Intermediate Temperature PEFC’s with Nafion<sup>®</sup> 211 Membrane Electrolytes: An Experimental and Numerical Study

This paper evaluates the performance of Nafion 211 at elevated temperatures up to 120 °C using an experimentally validated model. Increasing the fuel cell operating temperature could have many key benefits at the cell and system levels. However, current research excludes this due to issues with memb...

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Main Authors: Oliver Fernihough, Mohammed S. Ismail, Ahmad El-kharouf
Format: Article
Language:English
Published: MDPI AG 2022-04-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/12/4/430
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author Oliver Fernihough
Mohammed S. Ismail
Ahmad El-kharouf
author_facet Oliver Fernihough
Mohammed S. Ismail
Ahmad El-kharouf
author_sort Oliver Fernihough
collection DOAJ
description This paper evaluates the performance of Nafion 211 at elevated temperatures up to 120 °C using an experimentally validated model. Increasing the fuel cell operating temperature could have many key benefits at the cell and system levels. However, current research excludes this due to issues with membrane durability. Modelling is used to investigate complex systems to gain further information that is challenging to obtain experimentally. Nafion 211 is shown to have some interesting characteristics at elevated temperatures previously unreported, the first of which is that the highest performance reported is at 100 °C and 100% relative humidity. The model was trained on the experimental data and then used to predict the behaviour in the membrane region to understand how the fuel cell performs at varying temperatures and pressures. The model showed that the best membrane performance comes from a 100 °C operating temperature, with much better performance yielded from a higher pressure of 3 bar.
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spelling doaj.art-c2d4f33cdce44206b3025f83446b68032023-12-03T13:41:58ZengMDPI AGMembranes2077-03752022-04-0112443010.3390/membranes12040430Intermediate Temperature PEFC’s with Nafion<sup>®</sup> 211 Membrane Electrolytes: An Experimental and Numerical StudyOliver Fernihough0Mohammed S. Ismail1Ahmad El-kharouf2School of Chemical Engineering, University of Birmingham, Edgbaston, Birmingham B15 2TT, UKEnergy Institute, University of Sheffield, Sheffield S3 7RD, UKSchool of Chemical Engineering, University of Birmingham, Edgbaston, Birmingham B15 2TT, UKThis paper evaluates the performance of Nafion 211 at elevated temperatures up to 120 °C using an experimentally validated model. Increasing the fuel cell operating temperature could have many key benefits at the cell and system levels. However, current research excludes this due to issues with membrane durability. Modelling is used to investigate complex systems to gain further information that is challenging to obtain experimentally. Nafion 211 is shown to have some interesting characteristics at elevated temperatures previously unreported, the first of which is that the highest performance reported is at 100 °C and 100% relative humidity. The model was trained on the experimental data and then used to predict the behaviour in the membrane region to understand how the fuel cell performs at varying temperatures and pressures. The model showed that the best membrane performance comes from a 100 °C operating temperature, with much better performance yielded from a higher pressure of 3 bar.https://www.mdpi.com/2077-0375/12/4/430polymer electrolyte fuel cellsproton exchange membranefuel cell modellingNafionintermediate temperature
spellingShingle Oliver Fernihough
Mohammed S. Ismail
Ahmad El-kharouf
Intermediate Temperature PEFC’s with Nafion<sup>®</sup> 211 Membrane Electrolytes: An Experimental and Numerical Study
Membranes
polymer electrolyte fuel cells
proton exchange membrane
fuel cell modelling
Nafion
intermediate temperature
title Intermediate Temperature PEFC’s with Nafion<sup>®</sup> 211 Membrane Electrolytes: An Experimental and Numerical Study
title_full Intermediate Temperature PEFC’s with Nafion<sup>®</sup> 211 Membrane Electrolytes: An Experimental and Numerical Study
title_fullStr Intermediate Temperature PEFC’s with Nafion<sup>®</sup> 211 Membrane Electrolytes: An Experimental and Numerical Study
title_full_unstemmed Intermediate Temperature PEFC’s with Nafion<sup>®</sup> 211 Membrane Electrolytes: An Experimental and Numerical Study
title_short Intermediate Temperature PEFC’s with Nafion<sup>®</sup> 211 Membrane Electrolytes: An Experimental and Numerical Study
title_sort intermediate temperature pefc s with nafion sup r sup 211 membrane electrolytes an experimental and numerical study
topic polymer electrolyte fuel cells
proton exchange membrane
fuel cell modelling
Nafion
intermediate temperature
url https://www.mdpi.com/2077-0375/12/4/430
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AT mohammedsismail intermediatetemperaturepefcswithnafionsupsup211membraneelectrolytesanexperimentalandnumericalstudy
AT ahmadelkharouf intermediatetemperaturepefcswithnafionsupsup211membraneelectrolytesanexperimentalandnumericalstudy