Mononuclear Dysprosium(III) Complexes with Triphenylphosphine Oxide Ligands: Controlling the Coordination Environment and Magnetic Anisotropy

Mononuclear Dysprosium(III) Complexes with Triphenylphosphine Oxide Ligands: Controlling the Coordination Environment and Magnetic Anisotropy

We report the synthesis, structural and magnetic characterization of five mononuclear DyIII ion complexes using triphenylphosphine oxide as a monodentate ligand. They have formulae [DyIII(OPPh3)3(NO3)3] (1), [DyIII(OPPh3)4(NO3)2](NO3) (2), [DyIII(OPPh3)3Cl3] (3), [DyIII(OPPh3)4Cl2]Cl (4) and [DyIII(...

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Bibliographic Details
Main Authors: Stuart K. Langley, Kuduva R. Vignesh, Kerey Holton, Sophie Benjamin, Gary B. Hix, Wasinee Phonsri, Boujemaa Moubaraki, Keith S. Murray, Gopalan Rajaraman
Format: Article
Language:English
Published: MDPI AG 2018-06-01
Series:Inorganics
Subjects:
single molecule magnets
single ion magnets
phosphine oxide complexes
lanthanide SMMs
magnetic anisotropy
ab initio calculations
Online Access:http://www.mdpi.com/2304-6740/6/2/61

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