Local transformation of the electronic structure and generation of free carriers in cuprates and ferropnictides under heterovalent and isovalent doping

We have previously shown that most of the anomalies in the superconducting characteristics of cuprates and ferropnictides observed at dopant concentrations within the superconducting dome, as well as the position of the domes in the phase diagrams, do not require knowledge of the details of their el...

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Main Authors: Kirill Mitsen, Olga Ivanenko
Format: Article
Language:English
Published: Elsevier 2022-07-01
Series:Results in Physics
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S221137972200300X
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author Kirill Mitsen
Olga Ivanenko
author_facet Kirill Mitsen
Olga Ivanenko
author_sort Kirill Mitsen
collection DOAJ
description We have previously shown that most of the anomalies in the superconducting characteristics of cuprates and ferropnictides observed at dopant concentrations within the superconducting dome, as well as the position of the domes in the phase diagrams, do not require knowledge of the details of their electronic structure for explanation, but can be understood and calculated with high accuracy within the framework of a simple model describing the cluster structure of the superconducting phase. This fact suggests a change in the paradigm that forms our understanding of HTSC. In this paper, we propose a unified view on the transformation of the electronic structure of cuprates and ferropnictides upon heterovalent and isovalent doping, based on the assumption of self-localization of doped carriers. In this representation, in undoped cuprates and ferropnictides, which initially have different electronic structures (Mott insulator and semimetal), local doping forms percolation clusters with the same electronic structure of a self-doped excitonic insulator where a specific mechanism of superconducting pairing is implemented, which is genetically inherent in such a system. The proposed model includes a mechanism for generating additional free carriers under heterovalent and isovalent doping and makes it possible to predict their sign, which, in the general case, does not coincide with the sign of doped carriers.
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spelling doaj.art-c1dcaeba8a0c47cfb5e60783ade860362022-12-22T00:39:48ZengElsevierResults in Physics2211-37972022-07-0138105577Local transformation of the electronic structure and generation of free carriers in cuprates and ferropnictides under heterovalent and isovalent dopingKirill Mitsen0Olga Ivanenko1Corresponding author.; Lebedev Physical Institute, Leninsky pr., 53, Moscow 119991, RussiaLebedev Physical Institute, Leninsky pr., 53, Moscow 119991, RussiaWe have previously shown that most of the anomalies in the superconducting characteristics of cuprates and ferropnictides observed at dopant concentrations within the superconducting dome, as well as the position of the domes in the phase diagrams, do not require knowledge of the details of their electronic structure for explanation, but can be understood and calculated with high accuracy within the framework of a simple model describing the cluster structure of the superconducting phase. This fact suggests a change in the paradigm that forms our understanding of HTSC. In this paper, we propose a unified view on the transformation of the electronic structure of cuprates and ferropnictides upon heterovalent and isovalent doping, based on the assumption of self-localization of doped carriers. In this representation, in undoped cuprates and ferropnictides, which initially have different electronic structures (Mott insulator and semimetal), local doping forms percolation clusters with the same electronic structure of a self-doped excitonic insulator where a specific mechanism of superconducting pairing is implemented, which is genetically inherent in such a system. The proposed model includes a mechanism for generating additional free carriers under heterovalent and isovalent doping and makes it possible to predict their sign, which, in the general case, does not coincide with the sign of doped carriers.http://www.sciencedirect.com/science/article/pii/S221137972200300XHigh temperature superconductorsCupratesFerropnictidesExcitonic insulatorIsovalent dopingHeterovalent doping
spellingShingle Kirill Mitsen
Olga Ivanenko
Local transformation of the electronic structure and generation of free carriers in cuprates and ferropnictides under heterovalent and isovalent doping
Results in Physics
High temperature superconductors
Cuprates
Ferropnictides
Excitonic insulator
Isovalent doping
Heterovalent doping
title Local transformation of the electronic structure and generation of free carriers in cuprates and ferropnictides under heterovalent and isovalent doping
title_full Local transformation of the electronic structure and generation of free carriers in cuprates and ferropnictides under heterovalent and isovalent doping
title_fullStr Local transformation of the electronic structure and generation of free carriers in cuprates and ferropnictides under heterovalent and isovalent doping
title_full_unstemmed Local transformation of the electronic structure and generation of free carriers in cuprates and ferropnictides under heterovalent and isovalent doping
title_short Local transformation of the electronic structure and generation of free carriers in cuprates and ferropnictides under heterovalent and isovalent doping
title_sort local transformation of the electronic structure and generation of free carriers in cuprates and ferropnictides under heterovalent and isovalent doping
topic High temperature superconductors
Cuprates
Ferropnictides
Excitonic insulator
Isovalent doping
Heterovalent doping
url http://www.sciencedirect.com/science/article/pii/S221137972200300X
work_keys_str_mv AT kirillmitsen localtransformationoftheelectronicstructureandgenerationoffreecarriersincupratesandferropnictidesunderheterovalentandisovalentdoping
AT olgaivanenko localtransformationoftheelectronicstructureandgenerationoffreecarriersincupratesandferropnictidesunderheterovalentandisovalentdoping