Quartz Fine Particle Processing: Hydrophobic Aggregation by Shear Flocculation

This study investigates the hydrophobic aggregation of fine quartz particles through shear flocculation induced by dodecylamine in aqueous solutions. The effect of stirring speed, collector concentration, flocculation time, and pH were investigated. The results showed that the impact of stirring spe...

Full description

Bibliographic Details
Main Authors: Francielle Nogueira, Karine Rodrigues, Carlos Pereira, André Carlos Silva, Elenice M. Schons Silva, Asghar Azizi, Ahmad Hassanzadeh
Format: Article
Language:English
Published: MDPI AG 2023-09-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/13/9/1208
_version_ 1797578698009870336
author Francielle Nogueira
Karine Rodrigues
Carlos Pereira
André Carlos Silva
Elenice M. Schons Silva
Asghar Azizi
Ahmad Hassanzadeh
author_facet Francielle Nogueira
Karine Rodrigues
Carlos Pereira
André Carlos Silva
Elenice M. Schons Silva
Asghar Azizi
Ahmad Hassanzadeh
author_sort Francielle Nogueira
collection DOAJ
description This study investigates the hydrophobic aggregation of fine quartz particles through shear flocculation induced by dodecylamine in aqueous solutions. The effect of stirring speed, collector concentration, flocculation time, and pH were investigated. The results showed that the impact of stirring speed on particle aggregation in the absence of a collector is very limited. Quantitative analyses demonstrated that the variation of collector concentration intensified the flocculation process more than the stirring rate. Numerical optimization showed that the large volume occupied by the flocs was 12.3 mL, achieved with a stirring speed of 2135 rpm and dodecylamine concentration of 1.39 × 10<sup>−2</sup> mol·L<sup>−1</sup>. The highest quartz particle aggregation was observed at pH 10.5, corroborating the importance of the non-dissociated amine molecules for particle hydrophobization. High zeta potential values did not result in reducing aggregation, indicating that hydrophobicity was the governing factor in the shear flocculation process.
first_indexed 2024-03-10T22:26:29Z
format Article
id doaj.art-c351110f53144ded9dc2114253f469f3
institution Directory Open Access Journal
issn 2075-163X
language English
last_indexed 2024-03-10T22:26:29Z
publishDate 2023-09-01
publisher MDPI AG
record_format Article
series Minerals
spelling doaj.art-c351110f53144ded9dc2114253f469f32023-11-19T12:05:49ZengMDPI AGMinerals2075-163X2023-09-01139120810.3390/min13091208Quartz Fine Particle Processing: Hydrophobic Aggregation by Shear FlocculationFrancielle Nogueira0Karine Rodrigues1Carlos Pereira2André Carlos Silva3Elenice M. Schons Silva4Asghar Azizi5Ahmad Hassanzadeh6School of Mines, Federal University of Ouro Preto, Ouro Preto 35400-000, BrazilSchool of Mines, Federal University of Ouro Preto, Ouro Preto 35400-000, BrazilSchool of Mines, Federal University of Ouro Preto, Ouro Preto 35400-000, BrazilModelling and Mineral Processing Research Lab (LaMPPMin), Federal University of Catalão, Catalão 75705-321, BrazilModelling and Mineral Processing Research Lab (LaMPPMin), Federal University of Catalão, Catalão 75705-321, BrazilFaculty of Mining, Petroleum & Geophysics Engineering, Shahrood University of Technology, Shahrood 3619995161, IranDepartment of Geoscience and Petroleum, Faculty of Engineering, Norwegian University of Science and Technology, 7031 Trondheim, NorwayThis study investigates the hydrophobic aggregation of fine quartz particles through shear flocculation induced by dodecylamine in aqueous solutions. The effect of stirring speed, collector concentration, flocculation time, and pH were investigated. The results showed that the impact of stirring speed on particle aggregation in the absence of a collector is very limited. Quantitative analyses demonstrated that the variation of collector concentration intensified the flocculation process more than the stirring rate. Numerical optimization showed that the large volume occupied by the flocs was 12.3 mL, achieved with a stirring speed of 2135 rpm and dodecylamine concentration of 1.39 × 10<sup>−2</sup> mol·L<sup>−1</sup>. The highest quartz particle aggregation was observed at pH 10.5, corroborating the importance of the non-dissociated amine molecules for particle hydrophobization. High zeta potential values did not result in reducing aggregation, indicating that hydrophobicity was the governing factor in the shear flocculation process.https://www.mdpi.com/2075-163X/13/9/1208shear flocculationfine quartz particleshydrophobic aggregationdodecylamine
spellingShingle Francielle Nogueira
Karine Rodrigues
Carlos Pereira
André Carlos Silva
Elenice M. Schons Silva
Asghar Azizi
Ahmad Hassanzadeh
Quartz Fine Particle Processing: Hydrophobic Aggregation by Shear Flocculation
Minerals
shear flocculation
fine quartz particles
hydrophobic aggregation
dodecylamine
title Quartz Fine Particle Processing: Hydrophobic Aggregation by Shear Flocculation
title_full Quartz Fine Particle Processing: Hydrophobic Aggregation by Shear Flocculation
title_fullStr Quartz Fine Particle Processing: Hydrophobic Aggregation by Shear Flocculation
title_full_unstemmed Quartz Fine Particle Processing: Hydrophobic Aggregation by Shear Flocculation
title_short Quartz Fine Particle Processing: Hydrophobic Aggregation by Shear Flocculation
title_sort quartz fine particle processing hydrophobic aggregation by shear flocculation
topic shear flocculation
fine quartz particles
hydrophobic aggregation
dodecylamine
url https://www.mdpi.com/2075-163X/13/9/1208
work_keys_str_mv AT franciellenogueira quartzfineparticleprocessinghydrophobicaggregationbyshearflocculation
AT karinerodrigues quartzfineparticleprocessinghydrophobicaggregationbyshearflocculation
AT carlospereira quartzfineparticleprocessinghydrophobicaggregationbyshearflocculation
AT andrecarlossilva quartzfineparticleprocessinghydrophobicaggregationbyshearflocculation
AT elenicemschonssilva quartzfineparticleprocessinghydrophobicaggregationbyshearflocculation
AT asgharazizi quartzfineparticleprocessinghydrophobicaggregationbyshearflocculation
AT ahmadhassanzadeh quartzfineparticleprocessinghydrophobicaggregationbyshearflocculation