Synthesis, crystal structure and Hirshfeld surface analysis of bis(caffeinium) hexachloridoplatinum(IV) in comparison with some related compounds

Synthesis, crystal structure and Hirshfeld surface analysis of bis(caffeinium) hexachloridoplatinum(IV) in comparison with some related compounds

The molecular and crystal structure of the title compound, (C8H11N4O2)2[PtCl6], synthesized from hexachloroplatinic acid and caffeine in methanol, was studied by single-crystal X-ray diffraction. The caffeinium cations form a double layer via hydrogen bonds and π-stacking interactions. The Hirshfeld...

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Bibliographic Details
Main Authors: Karim A. Zagidullin, Anton P. Novikov, Daria A. Zelenina, Mikhail S. Grigoriev, Konstantin E. German
Format: Article
Language:English
Published: International Union of Crystallography 2023-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
platinum
pt
caffeine
hirshfeld surface analysis
hexahalide
π-stacking
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989023005157

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http://scripts.iucr.org/cgi-bin/paper?S2056989023005157

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