Reduction of Fe2O3 content of foyaite by flotation and magnetic separation for ceramics production

Feldspars are used as a fluxing agent in ceramics and glass production. However, the presence of iron-bearing minerals reduces whiteness of the ceramics. The objective of this work was to decrease the Fe2O3 content of a foyaite to <1% by flotation and magnetic separation, individually or combined...

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Main Authors: Juliana Costa Silva, Carina Ulsen, Maurício Guimarães Bergerman, Daniela Gomes Horta
Format: Article
Language:English
Published: Elsevier 2019-09-01
Series:Journal of Materials Research and Technology
Online Access:http://www.sciencedirect.com/science/article/pii/S223878541831038X
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author Juliana Costa Silva
Carina Ulsen
Maurício Guimarães Bergerman
Daniela Gomes Horta
author_facet Juliana Costa Silva
Carina Ulsen
Maurício Guimarães Bergerman
Daniela Gomes Horta
author_sort Juliana Costa Silva
collection DOAJ
description Feldspars are used as a fluxing agent in ceramics and glass production. However, the presence of iron-bearing minerals reduces whiteness of the ceramics. The objective of this work was to decrease the Fe2O3 content of a foyaite to <1% by flotation and magnetic separation, individually or combined, to make the sample suitable for white ceramics manufacture. The sample was prepared regarding its particle size distribution, characterised, and submitted to concentration experiments. Flotation was arried out to investigate promising anionic collectors and the most suitable conditions of dosage and pH. Wet magnetic separation was used in several stages, increasing the magnetic field. Lastly, magnetic separation was applied to the concentrate of the most efficient flotation test. Technological characterisation showed that the foyaite sample displays 3.2% Fe2O3 from pyroxene/amphibole. The most efficient flotation condition was the reverse flotation of iron-bearing minerals with alkyl sulphate as collector under 400 g t−1 at pH 4. The desired specification was reached after three cleaner stages, yielding a concentrate with 0.92% Fe2O3 and 74.6 wt.% recovery. By magnetic separation, the Fe2O3 content was reduced to 0.8% with 70.6 wt.% recovery, after five stages of concentration with the magnetic field varying from 0.78 to 1.12 T. The most efficient combined circuit comprised three stages of flotation followed by one stage of magnetic separation at 0.78 T. The concentrate presented 0.55% Fe2O3 and 71.2 wt.% recovery. Keywords: Flotation, Foyaite, Magnetic separation, White ceramic
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spelling doaj.art-c270788fb25f4af08970df720ae040a12022-12-22T00:16:00ZengElsevierJournal of Materials Research and Technology2238-78542019-09-018549154923Reduction of Fe2O3 content of foyaite by flotation and magnetic separation for ceramics productionJuliana Costa Silva0Carina Ulsen1Maurício Guimarães Bergerman2Daniela Gomes Horta3Federal University of Alfenas, Department of Mining Engineering, Rod. José Aurélio Vilela, 11999, BR 267 km 533, 37715-400, Poços de Caldas, Minas Gerais State, BrazilUniversity of São Paulo, Department of Mining and Petroleum Engineering, Technological Characterization Laboratory (LCT-USP), Av. Prof. Mello Moraes, 2373 — Cidade Universitária, CEP 05508-030, São Paulo, SP, BrazilUniversity of São Paulo, Department of Mining and Petroleum Engineering, Laboratory of Mineral Processing (LTM-USP), Av. Prof. Mello Moraes, 2373 — Cidade Universitária, CEP 05508-030, São Paulo, SP, BrazilFederal University of Alfenas, Department of Mining Engineering, Rod. José Aurélio Vilela, 11999, BR 267 km 533, 37715-400, Poços de Caldas, Minas Gerais State, Brazil; Corresponding author.Feldspars are used as a fluxing agent in ceramics and glass production. However, the presence of iron-bearing minerals reduces whiteness of the ceramics. The objective of this work was to decrease the Fe2O3 content of a foyaite to <1% by flotation and magnetic separation, individually or combined, to make the sample suitable for white ceramics manufacture. The sample was prepared regarding its particle size distribution, characterised, and submitted to concentration experiments. Flotation was arried out to investigate promising anionic collectors and the most suitable conditions of dosage and pH. Wet magnetic separation was used in several stages, increasing the magnetic field. Lastly, magnetic separation was applied to the concentrate of the most efficient flotation test. Technological characterisation showed that the foyaite sample displays 3.2% Fe2O3 from pyroxene/amphibole. The most efficient flotation condition was the reverse flotation of iron-bearing minerals with alkyl sulphate as collector under 400 g t−1 at pH 4. The desired specification was reached after three cleaner stages, yielding a concentrate with 0.92% Fe2O3 and 74.6 wt.% recovery. By magnetic separation, the Fe2O3 content was reduced to 0.8% with 70.6 wt.% recovery, after five stages of concentration with the magnetic field varying from 0.78 to 1.12 T. The most efficient combined circuit comprised three stages of flotation followed by one stage of magnetic separation at 0.78 T. The concentrate presented 0.55% Fe2O3 and 71.2 wt.% recovery. Keywords: Flotation, Foyaite, Magnetic separation, White ceramichttp://www.sciencedirect.com/science/article/pii/S223878541831038X
spellingShingle Juliana Costa Silva
Carina Ulsen
Maurício Guimarães Bergerman
Daniela Gomes Horta
Reduction of Fe2O3 content of foyaite by flotation and magnetic separation for ceramics production
Journal of Materials Research and Technology
title Reduction of Fe2O3 content of foyaite by flotation and magnetic separation for ceramics production
title_full Reduction of Fe2O3 content of foyaite by flotation and magnetic separation for ceramics production
title_fullStr Reduction of Fe2O3 content of foyaite by flotation and magnetic separation for ceramics production
title_full_unstemmed Reduction of Fe2O3 content of foyaite by flotation and magnetic separation for ceramics production
title_short Reduction of Fe2O3 content of foyaite by flotation and magnetic separation for ceramics production
title_sort reduction of fe2o3 content of foyaite by flotation and magnetic separation for ceramics production
url http://www.sciencedirect.com/science/article/pii/S223878541831038X
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AT mauricioguimaraesbergerman reductionoffe2o3contentoffoyaitebyflotationandmagneticseparationforceramicsproduction
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