Pozzolanic Reactivity and Hydration Products of Hedenbergite

With hedenbergite, desulfurized gypsum and calcium hydroxide as the materials, this paper studies the pozzolanic reactivity of finely ground hedenbergite and performs XRD, IR, NMR and SEM analysis on the hydration products of the neat paste specimens. The results show that the compressive strength o...

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Main Authors: Biyao Geng, Wen Ni, Jiajia Wang, Xiajie Qiu, Xiaowei Cui, Chao Ren, Siqi Zhang, Yi Xing
Format: Article
Language:English
Published: AIDIC Servizi S.r.l. 2017-12-01
Series:Chemical Engineering Transactions
Online Access:https://www.cetjournal.it/index.php/cet/article/view/956
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author Biyao Geng
Wen Ni
Jiajia Wang
Xiajie Qiu
Xiaowei Cui
Chao Ren
Siqi Zhang
Yi Xing
author_facet Biyao Geng
Wen Ni
Jiajia Wang
Xiajie Qiu
Xiaowei Cui
Chao Ren
Siqi Zhang
Yi Xing
author_sort Biyao Geng
collection DOAJ
description With hedenbergite, desulfurized gypsum and calcium hydroxide as the materials, this paper studies the pozzolanic reactivity of finely ground hedenbergite and performs XRD, IR, NMR and SEM analysis on the hydration products of the neat paste specimens. The results show that the compressive strength of the finely ground neat hedenbergite paste is 5.66MPa and 23.49MPa respectively at the age of 3d and 28d, which indicates that the finely ground hedenbergite has the pozzolanic reactivity, and that its hydration products are mainly C-S-H gel and ettringite. With the curing age, gypsum and silicate minerals are continuously consumed, the bonds connecting the silica tetrahedral network structures rupture, Si4+ is replaced by Al3+ disorderly, and the polymerization of the whole network is reduced, enhancing the activity and gradually increasing the hydration products.
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spelling doaj.art-c1c1e9b9a539493f8de1f159211bc4962022-12-21T17:43:53ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162017-12-016210.3303/CET1762158Pozzolanic Reactivity and Hydration Products of HedenbergiteBiyao GengWen NiJiajia WangXiajie QiuXiaowei CuiChao RenSiqi ZhangYi XingWith hedenbergite, desulfurized gypsum and calcium hydroxide as the materials, this paper studies the pozzolanic reactivity of finely ground hedenbergite and performs XRD, IR, NMR and SEM analysis on the hydration products of the neat paste specimens. The results show that the compressive strength of the finely ground neat hedenbergite paste is 5.66MPa and 23.49MPa respectively at the age of 3d and 28d, which indicates that the finely ground hedenbergite has the pozzolanic reactivity, and that its hydration products are mainly C-S-H gel and ettringite. With the curing age, gypsum and silicate minerals are continuously consumed, the bonds connecting the silica tetrahedral network structures rupture, Si4+ is replaced by Al3+ disorderly, and the polymerization of the whole network is reduced, enhancing the activity and gradually increasing the hydration products.https://www.cetjournal.it/index.php/cet/article/view/956
spellingShingle Biyao Geng
Wen Ni
Jiajia Wang
Xiajie Qiu
Xiaowei Cui
Chao Ren
Siqi Zhang
Yi Xing
Pozzolanic Reactivity and Hydration Products of Hedenbergite
Chemical Engineering Transactions
title Pozzolanic Reactivity and Hydration Products of Hedenbergite
title_full Pozzolanic Reactivity and Hydration Products of Hedenbergite
title_fullStr Pozzolanic Reactivity and Hydration Products of Hedenbergite
title_full_unstemmed Pozzolanic Reactivity and Hydration Products of Hedenbergite
title_short Pozzolanic Reactivity and Hydration Products of Hedenbergite
title_sort pozzolanic reactivity and hydration products of hedenbergite
url https://www.cetjournal.it/index.php/cet/article/view/956
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AT xiajieqiu pozzolanicreactivityandhydrationproductsofhedenbergite
AT xiaoweicui pozzolanicreactivityandhydrationproductsofhedenbergite
AT chaoren pozzolanicreactivityandhydrationproductsofhedenbergite
AT siqizhang pozzolanicreactivityandhydrationproductsofhedenbergite
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