, including a fixed sublimation speed that hardly fits into all the possible applications and climates, hence the development of new VBM is strongly needed. In recent years, a certain attention was addressed to menthol as a possible alternative, but the research on other possible substitutes is still lacking. In this paper, a range of different VBM for temporary consolidation of cultural heritage materials was prepared and investigated, including five pure compounds (CDD, cyclododecanol, cyclododecanone, menthol and camphene) and fifteen mixes. These new materials are expected to provide tunable properties in terms of melting temperatures and sublimation rates, allowing their use in a variety of climatic contexts and applications, and to exhibit better properties for onsite applications compared to CDD, such as lower flash point, lower hazard for conservators’ health and/or higher availability.
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spelling doaj.art-c188142a845d46a7b85ed862c26e38d12024-03-05T18:45:32ZengNature PortfolioScientific Reports2045-23222024-03-0114111710.1038/s41598-024-53828-0Preliminary assessment of new single and blended volatile binding media for temporary consolidation of cultural heritageHamada Sadek Kotb0Andrea Saccani1Jean-Marc Vallet2Elisa Franzoni3Department of Civil, Chemical, Environmental and Materials Engineering, University of BolognaDepartment of Civil, Chemical, Environmental and Materials Engineering, University of BolognaCentre Interdisciplinaire de Conservation Et de Restauration du Patrimoine (CICRP)Department of Civil, Chemical, Environmental and Materials Engineering, University of BolognaAbstract Volatile Binding Media (VBM) are waxy solids that can be used for temporary consolidation of heritage artifacts and architectural surfaces thanks to their spontaneous sublimation at room temperature. They are used to temporary shelter, consolidate or protect materials during high-risk operation, such as excavation, transportation, water-based treatments, etc. Although they are employed since the 1990s, research focused almost entirely on one of them, cyclododecane (CDD), which is by far the most used in onsite applications. However, CDD exhibits some drawbacks, including a fixed sublimation speed that hardly fits into all the possible applications and climates, hence the development of new VBM is strongly needed. In recent years, a certain attention was addressed to menthol as a possible alternative, but the research on other possible substitutes is still lacking. In this paper, a range of different VBM for temporary consolidation of cultural heritage materials was prepared and investigated, including five pure compounds (CDD, cyclododecanol, cyclododecanone, menthol and camphene) and fifteen mixes. These new materials are expected to provide tunable properties in terms of melting temperatures and sublimation rates, allowing their use in a variety of climatic contexts and applications, and to exhibit better properties for onsite applications compared to CDD, such as lower flash point, lower hazard for conservators’ health and/or higher availability.https://doi.org/10.1038/s41598-024-53828-0
spellingShingle Hamada Sadek Kotb
Andrea Saccani
Jean-Marc Vallet
Elisa Franzoni
Preliminary assessment of new single and blended volatile binding media for temporary consolidation of cultural heritage
Scientific Reports
title Preliminary assessment of new single and blended volatile binding media for temporary consolidation of cultural heritage
title_full Preliminary assessment of new single and blended volatile binding media for temporary consolidation of cultural heritage
title_fullStr Preliminary assessment of new single and blended volatile binding media for temporary consolidation of cultural heritage
title_full_unstemmed Preliminary assessment of new single and blended volatile binding media for temporary consolidation of cultural heritage
title_short Preliminary assessment of new single and blended volatile binding media for temporary consolidation of cultural heritage
title_sort preliminary assessment of new single and blended volatile binding media for temporary consolidation of cultural heritage
url https://doi.org/10.1038/s41598-024-53828-0
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