Two new zinc(II) acetates with 3– and 4–aminopyridine: syntheses and structural properties
The synthesis and characterization of two new zinc(II) coordination compounds with 3– and 4–aminopyridine are reported. They were obtained after dissolving Zn(CH3COO)2·2H2O in different solutions of 3– and 4–aminopyridine. The products were characterized structurally by single–crystal X–ray diffract...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Slovenian Chemical Society
2015-03-01
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| Series: | Acta Chimica Slovenica |
| Subjects: | |
| Online Access: | https://journals.matheo.si/index.php/ACSi/article/view/1111 |
| _version_ | 1819036753134092288 |
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| author | Brina Dojer Andrej Pevec Ferdinand Belaj Matjaž Kristl |
| author_facet | Brina Dojer Andrej Pevec Ferdinand Belaj Matjaž Kristl |
| author_sort | Brina Dojer |
| collection | DOAJ |
| description | The synthesis and characterization of two new zinc(II) coordination compounds with 3– and 4–aminopyridine are reported. They were obtained after dissolving Zn(CH3COO)2·2H2O in different solutions of 3– and 4–aminopyridine. The products were characterized structurally by single–crystal X–ray diffraction analysis. Colourless crystals of the compound synthesized by the reaction of Zn(CH3COO)2·2H2O and 3–aminopyridine (3–apy), result in a trinuclear complex with the formula [Zn3(O2CCH3)6(3–apy)2(H2O)2] (1). The compound consists of two terminal Zn atoms, coordinated tetrahedrally, and one central Zn atom, coordinated octahedrally. Colourless crystals, obtained by the reaction of Zn(CH3COO)2·2H2O with 4–aminopyridine (4–apy), consist of a mononuclear complex [Zn(O2CCH3)2(4–apy)2] (2). Hydrogen‒bonding interactions in the crystal structures of both complexes are discussed. |
| first_indexed | 2024-12-21T08:10:32Z |
| format | Article |
| id | doaj.art-c2dcc2e98d244c43b4451be8692c8a70 |
| institution | Directory Open Access Journal |
| issn | 1318-0207 1580-3155 |
| language | English |
| last_indexed | 2024-12-21T08:10:32Z |
| publishDate | 2015-03-01 |
| publisher | Slovenian Chemical Society |
| record_format | Article |
| series | Acta Chimica Slovenica |
| spelling | doaj.art-c2dcc2e98d244c43b4451be8692c8a702022-12-21T19:10:41ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552015-03-0162231231810.17344/acsi.2014.1111226Two new zinc(II) acetates with 3– and 4–aminopyridine: syntheses and structural propertiesBrina DojerAndrej PevecFerdinand BelajMatjaž KristlThe synthesis and characterization of two new zinc(II) coordination compounds with 3– and 4–aminopyridine are reported. They were obtained after dissolving Zn(CH3COO)2·2H2O in different solutions of 3– and 4–aminopyridine. The products were characterized structurally by single–crystal X–ray diffraction analysis. Colourless crystals of the compound synthesized by the reaction of Zn(CH3COO)2·2H2O and 3–aminopyridine (3–apy), result in a trinuclear complex with the formula [Zn3(O2CCH3)6(3–apy)2(H2O)2] (1). The compound consists of two terminal Zn atoms, coordinated tetrahedrally, and one central Zn atom, coordinated octahedrally. Colourless crystals, obtained by the reaction of Zn(CH3COO)2·2H2O with 4–aminopyridine (4–apy), consist of a mononuclear complex [Zn(O2CCH3)2(4–apy)2] (2). Hydrogen‒bonding interactions in the crystal structures of both complexes are discussed.https://journals.matheo.si/index.php/ACSi/article/view/1111zinc(II) acetate dihydrateaminopyridineX–ray crystal structurehydrogen bonds |
| spellingShingle | Brina Dojer Andrej Pevec Ferdinand Belaj Matjaž Kristl Two new zinc(II) acetates with 3– and 4–aminopyridine: syntheses and structural properties Acta Chimica Slovenica zinc(II) acetate dihydrate aminopyridine X–ray crystal structure hydrogen bonds |
| title | Two new zinc(II) acetates with 3– and 4–aminopyridine: syntheses and structural properties |
| title_full | Two new zinc(II) acetates with 3– and 4–aminopyridine: syntheses and structural properties |
| title_fullStr | Two new zinc(II) acetates with 3– and 4–aminopyridine: syntheses and structural properties |
| title_full_unstemmed | Two new zinc(II) acetates with 3– and 4–aminopyridine: syntheses and structural properties |
| title_short | Two new zinc(II) acetates with 3– and 4–aminopyridine: syntheses and structural properties |
| title_sort | two new zinc ii acetates with 3 and 4 aminopyridine syntheses and structural properties |
| topic | zinc(II) acetate dihydrate aminopyridine X–ray crystal structure hydrogen bonds |
| url | https://journals.matheo.si/index.php/ACSi/article/view/1111 |
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