N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-dihydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide
The molecule of the title compound, C42H32N6O, is built up from one pyrazole ring linked to three phenyl rings and to an approximately planar [maximum deviation = 0.0455 (15) Å] quinoxaline system connected to a phenylbenzohydrazide group. The pyrazole ring assumes an en...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813020035 |
| _version_ | 1818500265914925056 |
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| author | Lahcen El Ammari El Mokhtar Essassi Khalid Karrouchi Youssef Ramli |
| author_facet | Lahcen El Ammari El Mokhtar Essassi Khalid Karrouchi Youssef Ramli |
| author_sort | Lahcen El Ammari |
| collection | DOAJ |
| description | The molecule of the title compound, C42H32N6O, is built up from one pyrazole ring linked to three phenyl rings and to an approximately planar [maximum deviation = 0.0455 (15) Å] quinoxaline system connected to a phenylbenzohydrazide group. The pyrazole ring assumes an envelope conformation, the C atom attached to the quinoxalin-3-yl ring system being the flap atom. The dihedral angle between the two phenyl rings of the phenylbenzohydrazide group is of 58.27 (9)°. The mean plane through the pyrazole ring is nearly perpendicular to the quinoxaline ring system and to the phenyl ring attached to the opposite side, forming dihedral angles of 82.58 (7) and 87.29 (9)°, respectively. An intramolecular C—H...O hydrogen bond is present. In the crystal, molecules are linked by pairs of N—H...N hydrogen bonds, forming inversion dimers, which are further connected by C—H...N hydrogen bonds into chains parallel to the b axis. |
| first_indexed | 2024-12-10T20:40:25Z |
| format | Article |
| id | doaj.art-c1f13c9e5dea42e38979ec41db28aa56 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T20:40:25Z |
| publishDate | 2013-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c1f13c9e5dea42e38979ec41db28aa562022-12-22T01:34:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-08-01698o1320o132110.1107/S1600536813020035N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-dihydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazideLahcen El AmmariEl Mokhtar EssassiKhalid KarrouchiYoussef RamliThe molecule of the title compound, C42H32N6O, is built up from one pyrazole ring linked to three phenyl rings and to an approximately planar [maximum deviation = 0.0455 (15) Å] quinoxaline system connected to a phenylbenzohydrazide group. The pyrazole ring assumes an envelope conformation, the C atom attached to the quinoxalin-3-yl ring system being the flap atom. The dihedral angle between the two phenyl rings of the phenylbenzohydrazide group is of 58.27 (9)°. The mean plane through the pyrazole ring is nearly perpendicular to the quinoxaline ring system and to the phenyl ring attached to the opposite side, forming dihedral angles of 82.58 (7) and 87.29 (9)°, respectively. An intramolecular C—H...O hydrogen bond is present. In the crystal, molecules are linked by pairs of N—H...N hydrogen bonds, forming inversion dimers, which are further connected by C—H...N hydrogen bonds into chains parallel to the b axis.http://scripts.iucr.org/cgi-bin/paper?S1600536813020035 |
| spellingShingle | Lahcen El Ammari El Mokhtar Essassi Khalid Karrouchi Youssef Ramli N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-dihydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide Acta Crystallographica Section E |
| title | N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-dihydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide |
| title_full | N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-dihydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide |
| title_fullStr | N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-dihydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide |
| title_full_unstemmed | N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-dihydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide |
| title_short | N′-Phenyl-N′-[3-(2,4,5-triphenyl-2,5-dihydro-1H-pyrazol-3-yl)quinoxalin-2-yl]benzohydrazide |
| title_sort | n 8242 phenyl n 8242 3 2 4 5 triphenyl 2 5 dihydro 1h pyrazol 3 yl quinoxalin 2 yl benzohydrazide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813020035 |
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