Mechanism for the subglacial formation of cryogenic brines

Cryogenic brines are under-studied, despite the fact that they may contain information about past ice-sheet behavior. Cryogenic brines form through cryoconcentration of seawater, although the specific setting and mechanism of formation have been debated. Previous conceptual models of brine formation...

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Main Authors: Sarah U. Neuhaus, Slawek M. Tulaczyk
Format: Article
Language:English
Published: Cambridge University Press 2022-09-01
Series:Annals of Glaciology
Subjects:
Online Access:https://www.cambridge.org/core/product/identifier/S0260305523000289/type/journal_article
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author Sarah U. Neuhaus
Slawek M. Tulaczyk
author_facet Sarah U. Neuhaus
Slawek M. Tulaczyk
author_sort Sarah U. Neuhaus
collection DOAJ
description Cryogenic brines are under-studied, despite the fact that they may contain information about past ice-sheet behavior. Cryogenic brines form through cryoconcentration of seawater, although the specific setting and mechanism of formation have been debated. Previous conceptual models of brine formation require seawater isolation from the ocean in a closed basin experiencing freezing. We propose instead that they may form in pore spaces of marine sediments subjected to repeat cycles of ice-sheet advance and retreat. During periods of basal freezing, cryoconcentration produces hypersaline brines which experience downward flow driven by unstable density stratification. Our advection-diffusion model of porewater chemistry evolution successfully recreates the porewater chemistry of two deep Antarctic cores containing cryogenic brines (AND-1B and AND-2A), suggesting that cryogenic brines can be formed through the repeated isolation and cryoconcentration of marine waters within subglacial sediment pore spaces of modern and past ice sheets.
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spelling doaj.art-c33b1fd812914990b01c598310f55f6e2023-10-13T10:44:52ZengCambridge University PressAnnals of Glaciology0260-30551727-56442022-09-016312112410.1017/aog.2023.28Mechanism for the subglacial formation of cryogenic brinesSarah U. Neuhaus0Slawek M. Tulaczyk1https://orcid.org/0000-0002-9711-4332Earth and Planetary Sciences, University of California Santa Cruz, Santa Cruz, CA 95064, USAEarth and Planetary Sciences, University of California Santa Cruz, Santa Cruz, CA 95064, USACryogenic brines are under-studied, despite the fact that they may contain information about past ice-sheet behavior. Cryogenic brines form through cryoconcentration of seawater, although the specific setting and mechanism of formation have been debated. Previous conceptual models of brine formation require seawater isolation from the ocean in a closed basin experiencing freezing. We propose instead that they may form in pore spaces of marine sediments subjected to repeat cycles of ice-sheet advance and retreat. During periods of basal freezing, cryoconcentration produces hypersaline brines which experience downward flow driven by unstable density stratification. Our advection-diffusion model of porewater chemistry evolution successfully recreates the porewater chemistry of two deep Antarctic cores containing cryogenic brines (AND-1B and AND-2A), suggesting that cryogenic brines can be formed through the repeated isolation and cryoconcentration of marine waters within subglacial sediment pore spaces of modern and past ice sheets.https://www.cambridge.org/core/product/identifier/S0260305523000289/type/journal_articleGlacier hydrochemistryice/ocean interactionsmeltwater chemistry
spellingShingle Sarah U. Neuhaus
Slawek M. Tulaczyk
Mechanism for the subglacial formation of cryogenic brines
Annals of Glaciology
Glacier hydrochemistry
ice/ocean interactions
meltwater chemistry
title Mechanism for the subglacial formation of cryogenic brines
title_full Mechanism for the subglacial formation of cryogenic brines
title_fullStr Mechanism for the subglacial formation of cryogenic brines
title_full_unstemmed Mechanism for the subglacial formation of cryogenic brines
title_short Mechanism for the subglacial formation of cryogenic brines
title_sort mechanism for the subglacial formation of cryogenic brines
topic Glacier hydrochemistry
ice/ocean interactions
meltwater chemistry
url https://www.cambridge.org/core/product/identifier/S0260305523000289/type/journal_article
work_keys_str_mv AT sarahuneuhaus mechanismforthesubglacialformationofcryogenicbrines
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