Overcoming Size Effects in Ferroelectric Thin Films

Abstract Ferroelectric thin films have recently received unprecedented attention due to the need to miniaturize electronic circuit devices. Synthesis and deposition processes along with theoretical calculations are improved remarkably to realize stable ferroelectric thin films up to nanometer thickn...

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Main Authors: Sung Hyuk Park, Jae Young Kim, Jae Yong Song, Ho Won Jang
Format: Article
Language:English
Published: Wiley-VCH 2023-06-01
Series:Advanced Physics Research
Subjects:
Online Access:https://doi.org/10.1002/apxr.202200096
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author Sung Hyuk Park
Jae Young Kim
Jae Yong Song
Ho Won Jang
author_facet Sung Hyuk Park
Jae Young Kim
Jae Yong Song
Ho Won Jang
author_sort Sung Hyuk Park
collection DOAJ
description Abstract Ferroelectric thin films have recently received unprecedented attention due to the need to miniaturize electronic circuit devices. Synthesis and deposition processes along with theoretical calculations are improved remarkably to realize stable ferroelectric thin films up to nanometer thickness. However, even with technological advances, it is still difficult to overcome the size effect of ferroelectrics, so research is being conducted to achieve stable ferroelectricity in unit‐cell thicknesses thinner than the typical critical thicknesses. In this review, the size effects in ferroelectric thin films are described, and their importance and fundamental limitations are discussed. First, intrinsic and extrinsic factors affecting ferroelectricity are introduced based on the theoretical background of the size effects in ferroelectricity. Then, on understanding the size effects by considering complex interacting factors, the recent works showing ferroelectricity below the commonly known critical thicknesses in perovskite, fluorite oxides, and two‐dimensional (2D) ferroelectrics are introduced. Finally, the results of research efforts in scaling ferroelectric thin films with a future perspective are summarized.
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spelling doaj.art-c2f00907075544559177c606fb1337f52023-07-21T15:30:36ZengWiley-VCHAdvanced Physics Research2751-12002023-06-0126n/an/a10.1002/apxr.202200096Overcoming Size Effects in Ferroelectric Thin FilmsSung Hyuk Park0Jae Young Kim1Jae Yong Song2Ho Won Jang3Department of Materials Science and Engineering Research Institute of Advanced Materials Seoul National University Seoul 08826 Republic of KoreaDepartment of Materials Science and Engineering Research Institute of Advanced Materials Seoul National University Seoul 08826 Republic of KoreaDepartment of Semiconductor Engineering Pohang University of Science and Technology Pohang Gyeongbuk 37673 Republic of KoreaDepartment of Materials Science and Engineering Research Institute of Advanced Materials Seoul National University Seoul 08826 Republic of KoreaAbstract Ferroelectric thin films have recently received unprecedented attention due to the need to miniaturize electronic circuit devices. Synthesis and deposition processes along with theoretical calculations are improved remarkably to realize stable ferroelectric thin films up to nanometer thickness. However, even with technological advances, it is still difficult to overcome the size effect of ferroelectrics, so research is being conducted to achieve stable ferroelectricity in unit‐cell thicknesses thinner than the typical critical thicknesses. In this review, the size effects in ferroelectric thin films are described, and their importance and fundamental limitations are discussed. First, intrinsic and extrinsic factors affecting ferroelectricity are introduced based on the theoretical background of the size effects in ferroelectricity. Then, on understanding the size effects by considering complex interacting factors, the recent works showing ferroelectricity below the commonly known critical thicknesses in perovskite, fluorite oxides, and two‐dimensional (2D) ferroelectrics are introduced. Finally, the results of research efforts in scaling ferroelectric thin films with a future perspective are summarized.https://doi.org/10.1002/apxr.2022000962D ferroelectricsferroelectricfluoriteperovskite oxidesize effect
spellingShingle Sung Hyuk Park
Jae Young Kim
Jae Yong Song
Ho Won Jang
Overcoming Size Effects in Ferroelectric Thin Films
Advanced Physics Research
2D ferroelectrics
ferroelectric
fluorite
perovskite oxide
size effect
title Overcoming Size Effects in Ferroelectric Thin Films
title_full Overcoming Size Effects in Ferroelectric Thin Films
title_fullStr Overcoming Size Effects in Ferroelectric Thin Films
title_full_unstemmed Overcoming Size Effects in Ferroelectric Thin Films
title_short Overcoming Size Effects in Ferroelectric Thin Films
title_sort overcoming size effects in ferroelectric thin films
topic 2D ferroelectrics
ferroelectric
fluorite
perovskite oxide
size effect
url https://doi.org/10.1002/apxr.202200096
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