Electrospun Ternary Composite Metal Oxide Fibers as an Anode for Lithium-Ion Batteries
Nickel–cobalt–manganese oxides (NCMs) are widely investigated as cathode materials for lithium-ion batteries (LIBs) given their beneficial synergistic effects of high storability, electrical conductivity, and stability. However, their use as an anode for LIBs has not been adequately addressed. NCM n...
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| Format: | Article |
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Frontiers Media S.A.
2022-02-01
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| Series: | Frontiers in Materials |
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| Online Access: | https://www.frontiersin.org/articles/10.3389/fmats.2022.815204/full |
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| author | JinKiong Ling JinKiong Ling Chelladurai Karuppiah Santanu Das Izan Izwan Misnon Izan Izwan Misnon Mohd Hasbi Ab. Rahim Mohd Hasbi Ab. Rahim Chun-Chen Yang Chun-Chen Yang Chun-Chen Yang Rajan Jose Rajan Jose |
| author_facet | JinKiong Ling JinKiong Ling Chelladurai Karuppiah Santanu Das Izan Izwan Misnon Izan Izwan Misnon Mohd Hasbi Ab. Rahim Mohd Hasbi Ab. Rahim Chun-Chen Yang Chun-Chen Yang Chun-Chen Yang Rajan Jose Rajan Jose |
| author_sort | JinKiong Ling |
| collection | DOAJ |
| description | Nickel–cobalt–manganese oxides (NCMs) are widely investigated as cathode materials for lithium-ion batteries (LIBs) given their beneficial synergistic effects of high storability, electrical conductivity, and stability. However, their use as an anode for LIBs has not been adequately addressed. NCM nanofibers prepared using the multi-needle electrospinning technique are examined as the anode in LIBs. The NCM nanofibers demonstrated an initial discharge capacity of ∼1,075 mAh g−1 with an initial capacity loss of ∼42%. Through controlling the conductive additive content, the initial discharge capacity can be further improved to ∼1810 mAh g−1, mostly attributing to the improved interfiber connectivity supported by the significant lowering of impedance when the amount of conductive additive is increased. This study also reveals that the conventional ratio of 80:10:10 wt% (active materials:additives:binder) is not optimal for all samples, especially for the high active surface area electrospun nanofibers. |
| first_indexed | 2024-12-13T11:28:25Z |
| format | Article |
| id | doaj.art-c2ef9c22a0b34d1fabc398bd9031c39c |
| institution | Directory Open Access Journal |
| issn | 2296-8016 |
| language | English |
| last_indexed | 2024-12-13T11:28:25Z |
| publishDate | 2022-02-01 |
| publisher | Frontiers Media S.A. |
| record_format | Article |
| series | Frontiers in Materials |
| spelling | doaj.art-c2ef9c22a0b34d1fabc398bd9031c39c2022-12-21T23:48:04ZengFrontiers Media S.A.Frontiers in Materials2296-80162022-02-01910.3389/fmats.2022.815204815204Electrospun Ternary Composite Metal Oxide Fibers as an Anode for Lithium-Ion BatteriesJinKiong Ling0JinKiong Ling1Chelladurai Karuppiah2Santanu Das3Izan Izwan Misnon4Izan Izwan Misnon5Mohd Hasbi Ab. Rahim6Mohd Hasbi Ab. Rahim7Chun-Chen Yang8Chun-Chen Yang9Chun-Chen Yang10Rajan Jose11Rajan Jose12Center of Advanced Intelligent Materials, Universiti Malaysia Pahang, Kuantan, MalaysiaFaculty of Industrial Sciences and Technology, Universiti Malaysia Pahang, Kuantan, MalaysiaBattery Research Centre for Green Energy (BRCGE), Ming Chi University of Technology, New Taipei City, TaiwanDepartment of Ceramic Engineering, Indian Institute of Technology (Banaras Hindu University), Varanasi, IndiaCenter of Advanced Intelligent Materials, Universiti Malaysia Pahang, Kuantan, MalaysiaFaculty of Industrial Sciences and Technology, Universiti Malaysia Pahang, Kuantan, MalaysiaCenter of Advanced Intelligent Materials, Universiti Malaysia Pahang, Kuantan, MalaysiaFaculty of Industrial Sciences and Technology, Universiti Malaysia Pahang, Kuantan, MalaysiaBattery Research Centre for Green Energy (BRCGE), Ming Chi University of Technology, New Taipei City, TaiwanDepartment of Chemical Engineering, Ming Chi University of Technology, New Taipei City, TaiwanDepartment of Chemical and Materials Engineering, Chang Gung University, Taoyuan, TaiwanCenter of Advanced Intelligent Materials, Universiti Malaysia Pahang, Kuantan, MalaysiaFaculty of Industrial Sciences and Technology, Universiti Malaysia Pahang, Kuantan, MalaysiaNickel–cobalt–manganese oxides (NCMs) are widely investigated as cathode materials for lithium-ion batteries (LIBs) given their beneficial synergistic effects of high storability, electrical conductivity, and stability. However, their use as an anode for LIBs has not been adequately addressed. NCM nanofibers prepared using the multi-needle electrospinning technique are examined as the anode in LIBs. The NCM nanofibers demonstrated an initial discharge capacity of ∼1,075 mAh g−1 with an initial capacity loss of ∼42%. Through controlling the conductive additive content, the initial discharge capacity can be further improved to ∼1810 mAh g−1, mostly attributing to the improved interfiber connectivity supported by the significant lowering of impedance when the amount of conductive additive is increased. This study also reveals that the conventional ratio of 80:10:10 wt% (active materials:additives:binder) is not optimal for all samples, especially for the high active surface area electrospun nanofibers.https://www.frontiersin.org/articles/10.3389/fmats.2022.815204/fullsecondary batteriesrechargeablequaternary metal oxidecompositevapor grown carbon fiber (VGCF)super P |
| spellingShingle | JinKiong Ling JinKiong Ling Chelladurai Karuppiah Santanu Das Izan Izwan Misnon Izan Izwan Misnon Mohd Hasbi Ab. Rahim Mohd Hasbi Ab. Rahim Chun-Chen Yang Chun-Chen Yang Chun-Chen Yang Rajan Jose Rajan Jose Electrospun Ternary Composite Metal Oxide Fibers as an Anode for Lithium-Ion Batteries Frontiers in Materials secondary batteries rechargeable quaternary metal oxide composite vapor grown carbon fiber (VGCF) super P |
| title | Electrospun Ternary Composite Metal Oxide Fibers as an Anode for Lithium-Ion Batteries |
| title_full | Electrospun Ternary Composite Metal Oxide Fibers as an Anode for Lithium-Ion Batteries |
| title_fullStr | Electrospun Ternary Composite Metal Oxide Fibers as an Anode for Lithium-Ion Batteries |
| title_full_unstemmed | Electrospun Ternary Composite Metal Oxide Fibers as an Anode for Lithium-Ion Batteries |
| title_short | Electrospun Ternary Composite Metal Oxide Fibers as an Anode for Lithium-Ion Batteries |
| title_sort | electrospun ternary composite metal oxide fibers as an anode for lithium ion batteries |
| topic | secondary batteries rechargeable quaternary metal oxide composite vapor grown carbon fiber (VGCF) super P |
| url | https://www.frontiersin.org/articles/10.3389/fmats.2022.815204/full |
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