Performance of coagulation-flocculation followed by ultra-violet/ultrasound activated persulfate/hydrogen peroxide for landfill leachate treatment

The advanced oxidation processes (AOPs) were assessed for enhancing the treatment of stabilized landfill leachate previously pretreated using coagulation-flocculation (C-F).The primary treatment by C-F using 20 g.L−1 of FeCl3 (optimal coagulant dosage) has removed 71% of chemical oxidation demand (C...

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Main Authors: Hamza Bellouk, Imane El Mrabet, Karim Tanji, Mostafa Nawdali, Mourad Benzina, Mabrouk Eloussaief, Hicham Zaitan
Format: Article
Language:English
Published: Elsevier 2022-09-01
Series:Scientific African
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2468227622002198
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author Hamza Bellouk
Imane El Mrabet
Karim Tanji
Mostafa Nawdali
Mourad Benzina
Mabrouk Eloussaief
Hicham Zaitan
author_facet Hamza Bellouk
Imane El Mrabet
Karim Tanji
Mostafa Nawdali
Mourad Benzina
Mabrouk Eloussaief
Hicham Zaitan
author_sort Hamza Bellouk
collection DOAJ
description The advanced oxidation processes (AOPs) were assessed for enhancing the treatment of stabilized landfill leachate previously pretreated using coagulation-flocculation (C-F).The primary treatment by C-F using 20 g.L−1 of FeCl3 (optimal coagulant dosage) has removed 71% of chemical oxidation demand (COD) and 95% of turbidity. Thereafter, secondary treatment was applied using different system combinations of two inorganic oxidants (potassium persulfate, K2S2O8 (PS) (1500 mg. L−1) and hydrogen peroxide, H2O2 (1327 mg. L−1)) that were used simultaneously or separately with UV-A and/or ultrasonic (US) irradiations.The obtained results indicated that the oxidation systems with the presence of H2O2 were more efficient than other systems. Indeed, the H2O2-PS-US-UV-A system reached the highest COD removal of 89%, while PS-based combinations were the less efficient (PS alone 19%, PS-UV-A 22%, PS-US 32%, and PS-US-UV-A 35%).Hence, the sequential process including C-F as pretreatment followed by the application of the H2O2-PS-US-UV-A system has proven high efficiency for COD removal, absorbance at 254 nm, and color number of 97%, 97%, and 99%, respectively.The sequential application of AOPs after preliminary treatment using coagulation-flocculation is a promising alternative to reducing the high organic load of stabilized leachate and that could be largely applied to other types of effluents.
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spelling doaj.art-c204ffe2d1f747b483ac73a5b2b058702022-12-22T04:07:18ZengElsevierScientific African2468-22762022-09-0117e01312Performance of coagulation-flocculation followed by ultra-violet/ultrasound activated persulfate/hydrogen peroxide for landfill leachate treatmentHamza Bellouk0Imane El Mrabet1Karim Tanji2Mostafa Nawdali3Mourad Benzina4Mabrouk Eloussaief5Hicham Zaitan6Processes, Materials and Environment Laboratory (LPME), Faculty of Sciences and Technology of Fez, Sidi Mohamed Ben Abdellah University, BP 2202, MoroccoDepartment of Physics-Chemistry, Polydisciplinary Faculty of Ouarzazate, University of Ibn Zohr, Morocco; Corresponding authors.Independent Scientist, Sidi Mohamed Ben Abdellah University, Fez, MoroccoProcesses, Materials and Environment Laboratory (LPME), Faculty of Sciences and Technology of Fez, Sidi Mohamed Ben Abdellah University, BP 2202, MoroccoLaboratory ''Water, Energy and Environment'' (LR3E), National Engineering School of Sfax, University of Sfax, TunisiaLaboratory ''Water, Energy and Environment'' (LR3E), National Engineering School of Sfax, University of Sfax, TunisiaProcesses, Materials and Environment Laboratory (LPME), Faculty of Sciences and Technology of Fez, Sidi Mohamed Ben Abdellah University, BP 2202, Morocco; Corresponding authors.The advanced oxidation processes (AOPs) were assessed for enhancing the treatment of stabilized landfill leachate previously pretreated using coagulation-flocculation (C-F).The primary treatment by C-F using 20 g.L−1 of FeCl3 (optimal coagulant dosage) has removed 71% of chemical oxidation demand (COD) and 95% of turbidity. Thereafter, secondary treatment was applied using different system combinations of two inorganic oxidants (potassium persulfate, K2S2O8 (PS) (1500 mg. L−1) and hydrogen peroxide, H2O2 (1327 mg. L−1)) that were used simultaneously or separately with UV-A and/or ultrasonic (US) irradiations.The obtained results indicated that the oxidation systems with the presence of H2O2 were more efficient than other systems. Indeed, the H2O2-PS-US-UV-A system reached the highest COD removal of 89%, while PS-based combinations were the less efficient (PS alone 19%, PS-UV-A 22%, PS-US 32%, and PS-US-UV-A 35%).Hence, the sequential process including C-F as pretreatment followed by the application of the H2O2-PS-US-UV-A system has proven high efficiency for COD removal, absorbance at 254 nm, and color number of 97%, 97%, and 99%, respectively.The sequential application of AOPs after preliminary treatment using coagulation-flocculation is a promising alternative to reducing the high organic load of stabilized leachate and that could be largely applied to other types of effluents.http://www.sciencedirect.com/science/article/pii/S2468227622002198Landfill leachate treatmentUltrasound-activated persulfateUltraviolet irradiationHydroxyl radicalsOrganic contaminants removal
spellingShingle Hamza Bellouk
Imane El Mrabet
Karim Tanji
Mostafa Nawdali
Mourad Benzina
Mabrouk Eloussaief
Hicham Zaitan
Performance of coagulation-flocculation followed by ultra-violet/ultrasound activated persulfate/hydrogen peroxide for landfill leachate treatment
Scientific African
Landfill leachate treatment
Ultrasound-activated persulfate
Ultraviolet irradiation
Hydroxyl radicals
Organic contaminants removal
title Performance of coagulation-flocculation followed by ultra-violet/ultrasound activated persulfate/hydrogen peroxide for landfill leachate treatment
title_full Performance of coagulation-flocculation followed by ultra-violet/ultrasound activated persulfate/hydrogen peroxide for landfill leachate treatment
title_fullStr Performance of coagulation-flocculation followed by ultra-violet/ultrasound activated persulfate/hydrogen peroxide for landfill leachate treatment
title_full_unstemmed Performance of coagulation-flocculation followed by ultra-violet/ultrasound activated persulfate/hydrogen peroxide for landfill leachate treatment
title_short Performance of coagulation-flocculation followed by ultra-violet/ultrasound activated persulfate/hydrogen peroxide for landfill leachate treatment
title_sort performance of coagulation flocculation followed by ultra violet ultrasound activated persulfate hydrogen peroxide for landfill leachate treatment
topic Landfill leachate treatment
Ultrasound-activated persulfate
Ultraviolet irradiation
Hydroxyl radicals
Organic contaminants removal
url http://www.sciencedirect.com/science/article/pii/S2468227622002198
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