Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, Romania

This study aims to determine the spatial distribution of some potentially toxic elements, namely As, Cd, Co, Cr, Cu, Ni, Pb, Sn and Zn within riverbed sediments of Izvorul Roşu and Izvorul Băilor rivers with their tributaries (Rodna mining area) from Rodna Mountains and to assess the contamination d...

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Main Authors: Aurelia Andreea SCARLAT, Ovidiu Gabriel IANCU, Ciprian CHELARIU, Sergiu LOGHIN, Valentin Nicolae COȚAC, Iuliana BULIGA, Andreea Elena MAFTEI
Format: Article
Language:English
Published: Alexandru Ioan Cuza University Press, Iasi, Romania 2023-06-01
Series:Present Environment and Sustainable Development
Subjects:
Online Access:http://www.pesd.ro/articole/nr.17/nr.1/pesd2023171011.pdf
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author Aurelia Andreea SCARLAT
Ovidiu Gabriel IANCU
Ciprian CHELARIU
Sergiu LOGHIN
Valentin Nicolae COȚAC
Iuliana BULIGA
Andreea Elena MAFTEI
author_facet Aurelia Andreea SCARLAT
Ovidiu Gabriel IANCU
Ciprian CHELARIU
Sergiu LOGHIN
Valentin Nicolae COȚAC
Iuliana BULIGA
Andreea Elena MAFTEI
author_sort Aurelia Andreea SCARLAT
collection DOAJ
description This study aims to determine the spatial distribution of some potentially toxic elements, namely As, Cd, Co, Cr, Cu, Ni, Pb, Sn and Zn within riverbed sediments of Izvorul Roşu and Izvorul Băilor rivers with their tributaries (Rodna mining area) from Rodna Mountains and to assess the contamination degree of sediments using some widely used pollution indices. The concentrations of the elements were obtained through ICP-MS analysis using Four-Acid Digestion method and the results show an average of 56.21 mg·kg−1 for As, 1.66 mg·kg−1 for Cd, 27.50 mg·kg−1 for Co, 86.67 mg·kg−1 for Cr, 38.62 mg·kg−1 for Cu, 45.46 mg·kg−1 for Ni, 205.25 mg·kg−1 for Pb, 2.65 mg·kg−1 for Sn and 449.70 mg·kg−1 for Zn. The geochemical background was calculated using the Median±2 MAD procedure. From the evaluation of the sediment’s pollution indices, contamination factor (CF), enrichment factor (EF), pollution load index (PLI), ecological risk index (RI), geoaccumulation index (Igeo) it can be seen that the studied river sediments in most cases, are either not contaminated or slightly contaminated. However, there are a few samples with moderate contamination by As, Cd, Pb and Zn due to former mining activities.
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spelling doaj.art-c2410f2744d94340b24f6801a91a46a52023-08-07T21:33:42ZengAlexandru Ioan Cuza University Press, Iasi, RomaniaPresent Environment and Sustainable Development2284-78202023-06-0117115516910.47743/pesd2023171011Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, RomaniaAurelia Andreea SCARLAT0https://orcid.org/0009-0009-9055-6654Ovidiu Gabriel IANCU1https://orcid.org/0000-0003-1844-7102Ciprian CHELARIU2https://orcid.org/0000-0001-7639-5932Sergiu LOGHIN3https://orcid.org/0009-0002-1103-2131Valentin Nicolae COȚAC4Iuliana BULIGA5Andreea Elena MAFTEI6https://orcid.org/0000-0003-2393-0879Interdisciplinary research laboratory in the geochemistry of rural areas, RA-07, Mădârjac station for Geographic research and Environmental quality monitoring, Iasi, “Alexandru Ioan Cuza” University of Iaşi“Alexandru Ioan Cuza” University of Iaşi, Faculty of Geography and Geology, Department of Geology“Alexandru Ioan Cuza” University of Iaşi, Faculty of Geography and Geology, Department of Geology“Alexandru Ioan Cuza” University of Iaşi, Faculty of Geography and Geology, Department of Geology“Alexandru Ioan Cuza” University of Iaşi, Faculty of Geography and Geology, Department of Geology“Alexandru Ioan Cuza” University of Iaşi, Faculty of Geography and Geology, Department of GeologyAlexandru Ioan Cuza” University of Iaşi, Institute of Interdisciplinary Research, Department of Exact Sciences and Natural Sciences.This study aims to determine the spatial distribution of some potentially toxic elements, namely As, Cd, Co, Cr, Cu, Ni, Pb, Sn and Zn within riverbed sediments of Izvorul Roşu and Izvorul Băilor rivers with their tributaries (Rodna mining area) from Rodna Mountains and to assess the contamination degree of sediments using some widely used pollution indices. The concentrations of the elements were obtained through ICP-MS analysis using Four-Acid Digestion method and the results show an average of 56.21 mg·kg−1 for As, 1.66 mg·kg−1 for Cd, 27.50 mg·kg−1 for Co, 86.67 mg·kg−1 for Cr, 38.62 mg·kg−1 for Cu, 45.46 mg·kg−1 for Ni, 205.25 mg·kg−1 for Pb, 2.65 mg·kg−1 for Sn and 449.70 mg·kg−1 for Zn. The geochemical background was calculated using the Median±2 MAD procedure. From the evaluation of the sediment’s pollution indices, contamination factor (CF), enrichment factor (EF), pollution load index (PLI), ecological risk index (RI), geoaccumulation index (Igeo) it can be seen that the studied river sediments in most cases, are either not contaminated or slightly contaminated. However, there are a few samples with moderate contamination by As, Cd, Pb and Zn due to former mining activities.http://www.pesd.ro/articole/nr.17/nr.1/pesd2023171011.pdfriverbed sedimentsgeochemical distributionpollution indicesenvironmental geochemistryrodna mountainsmining area
spellingShingle Aurelia Andreea SCARLAT
Ovidiu Gabriel IANCU
Ciprian CHELARIU
Sergiu LOGHIN
Valentin Nicolae COȚAC
Iuliana BULIGA
Andreea Elena MAFTEI
Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, Romania
Present Environment and Sustainable Development
riverbed sediments
geochemical distribution
pollution indices
environmental geochemistry
rodna mountains
mining area
title Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, Romania
title_full Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, Romania
title_fullStr Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, Romania
title_full_unstemmed Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, Romania
title_short Spatial geochemical distribution of some potentially toxic elements within river bed sediments from Rodna Mountains, Eastern Carpathians, Romania
title_sort spatial geochemical distribution of some potentially toxic elements within river bed sediments from rodna mountains eastern carpathians romania
topic riverbed sediments
geochemical distribution
pollution indices
environmental geochemistry
rodna mountains
mining area
url http://www.pesd.ro/articole/nr.17/nr.1/pesd2023171011.pdf
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