Thermocatalytic Hydrogen Production Through Decomposition of Methane-A Review

Consumption of fossil fuels, especially in transport and energy-dependent sectors, has led to large greenhouse gas production. Hydrogen is an exciting energy source that can serve our energy purposes and decrease toxic waste production. Decomposition of methane yields hydrogen devoid of COx componen...

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Main Authors: Gowhar A. Naikoo, Fareeha Arshad, Israr U. Hassan, Musallam A. Tabook, Mona Z. Pedram, Mujahid Mustaqeem, Hassina Tabassum, Waqar Ahmed, Mashallah Rezakazemi
Format: Article
Language:English
Published: Frontiers Media S.A. 2021-10-01
Series:Frontiers in Chemistry
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2021.736801/full
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author Gowhar A. Naikoo
Fareeha Arshad
Israr U. Hassan
Musallam A. Tabook
Mona Z. Pedram
Mujahid Mustaqeem
Mujahid Mustaqeem
Hassina Tabassum
Waqar Ahmed
Mashallah Rezakazemi
author_facet Gowhar A. Naikoo
Fareeha Arshad
Israr U. Hassan
Musallam A. Tabook
Mona Z. Pedram
Mujahid Mustaqeem
Mujahid Mustaqeem
Hassina Tabassum
Waqar Ahmed
Mashallah Rezakazemi
author_sort Gowhar A. Naikoo
collection DOAJ
description Consumption of fossil fuels, especially in transport and energy-dependent sectors, has led to large greenhouse gas production. Hydrogen is an exciting energy source that can serve our energy purposes and decrease toxic waste production. Decomposition of methane yields hydrogen devoid of COx components, thereby aiding as an eco-friendly approach towards large-scale hydrogen production. This review article is focused on hydrogen production through thermocatalytic methane decomposition (TMD) for hydrogen production. The thermodynamics of this approach has been highlighted. Various methods of hydrogen production from fossil fuels and renewable resources were discussed. Methods including steam methane reforming, partial oxidation of methane, auto thermal reforming, direct biomass gasification, thermal water splitting, methane pyrolysis, aqueous reforming, and coal gasification have been reported in this article. A detailed overview of the different types of catalysts available, the reasons behind their deactivation, and their possible regeneration methods were discussed. Finally, we presented the challenges and future perspectives for hydrogen production via TMD. This review concluded that among all catalysts, nickel, ruthenium and platinum-based catalysts show the highest activity and catalytic efficiency and gave carbon-free hydrogen products during the TMD process. However, their rapid deactivation at high temperatures still needs the attention of the scientific community.
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spelling doaj.art-c1c7793d4e64422b8c4bc154cdb8525c2022-12-21T19:26:44ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462021-10-01910.3389/fchem.2021.736801736801Thermocatalytic Hydrogen Production Through Decomposition of Methane-A ReviewGowhar A. Naikoo0Fareeha Arshad1Israr U. Hassan2Musallam A. Tabook3Mona Z. Pedram4Mujahid Mustaqeem5Mujahid Mustaqeem6Hassina Tabassum7Waqar Ahmed8Mashallah Rezakazemi9Department of Mathematics and Sciences, College of Arts and Applied Sciences, Dhofar University, Salalah, OmanDepartment of Biochemistry, Aligarh Muslim University, Aligarh, IndiaCollege of Engineering, Dhofar University, Salalah, OmanDepartment of Mathematics and Sciences, College of Arts and Applied Sciences, Dhofar University, Salalah, OmanMechanical Engineering-Energy Division, K. N. Toosi University of Technology, Tehran, IranInstitute of Physics, Academia Sinica, Taipei, TaiwanDepartment of Chemistry, National Taiwan University, Taipei, TaiwanDepartment of Chemical and Biological Engineering, State University of New York at Buffalo, Buffalo, NY, United StatesSchool of Mathematics and Physics, College of Science, University of Lincoln, Lincoln, United KingdomSchool of Mathematics and Physics, College of Science, University of Lincoln, Lincoln, United KingdomConsumption of fossil fuels, especially in transport and energy-dependent sectors, has led to large greenhouse gas production. Hydrogen is an exciting energy source that can serve our energy purposes and decrease toxic waste production. Decomposition of methane yields hydrogen devoid of COx components, thereby aiding as an eco-friendly approach towards large-scale hydrogen production. This review article is focused on hydrogen production through thermocatalytic methane decomposition (TMD) for hydrogen production. The thermodynamics of this approach has been highlighted. Various methods of hydrogen production from fossil fuels and renewable resources were discussed. Methods including steam methane reforming, partial oxidation of methane, auto thermal reforming, direct biomass gasification, thermal water splitting, methane pyrolysis, aqueous reforming, and coal gasification have been reported in this article. A detailed overview of the different types of catalysts available, the reasons behind their deactivation, and their possible regeneration methods were discussed. Finally, we presented the challenges and future perspectives for hydrogen production via TMD. This review concluded that among all catalysts, nickel, ruthenium and platinum-based catalysts show the highest activity and catalytic efficiency and gave carbon-free hydrogen products during the TMD process. However, their rapid deactivation at high temperatures still needs the attention of the scientific community.https://www.frontiersin.org/articles/10.3389/fchem.2021.736801/fullhydrogen productionthermocatalytic methane decompositionenergycatalystscatalytic regeneration
spellingShingle Gowhar A. Naikoo
Fareeha Arshad
Israr U. Hassan
Musallam A. Tabook
Mona Z. Pedram
Mujahid Mustaqeem
Mujahid Mustaqeem
Hassina Tabassum
Waqar Ahmed
Mashallah Rezakazemi
Thermocatalytic Hydrogen Production Through Decomposition of Methane-A Review
Frontiers in Chemistry
hydrogen production
thermocatalytic methane decomposition
energy
catalysts
catalytic regeneration
title Thermocatalytic Hydrogen Production Through Decomposition of Methane-A Review
title_full Thermocatalytic Hydrogen Production Through Decomposition of Methane-A Review
title_fullStr Thermocatalytic Hydrogen Production Through Decomposition of Methane-A Review
title_full_unstemmed Thermocatalytic Hydrogen Production Through Decomposition of Methane-A Review
title_short Thermocatalytic Hydrogen Production Through Decomposition of Methane-A Review
title_sort thermocatalytic hydrogen production through decomposition of methane a review
topic hydrogen production
thermocatalytic methane decomposition
energy
catalysts
catalytic regeneration
url https://www.frontiersin.org/articles/10.3389/fchem.2021.736801/full
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