Recent progress, mechanisms, and perspectives for crystal and interface chemistry applying to the Zn metal anodes in aqueous zinc‐ion batteries

Abstract The need for large‐scale electrochemical energy storage devices in the future has spawned several new breeds of batteries in which aqueous zinc ion batteries (AZIBs) have attracted great attention due to their high safety, low cost, and excellent electrochemical performance. In the current...

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Main Authors: Zhengchunyu Zhang, Baojuan Xi, Xiaojian Ma, Weihua Chen, Jinkui Feng, Shenglin Xiong
Format: Article
Language:English
Published: Wiley 2022-04-01
Series:SusMat
Subjects:
Online Access:https://doi.org/10.1002/sus2.53
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author Zhengchunyu Zhang
Baojuan Xi
Xiaojian Ma
Weihua Chen
Jinkui Feng
Shenglin Xiong
author_facet Zhengchunyu Zhang
Baojuan Xi
Xiaojian Ma
Weihua Chen
Jinkui Feng
Shenglin Xiong
author_sort Zhengchunyu Zhang
collection DOAJ
description Abstract The need for large‐scale electrochemical energy storage devices in the future has spawned several new breeds of batteries in which aqueous zinc ion batteries (AZIBs) have attracted great attention due to their high safety, low cost, and excellent electrochemical performance. In the current research, the dendrite and corrosion caused by aqueous electrolytes are the main problems being studied. However, the research on the zinc metal anode is still in its infancy. We think it really needs to provide clear guidelines about how to reasonably configure the system of AZIBs to realize high‐energy density and long cycle life. Therefore, it is worth analyzing the works on the zinc anode, and several strategies are proposed to improve the stability and cycle life of the battery in recent years. Based on the crystal chemistry and interface chemistry, this review reveals the key factors and essential causes that inhibit dendrite growth and side reactions and puts forward the potential prospects for future work in this direction. It is foreseeable that guiding the construction of AZIBs with high‐energy density and long cycle life in various systems would be quite possible by following this overview as a roadmap.
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spelling doaj.art-c24796ec8dc6407389ad66d89e70be9f2022-12-22T00:14:35ZengWileySusMat2692-45522022-04-012211414110.1002/sus2.53Recent progress, mechanisms, and perspectives for crystal and interface chemistry applying to the Zn metal anodes in aqueous zinc‐ion batteriesZhengchunyu Zhang0Baojuan Xi1Xiaojian Ma2Weihua Chen3Jinkui Feng4Shenglin Xiong5School of Chemistry and Chemical Engineering State Key Laboratory of Crystal Materials Shandong University Jinan P.R. ChinaSchool of Chemistry and Chemical Engineering State Key Laboratory of Crystal Materials Shandong University Jinan P.R. ChinaSchool of Chemistry and Chemical Engineering State Key Laboratory of Crystal Materials Shandong University Jinan P.R. ChinaKey Laboratory of Material Processing and Mold of Ministry of Education Zhengzhou University Zhengzhou P.R. ChinaKey Laboratory for Liquid−Solid Structural Evolution & Processing of Materials Ministry of Education School of Materials Science and Engineering Shandong University Jinan P.R. ChinaSchool of Chemistry and Chemical Engineering State Key Laboratory of Crystal Materials Shandong University Jinan P.R. ChinaAbstract The need for large‐scale electrochemical energy storage devices in the future has spawned several new breeds of batteries in which aqueous zinc ion batteries (AZIBs) have attracted great attention due to their high safety, low cost, and excellent electrochemical performance. In the current research, the dendrite and corrosion caused by aqueous electrolytes are the main problems being studied. However, the research on the zinc metal anode is still in its infancy. We think it really needs to provide clear guidelines about how to reasonably configure the system of AZIBs to realize high‐energy density and long cycle life. Therefore, it is worth analyzing the works on the zinc anode, and several strategies are proposed to improve the stability and cycle life of the battery in recent years. Based on the crystal chemistry and interface chemistry, this review reveals the key factors and essential causes that inhibit dendrite growth and side reactions and puts forward the potential prospects for future work in this direction. It is foreseeable that guiding the construction of AZIBs with high‐energy density and long cycle life in various systems would be quite possible by following this overview as a roadmap.https://doi.org/10.1002/sus2.53crystal chemistryinterface chemistryside reactionZn dendritesZn metal anode
spellingShingle Zhengchunyu Zhang
Baojuan Xi
Xiaojian Ma
Weihua Chen
Jinkui Feng
Shenglin Xiong
Recent progress, mechanisms, and perspectives for crystal and interface chemistry applying to the Zn metal anodes in aqueous zinc‐ion batteries
SusMat
crystal chemistry
interface chemistry
side reaction
Zn dendrites
Zn metal anode
title Recent progress, mechanisms, and perspectives for crystal and interface chemistry applying to the Zn metal anodes in aqueous zinc‐ion batteries
title_full Recent progress, mechanisms, and perspectives for crystal and interface chemistry applying to the Zn metal anodes in aqueous zinc‐ion batteries
title_fullStr Recent progress, mechanisms, and perspectives for crystal and interface chemistry applying to the Zn metal anodes in aqueous zinc‐ion batteries
title_full_unstemmed Recent progress, mechanisms, and perspectives for crystal and interface chemistry applying to the Zn metal anodes in aqueous zinc‐ion batteries
title_short Recent progress, mechanisms, and perspectives for crystal and interface chemistry applying to the Zn metal anodes in aqueous zinc‐ion batteries
title_sort recent progress mechanisms and perspectives for crystal and interface chemistry applying to the zn metal anodes in aqueous zinc ion batteries
topic crystal chemistry
interface chemistry
side reaction
Zn dendrites
Zn metal anode
url https://doi.org/10.1002/sus2.53
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