Removal of ciprofloxacin and indigo carmine from water by carbon nanotubes fabricated from a low-cost precursor: Solution parameters and recyclability
Water contamination is one of humanity's threatening problems. This study synthesized pristine carbon nanotubes (PCNTs) from commercial gasoline (CG) as a relatively low-cost precursor. 200 mL of CG yielded an average CNTs mass of 26.23 ± 0.97 g. The functionalized carbon nanotubes (FCNTs) were...
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Elsevier
2023-02-01
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Series: | Ain Shams Engineering Journal |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2090447922001551 |
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author | Mohamed R. Elamin Babiker Y. Abdulkhair Amin O. Elzupir |
author_facet | Mohamed R. Elamin Babiker Y. Abdulkhair Amin O. Elzupir |
author_sort | Mohamed R. Elamin |
collection | DOAJ |
description | Water contamination is one of humanity's threatening problems. This study synthesized pristine carbon nanotubes (PCNTs) from commercial gasoline (CG) as a relatively low-cost precursor. 200 mL of CG yielded an average CNTs mass of 26.23 ± 0.97 g. The functionalized carbon nanotubes (FCNTs) were produced by acid-treatment of PCNTs, and the yield was 93.3%. The surface area of PCNTs and FCNTs was 29.69 and 66.16 m2 g−1. The FTIR and EDX indicated an introduction of oxygenated groups on the FCNTs. The FCNTs removed ciprofloxacin (CIP) and indigo carmine (IC) from water with an adsorption capacity of 95.5 and 93.0 mg g−1, respectively, while the PCNTs showed 78.9 and 63.7 mg g−1, respectively. The pH 4.0 and 6.0 suited the adsorption of CIP and IC on both sorbents. The adsorption processes for all sorbent-sorbate systems were spontaneous and exothermic. The FCNTs and PCNTs recyclability showed an average efficiency of 90.0%. |
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id | doaj.art-c1fcd8e53a7d4d269d15e4d882db6676 |
institution | Directory Open Access Journal |
issn | 2090-4479 |
language | English |
last_indexed | 2024-04-10T20:57:03Z |
publishDate | 2023-02-01 |
publisher | Elsevier |
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series | Ain Shams Engineering Journal |
spelling | doaj.art-c1fcd8e53a7d4d269d15e4d882db66762023-01-23T04:08:24ZengElsevierAin Shams Engineering Journal2090-44792023-02-01141101844Removal of ciprofloxacin and indigo carmine from water by carbon nanotubes fabricated from a low-cost precursor: Solution parameters and recyclabilityMohamed R. Elamin0Babiker Y. Abdulkhair1Amin O. Elzupir2Imam Mohammad Ibn Saud Islamic University (IMSIU), College of Science, Chemistry Department, Riyadh, Saudi Arabia; Industrial Research and Consultancy Center (IRCC), Khartoum North, SudanImam Mohammad Ibn Saud Islamic University (IMSIU), College of Science, Chemistry Department, Riyadh, Saudi Arabia; Sudan University of Science and Technology (SUST), College of Science, Chemistry Department, Khartoum, Sudan; Corresponding author at: Chemistry Department – College of Science, Imam Mohammad Ibn Saud Islamic University, P.O. Box 90905, Riyadh 11623, Saudi Arabia.Deanship of Scientific Research, Imam Mohammad Ibn Saud Islamic University (IMSIU), Saudi ArabiaWater contamination is one of humanity's threatening problems. This study synthesized pristine carbon nanotubes (PCNTs) from commercial gasoline (CG) as a relatively low-cost precursor. 200 mL of CG yielded an average CNTs mass of 26.23 ± 0.97 g. The functionalized carbon nanotubes (FCNTs) were produced by acid-treatment of PCNTs, and the yield was 93.3%. The surface area of PCNTs and FCNTs was 29.69 and 66.16 m2 g−1. The FTIR and EDX indicated an introduction of oxygenated groups on the FCNTs. The FCNTs removed ciprofloxacin (CIP) and indigo carmine (IC) from water with an adsorption capacity of 95.5 and 93.0 mg g−1, respectively, while the PCNTs showed 78.9 and 63.7 mg g−1, respectively. The pH 4.0 and 6.0 suited the adsorption of CIP and IC on both sorbents. The adsorption processes for all sorbent-sorbate systems were spontaneous and exothermic. The FCNTs and PCNTs recyclability showed an average efficiency of 90.0%.http://www.sciencedirect.com/science/article/pii/S2090447922001551Carbon nanotubesGasoline fuelHigh yield methodCiprofloxacinIndigo carmine |
spellingShingle | Mohamed R. Elamin Babiker Y. Abdulkhair Amin O. Elzupir Removal of ciprofloxacin and indigo carmine from water by carbon nanotubes fabricated from a low-cost precursor: Solution parameters and recyclability Ain Shams Engineering Journal Carbon nanotubes Gasoline fuel High yield method Ciprofloxacin Indigo carmine |
title | Removal of ciprofloxacin and indigo carmine from water by carbon nanotubes fabricated from a low-cost precursor: Solution parameters and recyclability |
title_full | Removal of ciprofloxacin and indigo carmine from water by carbon nanotubes fabricated from a low-cost precursor: Solution parameters and recyclability |
title_fullStr | Removal of ciprofloxacin and indigo carmine from water by carbon nanotubes fabricated from a low-cost precursor: Solution parameters and recyclability |
title_full_unstemmed | Removal of ciprofloxacin and indigo carmine from water by carbon nanotubes fabricated from a low-cost precursor: Solution parameters and recyclability |
title_short | Removal of ciprofloxacin and indigo carmine from water by carbon nanotubes fabricated from a low-cost precursor: Solution parameters and recyclability |
title_sort | removal of ciprofloxacin and indigo carmine from water by carbon nanotubes fabricated from a low cost precursor solution parameters and recyclability |
topic | Carbon nanotubes Gasoline fuel High yield method Ciprofloxacin Indigo carmine |
url | http://www.sciencedirect.com/science/article/pii/S2090447922001551 |
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