Co adsoption in kaolinite

Adsorption of metal ions in clay minerals has been used as an alternative to water and effluents treatment. Kaolinite is a clay mineral that presents low specific surface area and exchange ion capacity. Nevertheless, structural modifications can be achieved by means of acid or thermal activation. In...

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Main Authors: Eliel Silva Souza, Paulo Sergio Cardoso Silva
Format: Article
Language:English
Published: Brazilian Radiation Protection Society (Sociedade Brasileira de Proteção Radiológica, SBPR) 2019-02-01
Series:Brazilian Journal of Radiation Sciences
Subjects:
Online Access:https://bjrs.org.br/revista/index.php/REVISTA/article/view/658
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author Eliel Silva Souza
Paulo Sergio Cardoso Silva
author_facet Eliel Silva Souza
Paulo Sergio Cardoso Silva
author_sort Eliel Silva Souza
collection DOAJ
description Adsorption of metal ions in clay minerals has been used as an alternative to water and effluents treatment. Kaolinite is a clay mineral that presents low specific surface area and exchange ion capacity. Nevertheless, structural modifications can be achieved by means of acid or thermal activation. In this paper, it was studied the surface area of kaolinite/bentonite, kaolinite/activated carbon mixtures, thermal activated kaolinite and thermal activated kaolinite/activated carbon mixture. The mixture of kaolinite/activated carbon was tested for pH, contact time, interfering ions and initial concentration effects in the cobalt adsorption. Results showed that the optimized parameters are pH 6 and contact time of 30 min. Chromium acted as a competitive ion, zinc does not appear to have affected adsorption while iron seems to have favored it. Langmuir and Freundlich isotherms indicated that the adsorption of Co in the mixture of kaolinite/activated carbon is a spontaneous process.
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spelling doaj.art-c2699180c7d843ffb8b4b2f3ab72901a2022-12-22T02:36:03ZengBrazilian Radiation Protection Society (Sociedade Brasileira de Proteção Radiológica, SBPR)Brazilian Journal of Radiation Sciences2319-06122019-02-0172A10.15392/bjrs.v7i2A.658Co adsoption in kaoliniteEliel Silva Souza0Paulo Sergio Cardoso Silva1Instituto de Pesquisas Energéticas e NuclearesInstituto de Pesquisas Energéticas e NuclearesAdsorption of metal ions in clay minerals has been used as an alternative to water and effluents treatment. Kaolinite is a clay mineral that presents low specific surface area and exchange ion capacity. Nevertheless, structural modifications can be achieved by means of acid or thermal activation. In this paper, it was studied the surface area of kaolinite/bentonite, kaolinite/activated carbon mixtures, thermal activated kaolinite and thermal activated kaolinite/activated carbon mixture. The mixture of kaolinite/activated carbon was tested for pH, contact time, interfering ions and initial concentration effects in the cobalt adsorption. Results showed that the optimized parameters are pH 6 and contact time of 30 min. Chromium acted as a competitive ion, zinc does not appear to have affected adsorption while iron seems to have favored it. Langmuir and Freundlich isotherms indicated that the adsorption of Co in the mixture of kaolinite/activated carbon is a spontaneous process.https://bjrs.org.br/revista/index.php/REVISTA/article/view/658Cobaltadsorptionkaolinite
spellingShingle Eliel Silva Souza
Paulo Sergio Cardoso Silva
Co adsoption in kaolinite
Brazilian Journal of Radiation Sciences
Cobalt
adsorption
kaolinite
title Co adsoption in kaolinite
title_full Co adsoption in kaolinite
title_fullStr Co adsoption in kaolinite
title_full_unstemmed Co adsoption in kaolinite
title_short Co adsoption in kaolinite
title_sort co adsoption in kaolinite
topic Cobalt
adsorption
kaolinite
url https://bjrs.org.br/revista/index.php/REVISTA/article/view/658
work_keys_str_mv AT elielsilvasouza coadsoptioninkaolinite
AT paulosergiocardososilva coadsoptioninkaolinite