(E)-1-(2,4-Dinitrophenyl)-2-[1-(3-methoxyphenyl)ethylidene]hydrazine
There are two crystallographically independent molecules in the asymmetric unit of the title compound, C15H14N4O5, with different conformations for the methoxy groups. The molecules are both slightly twisted, the dihedral angles between two benzene rings being 8.37 (18)° i...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812026979 |
| _version_ | 1829118708978548736 |
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| author | Hoong-Kun Fun Suchada Chantrapromma Boonlerd Nilwanna Thawanrat Kobkeatthawin |
| author_facet | Hoong-Kun Fun Suchada Chantrapromma Boonlerd Nilwanna Thawanrat Kobkeatthawin |
| author_sort | Hoong-Kun Fun |
| collection | DOAJ |
| description | There are two crystallographically independent molecules in the asymmetric unit of the title compound, C15H14N4O5, with different conformations for the methoxy groups. The molecules are both slightly twisted, the dihedral angles between two benzene rings being 8.37 (18)° in one and 7.31 (18)° in the other. In both molecules, the two nitro groups are essentially coplanar with their bound benzene ring, with the r.m.s. deviation of the dinitrobenzene plane being 0.0310 (3) Å in one molecule and 0.0650 (3) Å in the other. In each molecule, an intramolecular N—H...O hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked by weak C—H...O interactions and stacked along the a axis through π–π interactions, with centroid–centroid distances of 3.651 (2) and 3.721 (2) Å. The crystal studied was a non-merohedral twin with a refined minor component of 20.1 (3)%. |
| first_indexed | 2024-12-13T10:43:16Z |
| format | Article |
| id | doaj.art-c31943257f134e2e93a63a2f61195bba |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:43:16Z |
| publishDate | 2012-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c31943257f134e2e93a63a2f61195bba2022-12-21T23:50:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-07-01687o2144o214510.1107/S1600536812026979(E)-1-(2,4-Dinitrophenyl)-2-[1-(3-methoxyphenyl)ethylidene]hydrazineHoong-Kun FunSuchada ChantraprommaBoonlerd NilwannaThawanrat KobkeatthawinThere are two crystallographically independent molecules in the asymmetric unit of the title compound, C15H14N4O5, with different conformations for the methoxy groups. The molecules are both slightly twisted, the dihedral angles between two benzene rings being 8.37 (18)° in one and 7.31 (18)° in the other. In both molecules, the two nitro groups are essentially coplanar with their bound benzene ring, with the r.m.s. deviation of the dinitrobenzene plane being 0.0310 (3) Å in one molecule and 0.0650 (3) Å in the other. In each molecule, an intramolecular N—H...O hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked by weak C—H...O interactions and stacked along the a axis through π–π interactions, with centroid–centroid distances of 3.651 (2) and 3.721 (2) Å. The crystal studied was a non-merohedral twin with a refined minor component of 20.1 (3)%.http://scripts.iucr.org/cgi-bin/paper?S1600536812026979 |
| spellingShingle | Hoong-Kun Fun Suchada Chantrapromma Boonlerd Nilwanna Thawanrat Kobkeatthawin (E)-1-(2,4-Dinitrophenyl)-2-[1-(3-methoxyphenyl)ethylidene]hydrazine Acta Crystallographica Section E |
| title | (E)-1-(2,4-Dinitrophenyl)-2-[1-(3-methoxyphenyl)ethylidene]hydrazine |
| title_full | (E)-1-(2,4-Dinitrophenyl)-2-[1-(3-methoxyphenyl)ethylidene]hydrazine |
| title_fullStr | (E)-1-(2,4-Dinitrophenyl)-2-[1-(3-methoxyphenyl)ethylidene]hydrazine |
| title_full_unstemmed | (E)-1-(2,4-Dinitrophenyl)-2-[1-(3-methoxyphenyl)ethylidene]hydrazine |
| title_short | (E)-1-(2,4-Dinitrophenyl)-2-[1-(3-methoxyphenyl)ethylidene]hydrazine |
| title_sort | e 1 2 4 dinitrophenyl 2 1 3 methoxyphenyl ethylidene hydrazine |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812026979 |
| work_keys_str_mv | AT hoongkunfun e124dinitrophenyl213methoxyphenylethylidenehydrazine AT suchadachantrapromma e124dinitrophenyl213methoxyphenylethylidenehydrazine AT boonlerdnilwanna e124dinitrophenyl213methoxyphenylethylidenehydrazine AT thawanratkobkeatthawin e124dinitrophenyl213methoxyphenylethylidenehydrazine |