Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to Benzaldehyde
A novel Cu and boron doped graphitic carbon nitride catalyst (Cu-CNB) was synthesized using cheap precursors and systematically characterized. The selective oxidation of toluene proceeded very smoothly over the catalyst at 70 °C using tert-butyl hydroperoxide (TBHP) as the oxidant to exclusively aff...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2015-07-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/20/7/12686 |
| _version_ | 1818559900647686144 |
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| author | Hongling Han Guodong Ding Tianbin Wu Dexin Yang Tao Jiang Buxing Han |
| author_facet | Hongling Han Guodong Ding Tianbin Wu Dexin Yang Tao Jiang Buxing Han |
| author_sort | Hongling Han |
| collection | DOAJ |
| description | A novel Cu and boron doped graphitic carbon nitride catalyst (Cu-CNB) was synthesized using cheap precursors and systematically characterized. The selective oxidation of toluene proceeded very smoothly over the catalyst at 70 °C using tert-butyl hydroperoxide (TBHP) as the oxidant to exclusively afford benzaldehyde. The catalyst can be used for at least five cycles without decrease in activity and selectivity. |
| first_indexed | 2024-12-14T00:31:32Z |
| format | Article |
| id | doaj.art-c379576e85c24ce084a5771165217675 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-14T00:31:32Z |
| publishDate | 2015-07-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-c379576e85c24ce084a57711652176752022-12-21T23:24:49ZengMDPI AGMolecules1420-30492015-07-01207126861269710.3390/molecules200712686molecules200712686Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to BenzaldehydeHongling Han0Guodong Ding1Tianbin Wu2Dexin Yang3Tao Jiang4Buxing Han5Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, ChinaBeijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, ChinaBeijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, ChinaBeijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, ChinaBeijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, ChinaBeijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, ChinaA novel Cu and boron doped graphitic carbon nitride catalyst (Cu-CNB) was synthesized using cheap precursors and systematically characterized. The selective oxidation of toluene proceeded very smoothly over the catalyst at 70 °C using tert-butyl hydroperoxide (TBHP) as the oxidant to exclusively afford benzaldehyde. The catalyst can be used for at least five cycles without decrease in activity and selectivity.http://www.mdpi.com/1420-3049/20/7/12686tolueneselective oxidationgraphitic carbon nitridebenzaldehyde |
| spellingShingle | Hongling Han Guodong Ding Tianbin Wu Dexin Yang Tao Jiang Buxing Han Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to Benzaldehyde Molecules toluene selective oxidation graphitic carbon nitride benzaldehyde |
| title | Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to Benzaldehyde |
| title_full | Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to Benzaldehyde |
| title_fullStr | Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to Benzaldehyde |
| title_full_unstemmed | Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to Benzaldehyde |
| title_short | Cu and Boron Doped Carbon Nitride for Highly Selective Oxidation of Toluene to Benzaldehyde |
| title_sort | cu and boron doped carbon nitride for highly selective oxidation of toluene to benzaldehyde |
| topic | toluene selective oxidation graphitic carbon nitride benzaldehyde |
| url | http://www.mdpi.com/1420-3049/20/7/12686 |
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