Quantum Numbers and the Eigenfunction Approach to Obtain Symmetry Adapted Functions for Discrete Symmetries

The eigenfunction approach used for discrete symmetries is deduced from the concept of quantum numbers. We show that the irreducible representations (irreps) associated with the eigenfunctions are indeed a shorthand notation for the set of eigenvalues of the class operators (character table). The ne...

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Main Author: Renato Lemus
Format: Article
Language:English
Published: MDPI AG 2012-11-01
Series:Symmetry
Subjects:
Online Access:http://www.mdpi.com/2073-8994/4/4/667
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author Renato Lemus
author_facet Renato Lemus
author_sort Renato Lemus
collection DOAJ
description The eigenfunction approach used for discrete symmetries is deduced from the concept of quantum numbers. We show that the irreducible representations (irreps) associated with the eigenfunctions are indeed a shorthand notation for the set of eigenvalues of the class operators (character table). The need of a canonical chain of groups to establish a complete set of commuting operators is emphasized. This analysis allows us to establish in natural form the connection between the quantum numbers and the eigenfunction method proposed by J.Q. Chen to obtain symmetry adapted functions. We then proceed to present a friendly version of the eigenfunction method to project functions.
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spelling doaj.art-c3675a529329435dba8cdd241e74c9992022-12-22T02:55:14ZengMDPI AGSymmetry2073-89942012-11-014466768510.3390/sym4040667Quantum Numbers and the Eigenfunction Approach to Obtain Symmetry Adapted Functions for Discrete SymmetriesRenato LemusThe eigenfunction approach used for discrete symmetries is deduced from the concept of quantum numbers. We show that the irreducible representations (irreps) associated with the eigenfunctions are indeed a shorthand notation for the set of eigenvalues of the class operators (character table). The need of a canonical chain of groups to establish a complete set of commuting operators is emphasized. This analysis allows us to establish in natural form the connection between the quantum numbers and the eigenfunction method proposed by J.Q. Chen to obtain symmetry adapted functions. We then proceed to present a friendly version of the eigenfunction method to project functions.http://www.mdpi.com/2073-8994/4/4/667quantum numbersdiscrete systemssymmetry projectioneigenfunction methodH+3CH4
spellingShingle Renato Lemus
Quantum Numbers and the Eigenfunction Approach to Obtain Symmetry Adapted Functions for Discrete Symmetries
Symmetry
quantum numbers
discrete systems
symmetry projection
eigenfunction method
H+3
CH4
title Quantum Numbers and the Eigenfunction Approach to Obtain Symmetry Adapted Functions for Discrete Symmetries
title_full Quantum Numbers and the Eigenfunction Approach to Obtain Symmetry Adapted Functions for Discrete Symmetries
title_fullStr Quantum Numbers and the Eigenfunction Approach to Obtain Symmetry Adapted Functions for Discrete Symmetries
title_full_unstemmed Quantum Numbers and the Eigenfunction Approach to Obtain Symmetry Adapted Functions for Discrete Symmetries
title_short Quantum Numbers and the Eigenfunction Approach to Obtain Symmetry Adapted Functions for Discrete Symmetries
title_sort quantum numbers and the eigenfunction approach to obtain symmetry adapted functions for discrete symmetries
topic quantum numbers
discrete systems
symmetry projection
eigenfunction method
H+3
CH4
url http://www.mdpi.com/2073-8994/4/4/667
work_keys_str_mv AT renatolemus quantumnumbersandtheeigenfunctionapproachtoobtainsymmetryadaptedfunctionsfordiscretesymmetries