Analytical study of KOH wet etch surface passivation for III-nitride micropillars

Summary: III-Nitride micropillar structures show great promise for applications in micro light-emitting diodes and vertical power transistors due to their excellent scalability and outstanding electrical properties. Typically, III-Nitride micropillars are fabricated through a top-down approach using...

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Bibliographic Details
Main Authors: Matthew Seitz, Jacob Boisvere, Bryan Melanson, John Wyatt Morrell, Nithil Harris Manimaran, Ke Xu, Jing Zhang
Format: Article
Language:English
Published: Elsevier 2024-04-01
Series:iScience
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2589004224006448
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Summary:Summary: III-Nitride micropillar structures show great promise for applications in micro light-emitting diodes and vertical power transistors due to their excellent scalability and outstanding electrical properties. Typically, III-Nitride micropillars are fabricated through a top-down approach using reactive ion etch which leads to roughened, nonvertical sidewalls that results in significant performance degradation. Thus, it is essential to remove this plasma etch induced surface damage. Here, we show that potassium hydroxide (KOH) acts as a crystallographic etchant for III-Nitride micropillars, preferentially exposing the vertical <11¯00> m-plane, and effectively removing dry etch damage and reducing the structure diameter at up to 36.6 nm/min. Both KOH solution temperature and concentration have a dramatic effect on this wet etch progression. We found that a solution of 20% AZ400K (2% KOH) at 90°C is effective at producing smooth, highly vertical sidewalls with RMS surface roughness as low as 2.59 nm, ideal for high-performance electronic and optoelectronic devices.
ISSN:2589-0042