Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, Romania
This study aims to determine the spatial distribution of some potentially toxic elements, namely As, Cd, Co, Cr, Cu, Ni, Pb, Sn and Zn within riverbed sediments of Izvorul Roşu and Izvorul Băilor rivers with their tributaries (Rodna mining area) from Rodna Mountains and to assess the contamination d...
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Format: | Article |
Language: | English |
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Alexandru Ioan Cuza University Press, Iasi, Romania
2023-06-01
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Series: | Present Environment and Sustainable Development |
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Online Access: | http://www.pesd.ro/articole/nr.17/nr.1/pesd2023171011.pdf |
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author | Aurelia Andreea SCARLAT Ovidiu Gabriel IANCU Ciprian CHELARIU Sergiu LOGHIN Valentin Nicolae COȚAC Iuliana BULIGA Andreea Elena MAFTEI |
author_facet | Aurelia Andreea SCARLAT Ovidiu Gabriel IANCU Ciprian CHELARIU Sergiu LOGHIN Valentin Nicolae COȚAC Iuliana BULIGA Andreea Elena MAFTEI |
author_sort | Aurelia Andreea SCARLAT |
collection | DOAJ |
description | This study aims to determine the spatial distribution of some potentially toxic elements, namely As, Cd, Co, Cr, Cu, Ni, Pb, Sn and Zn within riverbed sediments of Izvorul Roşu and Izvorul Băilor rivers with their tributaries (Rodna mining area) from Rodna Mountains and to assess the contamination degree of sediments using some widely used pollution indices. The concentrations of the elements were obtained through ICP-MS analysis using Four-Acid Digestion method and the results show an average of 56.21 mg·kg−1 for As, 1.66 mg·kg−1 for Cd, 27.50 mg·kg−1 for Co, 86.67 mg·kg−1 for Cr, 38.62 mg·kg−1 for Cu, 45.46 mg·kg−1 for Ni, 205.25 mg·kg−1 for Pb, 2.65 mg·kg−1 for Sn and 449.70 mg·kg−1 for Zn. The geochemical background was calculated using the Median±2 MAD procedure. From the evaluation of the sediment’s pollution indices, contamination factor (CF), enrichment factor (EF), pollution load index (PLI), ecological risk index (RI), geoaccumulation index (Igeo) it can be seen that the studied river sediments in most cases, are either not contaminated or slightly contaminated. However, there are a few samples with moderate contamination by As, Cd, Pb and Zn due to former mining activities. |
first_indexed | 2024-03-12T16:58:05Z |
format | Article |
id | doaj.art-c2410f2744d94340b24f6801a91a46a5 |
institution | Directory Open Access Journal |
issn | 2284-7820 |
language | English |
last_indexed | 2024-03-12T16:58:05Z |
publishDate | 2023-06-01 |
publisher | Alexandru Ioan Cuza University Press, Iasi, Romania |
record_format | Article |
series | Present Environment and Sustainable Development |
spelling | doaj.art-c2410f2744d94340b24f6801a91a46a52023-08-07T21:33:42ZengAlexandru Ioan Cuza University Press, Iasi, RomaniaPresent Environment and Sustainable Development2284-78202023-06-0117115516910.47743/pesd2023171011Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, RomaniaAurelia Andreea SCARLAT0https://orcid.org/0009-0009-9055-6654Ovidiu Gabriel IANCU1https://orcid.org/0000-0003-1844-7102Ciprian CHELARIU2https://orcid.org/0000-0001-7639-5932Sergiu LOGHIN3https://orcid.org/0009-0002-1103-2131Valentin Nicolae COȚAC4Iuliana BULIGA5Andreea Elena MAFTEI6https://orcid.org/0000-0003-2393-0879Interdisciplinary research laboratory in the geochemistry of rural areas, RA-07, Mădârjac station for Geographic research and Environmental quality monitoring, Iasi, “Alexandru Ioan Cuza” University of Iaşi“Alexandru Ioan Cuza” University of Iaşi, Faculty of Geography and Geology, Department of Geology“Alexandru Ioan Cuza” University of Iaşi, Faculty of Geography and Geology, Department of Geology“Alexandru Ioan Cuza” University of Iaşi, Faculty of Geography and Geology, Department of Geology“Alexandru Ioan Cuza” University of Iaşi, Faculty of Geography and Geology, Department of Geology“Alexandru Ioan Cuza” University of Iaşi, Faculty of Geography and Geology, Department of GeologyAlexandru Ioan Cuza” University of Iaşi, Institute of Interdisciplinary Research, Department of Exact Sciences and Natural Sciences.This study aims to determine the spatial distribution of some potentially toxic elements, namely As, Cd, Co, Cr, Cu, Ni, Pb, Sn and Zn within riverbed sediments of Izvorul Roşu and Izvorul Băilor rivers with their tributaries (Rodna mining area) from Rodna Mountains and to assess the contamination degree of sediments using some widely used pollution indices. The concentrations of the elements were obtained through ICP-MS analysis using Four-Acid Digestion method and the results show an average of 56.21 mg·kg−1 for As, 1.66 mg·kg−1 for Cd, 27.50 mg·kg−1 for Co, 86.67 mg·kg−1 for Cr, 38.62 mg·kg−1 for Cu, 45.46 mg·kg−1 for Ni, 205.25 mg·kg−1 for Pb, 2.65 mg·kg−1 for Sn and 449.70 mg·kg−1 for Zn. The geochemical background was calculated using the Median±2 MAD procedure. From the evaluation of the sediment’s pollution indices, contamination factor (CF), enrichment factor (EF), pollution load index (PLI), ecological risk index (RI), geoaccumulation index (Igeo) it can be seen that the studied river sediments in most cases, are either not contaminated or slightly contaminated. However, there are a few samples with moderate contamination by As, Cd, Pb and Zn due to former mining activities.http://www.pesd.ro/articole/nr.17/nr.1/pesd2023171011.pdfriverbed sedimentsgeochemical distributionpollution indicesenvironmental geochemistryrodna mountainsmining area |
spellingShingle | Aurelia Andreea SCARLAT Ovidiu Gabriel IANCU Ciprian CHELARIU Sergiu LOGHIN Valentin Nicolae COȚAC Iuliana BULIGA Andreea Elena MAFTEI Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, Romania Present Environment and Sustainable Development riverbed sediments geochemical distribution pollution indices environmental geochemistry rodna mountains mining area |
title | Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, Romania |
title_full | Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, Romania |
title_fullStr | Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, Romania |
title_full_unstemmed | Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, Romania |
title_short | Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, Romania |
title_sort | spatial geochemical distribution of some potentially toxic elements within river bed sediments from rodna mountains eastern carpathians romania |
topic | riverbed sediments geochemical distribution pollution indices environmental geochemistry rodna mountains mining area |
url | http://www.pesd.ro/articole/nr.17/nr.1/pesd2023171011.pdf |
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