(<i>E</i>)-1,1,1-Trifluoro-6,6-bis(4-methoxyphenyl)hexa-3,5-dien-2-one
The title compound was obtained in high yield (84%) via the deacetylation of 3-(3,3-bis(4-methoxyphenyl)allylidene)-1,1,1,5,5,5-hexafluoro-2,4-pentanedione with K<sub>2</sub>CO<sub>3</sub> in refluxing methanol. This previously unreported compound has been fully characterized...
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| Format: | Article |
| Language: | English |
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MDPI AG
2020-03-01
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| Series: | Molbank |
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| Online Access: | https://www.mdpi.com/1422-8599/2020/1/M1120 |
| _version_ | 1819099576562352128 |
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| author | Victorio Cadierno |
| author_facet | Victorio Cadierno |
| author_sort | Victorio Cadierno |
| collection | DOAJ |
| description | The title compound was obtained in high yield (84%) via the deacetylation of 3-(3,3-bis(4-methoxyphenyl)allylidene)-1,1,1,5,5,5-hexafluoro-2,4-pentanedione with K<sub>2</sub>CO<sub>3</sub> in refluxing methanol. This previously unreported compound has been fully characterized by <sup>19</sup>F{<sup>1</sup>H}, <sup>1</sup>H and <sup>13</sup>C{<sup>1</sup>H} NMR, IR, UV-Vis, and HRMS. |
| first_indexed | 2024-12-22T00:49:05Z |
| format | Article |
| id | doaj.art-c38371e9cf4f4ba7be7083ee0b9a6888 |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-12-22T00:49:05Z |
| publishDate | 2020-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-c38371e9cf4f4ba7be7083ee0b9a68882022-12-21T18:44:29ZengMDPI AGMolbank1422-85992020-03-0120201M112010.3390/M1120M1120(<i>E</i>)-1,1,1-Trifluoro-6,6-bis(4-methoxyphenyl)hexa-3,5-dien-2-oneVictorio Cadierno0Laboratorio de Compuestos Organometálicos y Catálisis (Unidad Asociada al CSIC), Departamento de Química Orgánica e Inorgánica, Facultad de Química, Universidad de Oviedo, Julián Clavería 8, E-33006 Oviedo, SpainThe title compound was obtained in high yield (84%) via the deacetylation of 3-(3,3-bis(4-methoxyphenyl)allylidene)-1,1,1,5,5,5-hexafluoro-2,4-pentanedione with K<sub>2</sub>CO<sub>3</sub> in refluxing methanol. This previously unreported compound has been fully characterized by <sup>19</sup>F{<sup>1</sup>H}, <sup>1</sup>H and <sup>13</sup>C{<sup>1</sup>H} NMR, IR, UV-Vis, and HRMS.https://www.mdpi.com/1422-8599/2020/1/M1120trifluoromethyl ketonesconjugated dienones1,3-butadienesdeacetylation reactions |
| spellingShingle | Victorio Cadierno (<i>E</i>)-1,1,1-Trifluoro-6,6-bis(4-methoxyphenyl)hexa-3,5-dien-2-one Molbank trifluoromethyl ketones conjugated dienones 1,3-butadienes deacetylation reactions |
| title | (<i>E</i>)-1,1,1-Trifluoro-6,6-bis(4-methoxyphenyl)hexa-3,5-dien-2-one |
| title_full | (<i>E</i>)-1,1,1-Trifluoro-6,6-bis(4-methoxyphenyl)hexa-3,5-dien-2-one |
| title_fullStr | (<i>E</i>)-1,1,1-Trifluoro-6,6-bis(4-methoxyphenyl)hexa-3,5-dien-2-one |
| title_full_unstemmed | (<i>E</i>)-1,1,1-Trifluoro-6,6-bis(4-methoxyphenyl)hexa-3,5-dien-2-one |
| title_short | (<i>E</i>)-1,1,1-Trifluoro-6,6-bis(4-methoxyphenyl)hexa-3,5-dien-2-one |
| title_sort | i e i 1 1 1 trifluoro 6 6 bis 4 methoxyphenyl hexa 3 5 dien 2 one |
| topic | trifluoromethyl ketones conjugated dienones 1,3-butadienes deacetylation reactions |
| url | https://www.mdpi.com/1422-8599/2020/1/M1120 |
| work_keys_str_mv | AT victoriocadierno iei111trifluoro66bis4methoxyphenylhexa35dien2one |