Characteristics of Biochar Obtained by Hydrothermal Carbonization of Cellulose for Renewable Energy

The effect of hydrothermal carbonization on the properties of cellulose present in lignocellulosic biomass was investigated for converting it into a renewable energy resource with high energy recovery efficiency. The biochar obtained from cellulose subjected to hydrothermal carbonization showed a si...

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Main Authors: Daegi Kim, Kunio Yoshikawa, Ki Young Park
Format: Article
Language:English
Published: MDPI AG 2015-12-01
Series:Energies
Subjects:
Online Access:http://www.mdpi.com/1996-1073/8/12/12412
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author Daegi Kim
Kunio Yoshikawa
Ki Young Park
author_facet Daegi Kim
Kunio Yoshikawa
Ki Young Park
author_sort Daegi Kim
collection DOAJ
description The effect of hydrothermal carbonization on the properties of cellulose present in lignocellulosic biomass was investigated for converting it into a renewable energy resource with high energy recovery efficiency. The biochar obtained from cellulose subjected to hydrothermal carbonization showed a significant increase in its carbon content and a calorific value. 13C NMR spectroscopy showed that when raw cellulose was subjected to hydrothermal carbonization above 220 °C, the resulting biochar had more aromatic and aliphatic fractions than those in raw cellulose. The resulting composition of the biochars was comparable to that of solid fuels and was between that of lignite and sub-bituminous coal. Therefore, cellulose, the main component of lignocellulosic biomass, was used to investigate the effects of varying the reaction temperature during hydrothermal carbonization. The energy recovery efficiency calculations showed that the optimum reaction temperature for the transformation of a mixture of cellulose was approximately 220 °C.
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spelling doaj.art-c3504518cf88437e826ba2f213add4342022-12-22T03:19:07ZengMDPI AGEnergies1996-10732015-12-01812140401404810.3390/en81212412en81212412Characteristics of Biochar Obtained by Hydrothermal Carbonization of Cellulose for Renewable EnergyDaegi Kim0Kunio Yoshikawa1Ki Young Park2Department of Civil and Environmental System Engineering, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 143-701, KoreaDepartment of Environmental Science and Technology, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8503, JapanDepartment of Civil and Environmental System Engineering, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 143-701, KoreaThe effect of hydrothermal carbonization on the properties of cellulose present in lignocellulosic biomass was investigated for converting it into a renewable energy resource with high energy recovery efficiency. The biochar obtained from cellulose subjected to hydrothermal carbonization showed a significant increase in its carbon content and a calorific value. 13C NMR spectroscopy showed that when raw cellulose was subjected to hydrothermal carbonization above 220 °C, the resulting biochar had more aromatic and aliphatic fractions than those in raw cellulose. The resulting composition of the biochars was comparable to that of solid fuels and was between that of lignite and sub-bituminous coal. Therefore, cellulose, the main component of lignocellulosic biomass, was used to investigate the effects of varying the reaction temperature during hydrothermal carbonization. The energy recovery efficiency calculations showed that the optimum reaction temperature for the transformation of a mixture of cellulose was approximately 220 °C.http://www.mdpi.com/1996-1073/8/12/12412lignocellulosic biomasscellulosebiocharupgrading solid fuelhydrothermal carbonizationenergy recovery
spellingShingle Daegi Kim
Kunio Yoshikawa
Ki Young Park
Characteristics of Biochar Obtained by Hydrothermal Carbonization of Cellulose for Renewable Energy
Energies
lignocellulosic biomass
cellulose
biochar
upgrading solid fuel
hydrothermal carbonization
energy recovery
title Characteristics of Biochar Obtained by Hydrothermal Carbonization of Cellulose for Renewable Energy
title_full Characteristics of Biochar Obtained by Hydrothermal Carbonization of Cellulose for Renewable Energy
title_fullStr Characteristics of Biochar Obtained by Hydrothermal Carbonization of Cellulose for Renewable Energy
title_full_unstemmed Characteristics of Biochar Obtained by Hydrothermal Carbonization of Cellulose for Renewable Energy
title_short Characteristics of Biochar Obtained by Hydrothermal Carbonization of Cellulose for Renewable Energy
title_sort characteristics of biochar obtained by hydrothermal carbonization of cellulose for renewable energy
topic lignocellulosic biomass
cellulose
biochar
upgrading solid fuel
hydrothermal carbonization
energy recovery
url http://www.mdpi.com/1996-1073/8/12/12412
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