Magnetism and Transport Properties of EuCdBi<sub>2</sub> with Bi Square Net

We report a possible coexistence of nontrivial topology and antiferromagnetism in the newly discovered compounds EuCdBi<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2&l...

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Bibliographic Details
Main Authors: Yi Liu, Jing Li, Shi-Jie Song, Wu-Zhang Yang, Jin-Ke Bao, Wen-He Jiao, Xiao-Feng Xu, Zhi Ren, Guang-Han Cao
Format: Article
Language:English
Published: MDPI AG 2023-04-01
Series:Crystals
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Online Access:https://www.mdpi.com/2073-4352/13/4/654
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Summary:We report a possible coexistence of nontrivial topology and antiferromagnetism in the newly discovered compounds EuCdBi<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula>, with magnetic Eu layer locating above and below Bi square net. The X-ray diffraction on single crystals and powder indicats that this 112-type material crystalizes in space group of <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mi>I</mi><mn>4</mn><mo>/</mo><mi>m</mi><mi>m</mi><mi>m</mi></mrow></semantics></math></inline-formula>, the same as SrMnBi<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula> and EuMnBi<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula>. Our combined measurements of magnetization, electrical transport and specific heat consistently reveal antiferromagnetic (AFM) transition of Eu<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msup><mrow></mrow><mrow><mn>2</mn><mo>+</mo></mrow></msup></semantics></math></inline-formula> moments at <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mi>T</mi><mi>N</mi></msub></semantics></math></inline-formula> = 20 K. The Eu moments are not saturated under a field of 7 T at 1.8 K. The anisotropic susceptibility suggests the Eu moments lie in the <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mi>a</mi><mi>b</mi></mrow></semantics></math></inline-formula> plane, and a metamagnetic (MM) transition is observed near 1 T below <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mi>T</mi><mi>N</mi></msub></semantics></math></inline-formula>. Large positive magnetoresistance (MR) present for both <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mi>H</mi><mo> </mo><mo>‖</mo><mo> </mo><mi>a</mi><mi>b</mi></mrow></semantics></math></inline-formula> and <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mi>H</mi><mo> </mo><mo>‖</mo><mo> </mo><mi>c</mi></mrow></semantics></math></inline-formula>, which are considered to contain part contributions from Dirac bands. Hall measurements show the electron-hole compensation effect is prominent above 100 K, with a crossover of Hall resistance from negative to positive values at ∼150 K. The fitted mobility of electrons is as high as 3250 cm<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msup><mrow></mrow><mn>2</mn></msup></semantics></math></inline-formula> V<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msup><mrow></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup></semantics></math></inline-formula> S<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msup><mrow></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup></semantics></math></inline-formula> at 1.8 K. Interestingly, the rapid increase of carrier density and suppression of mobility appear at around <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mi>T</mi><mi>N</mi></msub></semantics></math></inline-formula>, indicating non-negligible interaction between Eu moments and electron/hole bands. EuCdBi<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msub><mrow></mrow><mn>2</mn></msub></semantics></math></inline-formula> may provide a new platform to investigate the interplay of topological bands and antiferromagnetic order.
ISSN:2073-4352