Effect of Sc on the microstructure and room-temperature mechanical properties of Nb-Si based alloys

The microstructure and room-temperature mechanical properties of directionally solidified and heat-treated Nb‑16Si‑23Ti‑4Cr‑2Al‑2Hf‑0/0.3/0.5Sc (at.%) alloys were investigated. All alloys consisted of Nb-based solid solution (Nbss), α‑Nb5Si3 and γ‑Nb5Si3 with preferred 〈001〉 orientation for the firs...

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Main Authors: Yonglin Huang, Lina Jia, Zuheng Jin, Bin Kong, Yueling Guo, Jiangbo Sha, Hu Zhang
Format: Article
Language:English
Published: Elsevier 2018-12-01
Series:Materials & Design
Online Access:http://www.sciencedirect.com/science/article/pii/S0264127518307561
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author Yonglin Huang
Lina Jia
Zuheng Jin
Bin Kong
Yueling Guo
Jiangbo Sha
Hu Zhang
author_facet Yonglin Huang
Lina Jia
Zuheng Jin
Bin Kong
Yueling Guo
Jiangbo Sha
Hu Zhang
author_sort Yonglin Huang
collection DOAJ
description The microstructure and room-temperature mechanical properties of directionally solidified and heat-treated Nb‑16Si‑23Ti‑4Cr‑2Al‑2Hf‑0/0.3/0.5Sc (at.%) alloys were investigated. All alloys consisted of Nb-based solid solution (Nbss), α‑Nb5Si3 and γ‑Nb5Si3 with preferred 〈001〉 orientation for the first two phases, and Sc was enriched in γ‑Nb5Si3 phase. Sc-added alloys showed a more continuous Nbss matrix in which the finer Nb5Si3 phase distributed uniformly. The volume fraction of both α‑Nb5Si3 and γ‑Nb5Si3 phase was decreased by Sc addition. Sc alloying reduced the Young's modulus and nano-hardness of Nbss phase. 0.50 at.% Sc addition enhanced the fracture toughness and tensile strength from 9.88 MPa m1/2 and 430.3 MPa to 25.95 MPa m1/2 and 1119.7 MPa. The improvement in fracture toughness was due to the better deformability of Nbss phase. The high tensile strength was attributed to the dispersed and refined Nb5Si3 phase, which was not degraded by the increased Nbss volume fraction since dislocations were not open within most Nbss phase. Besides, the strong interface cohesion was preferable for the strength of Sc-added alloys. Keywords: Microstructure, Growth orientation, Young's modulus, Nano-hardness, Fracture toughness, Tensile strength
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spelling doaj.art-c3920c638a6e4be5b74c57bf0d4a644f2022-12-21T18:47:09ZengElsevierMaterials & Design0264-12752018-12-01160671682Effect of Sc on the microstructure and room-temperature mechanical properties of Nb-Si based alloysYonglin Huang0Lina Jia1Zuheng Jin2Bin Kong3Yueling Guo4Jiangbo Sha5Hu Zhang6School of Materials Science and Engineering, Beihang University, Beijing 100191, ChinaCorresponding author.; School of Materials Science and Engineering, Beihang University, Beijing 100191, ChinaSchool of Materials Science and Engineering, Beihang University, Beijing 100191, ChinaSchool of Materials Science and Engineering, Beihang University, Beijing 100191, ChinaSchool of Materials Science and Engineering, Beihang University, Beijing 100191, ChinaSchool of Materials Science and Engineering, Beihang University, Beijing 100191, ChinaSchool of Materials Science and Engineering, Beihang University, Beijing 100191, ChinaThe microstructure and room-temperature mechanical properties of directionally solidified and heat-treated Nb‑16Si‑23Ti‑4Cr‑2Al‑2Hf‑0/0.3/0.5Sc (at.%) alloys were investigated. All alloys consisted of Nb-based solid solution (Nbss), α‑Nb5Si3 and γ‑Nb5Si3 with preferred 〈001〉 orientation for the first two phases, and Sc was enriched in γ‑Nb5Si3 phase. Sc-added alloys showed a more continuous Nbss matrix in which the finer Nb5Si3 phase distributed uniformly. The volume fraction of both α‑Nb5Si3 and γ‑Nb5Si3 phase was decreased by Sc addition. Sc alloying reduced the Young's modulus and nano-hardness of Nbss phase. 0.50 at.% Sc addition enhanced the fracture toughness and tensile strength from 9.88 MPa m1/2 and 430.3 MPa to 25.95 MPa m1/2 and 1119.7 MPa. The improvement in fracture toughness was due to the better deformability of Nbss phase. The high tensile strength was attributed to the dispersed and refined Nb5Si3 phase, which was not degraded by the increased Nbss volume fraction since dislocations were not open within most Nbss phase. Besides, the strong interface cohesion was preferable for the strength of Sc-added alloys. Keywords: Microstructure, Growth orientation, Young's modulus, Nano-hardness, Fracture toughness, Tensile strengthhttp://www.sciencedirect.com/science/article/pii/S0264127518307561
spellingShingle Yonglin Huang
Lina Jia
Zuheng Jin
Bin Kong
Yueling Guo
Jiangbo Sha
Hu Zhang
Effect of Sc on the microstructure and room-temperature mechanical properties of Nb-Si based alloys
Materials & Design
title Effect of Sc on the microstructure and room-temperature mechanical properties of Nb-Si based alloys
title_full Effect of Sc on the microstructure and room-temperature mechanical properties of Nb-Si based alloys
title_fullStr Effect of Sc on the microstructure and room-temperature mechanical properties of Nb-Si based alloys
title_full_unstemmed Effect of Sc on the microstructure and room-temperature mechanical properties of Nb-Si based alloys
title_short Effect of Sc on the microstructure and room-temperature mechanical properties of Nb-Si based alloys
title_sort effect of sc on the microstructure and room temperature mechanical properties of nb si based alloys
url http://www.sciencedirect.com/science/article/pii/S0264127518307561
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