Phenol Derivatives as Co-Crystallized Templates to Modulate Trimesic-Acid-Based Hydrogen-Bonded Organic Molecular Frameworks
Five host−guest trimesic-acid-based hydrogen-bonds framework compounds with different guests, namely [(TMA)<sub>4</sub>·(TMB)<sub>3</sub>] (<b>1</b>), [(TMA)<sub>2</sub>·(DMB)<sub>1.5</sub>] (<b>2</b>), [(TMA)<sub>6</su...
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MDPI AG
2021-04-01
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| Series: | Crystals |
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| Online Access: | https://www.mdpi.com/2073-4352/11/4/409 |
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| author | Guangchuan Ou Qiong Wang Qiang Zhou Xiaofeng Wang |
| author_facet | Guangchuan Ou Qiong Wang Qiang Zhou Xiaofeng Wang |
| author_sort | Guangchuan Ou |
| collection | DOAJ |
| description | Five host−guest trimesic-acid-based hydrogen-bonds framework compounds with different guests, namely [(TMA)<sub>4</sub>·(TMB)<sub>3</sub>] (<b>1</b>), [(TMA)<sub>2</sub>·(DMB)<sub>1.5</sub>] (<b>2</b>), [(TMA)<sub>6</sub>·(MP)] (<b>3</b>), [(TMA)·(EP)] (<b>4</b>) and [(TMA)·(PP)] (<b>5</b>) (TMA = trimesic acid, TMB = 1,3,5-trimethoxybenzene, DMB = 1,4-dimethoxybenzene, MP = 4-methoxyphenol, EP = 4-ethoxyphenol and PP = 4-propoxyphenol), were obtained through co-crystallization, and were characterized by elemental analysis, infrared spectroscopy analysis, and thermogravimetric analysis. The trimesic acid molecules comprise a hydrogen bonding six-membered cyclic host network that is found in a two-dimensional arrangement in compounds <b>1</b> and <b>2</b>, and in a nine-fold interpenetrated three-dimensional structure in compound <b>3</b>. In compounds <b>4</b> and <b>5</b>, the trimesic acid and EP/PP molecules form a hydrogen-bonded six-membered cyclic network, resulting in a one-dimensional chain structure through O−H…O hydrogen bonds. |
| first_indexed | 2024-03-10T12:25:26Z |
| format | Article |
| id | doaj.art-c359ee4644b7468abccce5f777053714 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-10T12:25:26Z |
| publishDate | 2021-04-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-c359ee4644b7468abccce5f7770537142023-11-21T15:08:45ZengMDPI AGCrystals2073-43522021-04-0111440910.3390/cryst11040409Phenol Derivatives as Co-Crystallized Templates to Modulate Trimesic-Acid-Based Hydrogen-Bonded Organic Molecular FrameworksGuangchuan Ou0Qiong Wang1Qiang Zhou2Xiaofeng Wang3College of Chemistry and Bioengineering, Hunan University of Science and Engineering, Yongzhou 425199, Hunan, ChinaCollege of Chemistry and Bioengineering, Hunan University of Science and Engineering, Yongzhou 425199, Hunan, ChinaCollege of Chemistry and Bioengineering, Hunan University of Science and Engineering, Yongzhou 425199, Hunan, ChinaSchool of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, Hunan, ChinaFive host−guest trimesic-acid-based hydrogen-bonds framework compounds with different guests, namely [(TMA)<sub>4</sub>·(TMB)<sub>3</sub>] (<b>1</b>), [(TMA)<sub>2</sub>·(DMB)<sub>1.5</sub>] (<b>2</b>), [(TMA)<sub>6</sub>·(MP)] (<b>3</b>), [(TMA)·(EP)] (<b>4</b>) and [(TMA)·(PP)] (<b>5</b>) (TMA = trimesic acid, TMB = 1,3,5-trimethoxybenzene, DMB = 1,4-dimethoxybenzene, MP = 4-methoxyphenol, EP = 4-ethoxyphenol and PP = 4-propoxyphenol), were obtained through co-crystallization, and were characterized by elemental analysis, infrared spectroscopy analysis, and thermogravimetric analysis. The trimesic acid molecules comprise a hydrogen bonding six-membered cyclic host network that is found in a two-dimensional arrangement in compounds <b>1</b> and <b>2</b>, and in a nine-fold interpenetrated three-dimensional structure in compound <b>3</b>. In compounds <b>4</b> and <b>5</b>, the trimesic acid and EP/PP molecules form a hydrogen-bonded six-membered cyclic network, resulting in a one-dimensional chain structure through O−H…O hydrogen bonds.https://www.mdpi.com/2073-4352/11/4/409trimesic acidhydrogen bondingco-crystallization |
| spellingShingle | Guangchuan Ou Qiong Wang Qiang Zhou Xiaofeng Wang Phenol Derivatives as Co-Crystallized Templates to Modulate Trimesic-Acid-Based Hydrogen-Bonded Organic Molecular Frameworks Crystals trimesic acid hydrogen bonding co-crystallization |
| title | Phenol Derivatives as Co-Crystallized Templates to Modulate Trimesic-Acid-Based Hydrogen-Bonded Organic Molecular Frameworks |
| title_full | Phenol Derivatives as Co-Crystallized Templates to Modulate Trimesic-Acid-Based Hydrogen-Bonded Organic Molecular Frameworks |
| title_fullStr | Phenol Derivatives as Co-Crystallized Templates to Modulate Trimesic-Acid-Based Hydrogen-Bonded Organic Molecular Frameworks |
| title_full_unstemmed | Phenol Derivatives as Co-Crystallized Templates to Modulate Trimesic-Acid-Based Hydrogen-Bonded Organic Molecular Frameworks |
| title_short | Phenol Derivatives as Co-Crystallized Templates to Modulate Trimesic-Acid-Based Hydrogen-Bonded Organic Molecular Frameworks |
| title_sort | phenol derivatives as co crystallized templates to modulate trimesic acid based hydrogen bonded organic molecular frameworks |
| topic | trimesic acid hydrogen bonding co-crystallization |
| url | https://www.mdpi.com/2073-4352/11/4/409 |
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