Correlation between TiO2 nanotubes thickness and their tribocorrosion performance in simulated body fluid solution
Titanium dioxide nanotubes (TNTs) have been extensively researched for their enhanced biomedical characteristics, including biocompatibility, cell apposition, and growth morphology. However, there is a significant concern in metallic medical devices owing to micro-movements between implants and bone...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2023-09-01
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| Series: | Journal of Materials Research and Technology |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S223878542301983X |
| _version_ | 1797646742645112832 |
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| author | Iván Farías Omar Jiménez David Bravo Jorge Chávez Cesar D. Rivera-Tello Martin Flores Reynier Suárez Luís Olmos |
| author_facet | Iván Farías Omar Jiménez David Bravo Jorge Chávez Cesar D. Rivera-Tello Martin Flores Reynier Suárez Luís Olmos |
| author_sort | Iván Farías |
| collection | DOAJ |
| description | Titanium dioxide nanotubes (TNTs) have been extensively researched for their enhanced biomedical characteristics, including biocompatibility, cell apposition, and growth morphology. However, there is a significant concern in metallic medical devices owing to micro-movements between implants and bone in aggressive environments due to wear and corrosion synergies, leading to adverse body responses and implant failure. In this study, TNTs on Commercially Pure titanium (C.P. Ti) with three different thickness layers were grown to correlate their corrosion and wear behavior. Initially amorphous after anodization, TNTs underwent annealing at 450 °C for 2 h to transform the distorted, into a crystalline structure. The characterization included X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) with Energy Dispersive X-ray (EDX), X-ray Photoelectron Spectroscopy (XPS), and contact profilometry. Potentiodynamic polarization (PD) and tribocorrosion tests were conducted in Simulated Body Fluid Electrolyte (SBF). SEM micrographs showed TNT thickness layers of 314, 691, and 5280 nm, and X-ray Diffraction showed anatase transformation post-annealing. Results confirmed a significant influence of TNT thickness layers on corrosion and tribocorrosion properties, with higher current density obtained from PD for thicker TNTs layers, associated with surface fluorine content. During tribocorrosion, annealed samples demonstrated lower corrosion tendency, potential drop, and coefficient of friction. Morphology of worn surfaces and volumetric wear rate varied with TNT thickness layer and thermal treatment. |
| first_indexed | 2024-03-11T15:06:05Z |
| format | Article |
| id | doaj.art-c26d562a98ec44d7a248d89158a2b4f4 |
| institution | Directory Open Access Journal |
| issn | 2238-7854 |
| language | English |
| last_indexed | 2024-03-11T15:06:05Z |
| publishDate | 2023-09-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Journal of Materials Research and Technology |
| spelling | doaj.art-c26d562a98ec44d7a248d89158a2b4f42023-10-30T06:03:42ZengElsevierJournal of Materials Research and Technology2238-78542023-09-012644954505Correlation between TiO2 nanotubes thickness and their tribocorrosion performance in simulated body fluid solutionIván Farías0Omar Jiménez1David Bravo2Jorge Chávez3Cesar D. Rivera-Tello4Martin Flores5Reynier Suárez6Luís Olmos7Departamento de Ingeniería de Proyectos, Centro Universitario de Ciencias Exactas e Ingenierías, CUCEI, Universidad de Guadalajara, José Guadalupe Zuno 48, Los Belenes, Zapopan C.P. 45100, Jalisco, MexicoDepartamento de Ingeniería de Proyectos, Centro Universitario de Ciencias Exactas e Ingenierías, CUCEI, Universidad de Guadalajara, José Guadalupe Zuno 48, Los Belenes, Zapopan C.P. 45100, Jalisco, Mexico; Corresponding author.Departamento de Ingeniería de Proyectos, Centro Universitario de Ciencias Exactas e Ingenierías, CUCEI, CONACyT-Universidad de Guadalajara, José Guadalupe Zuno 48, Los Belenes, Zapopan C.P. 45100, Jalisco, MexicoDepartamento de Ingeniería Mecánica Eléctrica, Centro Universitario de Ciencias Exactas e Ingenierías, CUCEI, Universidad de Guadalajara, Blvd. Marcelino García Barragán 1421, Guadalajara C.P. 44430, Jalisco, MexicoDepartamento de Ingeniería Mecánica Eléctrica, Centro Universitario de Ciencias Exactas e Ingenierías, CUCEI, Universidad de Guadalajara, Blvd. Marcelino García Barragán 1421, Guadalajara C.P. 44430, Jalisco, MexicoUniversity of Guadalajara, MexicoCONACyT-Universidad de Guadalajara/CUCEI, Boulevard Marcelino García Barragán 1421, Guadalajara, Jalisco, CP 44430, MexicoInstituto de Investigaciones en Ciencias de La Tierra, INICIT, Universidad Michoacana de San Nicolás de Hidalgo, Ciudad Universitaria, Av. Francisco J. Mujica S/N, Edificio U-3, Morelia C.P. 58030, Michoacán, MexicoTitanium dioxide nanotubes (TNTs) have been extensively researched for their enhanced biomedical characteristics, including biocompatibility, cell apposition, and growth morphology. However, there is a significant concern in metallic medical devices owing to micro-movements between implants and bone in aggressive environments due to wear and corrosion synergies, leading to adverse body responses and implant failure. In this study, TNTs on Commercially Pure titanium (C.P. Ti) with three different thickness layers were grown to correlate their corrosion and wear behavior. Initially amorphous after anodization, TNTs underwent annealing at 450 °C for 2 h to transform the distorted, into a crystalline structure. The characterization included X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) with Energy Dispersive X-ray (EDX), X-ray Photoelectron Spectroscopy (XPS), and contact profilometry. Potentiodynamic polarization (PD) and tribocorrosion tests were conducted in Simulated Body Fluid Electrolyte (SBF). SEM micrographs showed TNT thickness layers of 314, 691, and 5280 nm, and X-ray Diffraction showed anatase transformation post-annealing. Results confirmed a significant influence of TNT thickness layers on corrosion and tribocorrosion properties, with higher current density obtained from PD for thicker TNTs layers, associated with surface fluorine content. During tribocorrosion, annealed samples demonstrated lower corrosion tendency, potential drop, and coefficient of friction. Morphology of worn surfaces and volumetric wear rate varied with TNT thickness layer and thermal treatment.http://www.sciencedirect.com/science/article/pii/S223878542301983XTitanium nanotubesTribocorrosionCorrosionWearBiomedical |
| spellingShingle | Iván Farías Omar Jiménez David Bravo Jorge Chávez Cesar D. Rivera-Tello Martin Flores Reynier Suárez Luís Olmos Correlation between TiO2 nanotubes thickness and their tribocorrosion performance in simulated body fluid solution Journal of Materials Research and Technology Titanium nanotubes Tribocorrosion Corrosion Wear Biomedical |
| title | Correlation between TiO2 nanotubes thickness and their tribocorrosion performance in simulated body fluid solution |
| title_full | Correlation between TiO2 nanotubes thickness and their tribocorrosion performance in simulated body fluid solution |
| title_fullStr | Correlation between TiO2 nanotubes thickness and their tribocorrosion performance in simulated body fluid solution |
| title_full_unstemmed | Correlation between TiO2 nanotubes thickness and their tribocorrosion performance in simulated body fluid solution |
| title_short | Correlation between TiO2 nanotubes thickness and their tribocorrosion performance in simulated body fluid solution |
| title_sort | correlation between tio2 nanotubes thickness and their tribocorrosion performance in simulated body fluid solution |
| topic | Titanium nanotubes Tribocorrosion Corrosion Wear Biomedical |
| url | http://www.sciencedirect.com/science/article/pii/S223878542301983X |
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