Quartz-Enhanced Photothermal Spectroscopy-Based Methane Detection in an Anti-Resonant Hollow-Core Fiber

In this paper, the combination of using an anti-resonant hollow-core fiber (ARHCF), working as a gas absorption cell, and an inexpensive, commercially available watch quartz tuning fork (QTF), acting as a detector in the quartz-enhanced photothermal spectroscopy (QEPTS) sensor configuration is demon...

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Main Authors: Piotr Bojęś, Piotr Pokryszka, Piotr Jaworski, Fei Yu, Dakun Wu, Karol Krzempek
Format: Article
Language:English
Published: MDPI AG 2022-07-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/22/15/5504
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author Piotr Bojęś
Piotr Pokryszka
Piotr Jaworski
Fei Yu
Dakun Wu
Karol Krzempek
author_facet Piotr Bojęś
Piotr Pokryszka
Piotr Jaworski
Fei Yu
Dakun Wu
Karol Krzempek
author_sort Piotr Bojęś
collection DOAJ
description In this paper, the combination of using an anti-resonant hollow-core fiber (ARHCF), working as a gas absorption cell, and an inexpensive, commercially available watch quartz tuning fork (QTF), acting as a detector in the quartz-enhanced photothermal spectroscopy (QEPTS) sensor configuration is demonstrated. The proof-of-concept experiment involved the detection of methane (CH<sub>4</sub>) at 1651 nm (6057 cm<sup>−1</sup>). The advantage of the high QTF Q-factor combined with a specially designed low-noise amplifier and additional wavelength modulation spectroscopy with the second harmonic (2f-WMS) method of signal analysis, resulted in achieving a normalized noise-equivalent absorption (NNEA) at the level of 1.34 × 10<sup>−10</sup> and 2.04 × 10<sup>−11</sup> W cm<sup>−1</sup> Hz<sup>−1/2</sup> for 1 and 100 s of integration time, respectively. Results obtained in that relatively non-complex sensor setup show great potential for further development of cost-optimized and miniaturized gas detectors, taking advantage of the combination of ARHCF-based absorption cells and QTF-aided spectroscopic signal retrieval methods.
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spelling doaj.art-c355899acf304636bb26958a60319c1b2023-12-03T12:59:47ZengMDPI AGSensors1424-82202022-07-012215550410.3390/s22155504Quartz-Enhanced Photothermal Spectroscopy-Based Methane Detection in an Anti-Resonant Hollow-Core FiberPiotr Bojęś0Piotr Pokryszka1Piotr Jaworski2Fei Yu3Dakun Wu4Karol Krzempek5Faculty of Electronics, Photonics and Microsystem, Wroclaw University of Science and Technology, 50-370 Wroclaw, PolandFaculty of Electronics, Photonics and Microsystem, Wroclaw University of Science and Technology, 50-370 Wroclaw, PolandFaculty of Electronics, Photonics and Microsystem, Wroclaw University of Science and Technology, 50-370 Wroclaw, PolandHangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou 310024, ChinaHangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou 310024, ChinaFaculty of Electronics, Photonics and Microsystem, Wroclaw University of Science and Technology, 50-370 Wroclaw, PolandIn this paper, the combination of using an anti-resonant hollow-core fiber (ARHCF), working as a gas absorption cell, and an inexpensive, commercially available watch quartz tuning fork (QTF), acting as a detector in the quartz-enhanced photothermal spectroscopy (QEPTS) sensor configuration is demonstrated. The proof-of-concept experiment involved the detection of methane (CH<sub>4</sub>) at 1651 nm (6057 cm<sup>−1</sup>). The advantage of the high QTF Q-factor combined with a specially designed low-noise amplifier and additional wavelength modulation spectroscopy with the second harmonic (2f-WMS) method of signal analysis, resulted in achieving a normalized noise-equivalent absorption (NNEA) at the level of 1.34 × 10<sup>−10</sup> and 2.04 × 10<sup>−11</sup> W cm<sup>−1</sup> Hz<sup>−1/2</sup> for 1 and 100 s of integration time, respectively. Results obtained in that relatively non-complex sensor setup show great potential for further development of cost-optimized and miniaturized gas detectors, taking advantage of the combination of ARHCF-based absorption cells and QTF-aided spectroscopic signal retrieval methods.https://www.mdpi.com/1424-8220/22/15/5504quartz-enhanced photothermal spectroscopy (QEPTS)anti-resonant hollow-core fiber (ARHCF)quartz tuning fork
spellingShingle Piotr Bojęś
Piotr Pokryszka
Piotr Jaworski
Fei Yu
Dakun Wu
Karol Krzempek
Quartz-Enhanced Photothermal Spectroscopy-Based Methane Detection in an Anti-Resonant Hollow-Core Fiber
Sensors
quartz-enhanced photothermal spectroscopy (QEPTS)
anti-resonant hollow-core fiber (ARHCF)
quartz tuning fork
title Quartz-Enhanced Photothermal Spectroscopy-Based Methane Detection in an Anti-Resonant Hollow-Core Fiber
title_full Quartz-Enhanced Photothermal Spectroscopy-Based Methane Detection in an Anti-Resonant Hollow-Core Fiber
title_fullStr Quartz-Enhanced Photothermal Spectroscopy-Based Methane Detection in an Anti-Resonant Hollow-Core Fiber
title_full_unstemmed Quartz-Enhanced Photothermal Spectroscopy-Based Methane Detection in an Anti-Resonant Hollow-Core Fiber
title_short Quartz-Enhanced Photothermal Spectroscopy-Based Methane Detection in an Anti-Resonant Hollow-Core Fiber
title_sort quartz enhanced photothermal spectroscopy based methane detection in an anti resonant hollow core fiber
topic quartz-enhanced photothermal spectroscopy (QEPTS)
anti-resonant hollow-core fiber (ARHCF)
quartz tuning fork
url https://www.mdpi.com/1424-8220/22/15/5504
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