N-(3-Chlorophenyl)benzamide
The conformation of the N—H bond in the structure of the title compound (N3CPBA), C13H10ClNO, is anti to the meta chloro substituent in the aniline benzene ring, similar to that observed with respect to the ortho chloro substituent in N-(2-chlorophenyl)benzamide (N2CPBA) and meta chloro su...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808001311 |
| _version_ | 1828138956759236608 |
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| author | Hartmut Fuess B. P. Sowmya Jozef Kožíšek Miroslav Tokarčík B. Thimme Gowda |
| author_facet | Hartmut Fuess B. P. Sowmya Jozef Kožíšek Miroslav Tokarčík B. Thimme Gowda |
| author_sort | Hartmut Fuess |
| collection | DOAJ |
| description | The conformation of the N—H bond in the structure of the title compound (N3CPBA), C13H10ClNO, is anti to the meta chloro substituent in the aniline benzene ring, similar to that observed with respect to the ortho chloro substituent in N-(2-chlorophenyl)benzamide (N2CPBA) and meta chloro substituent in N-(3,4-dichlorophenyl)benzamide (N34DCPBA), but in contrast to the syn conformation observed with respect to both the ortho and the meta chloro substituents in N-(2,3-dichlorophenyl)benzamide (N23DCPBA). The bond parameters in N3CPBA are similar to those in N-phenylbenzamide, N2CPBA, N23DCPBA, N34DCPBA and other benzanilides. The amide group –NHCO– makes a dihedral angle of 18.2 (2)° with the benzoyl ring, while the dihedral angle between the two benzene rings is 61.0 (1)°. The molecules are linked into chains along the b axis by N—H...O hydrogen bonds. |
| first_indexed | 2024-04-11T18:44:34Z |
| format | Article |
| id | doaj.art-c396017bb74146b488a5aaabb1bed87a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T18:44:34Z |
| publishDate | 2008-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c396017bb74146b488a5aaabb1bed87a2022-12-22T04:08:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642o462o46210.1107/S1600536808001311N-(3-Chlorophenyl)benzamideHartmut FuessB. P. SowmyaJozef KožíšekMiroslav TokarčíkB. Thimme GowdaThe conformation of the N—H bond in the structure of the title compound (N3CPBA), C13H10ClNO, is anti to the meta chloro substituent in the aniline benzene ring, similar to that observed with respect to the ortho chloro substituent in N-(2-chlorophenyl)benzamide (N2CPBA) and meta chloro substituent in N-(3,4-dichlorophenyl)benzamide (N34DCPBA), but in contrast to the syn conformation observed with respect to both the ortho and the meta chloro substituents in N-(2,3-dichlorophenyl)benzamide (N23DCPBA). The bond parameters in N3CPBA are similar to those in N-phenylbenzamide, N2CPBA, N23DCPBA, N34DCPBA and other benzanilides. The amide group –NHCO– makes a dihedral angle of 18.2 (2)° with the benzoyl ring, while the dihedral angle between the two benzene rings is 61.0 (1)°. The molecules are linked into chains along the b axis by N—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536808001311 |
| spellingShingle | Hartmut Fuess B. P. Sowmya Jozef Kožíšek Miroslav Tokarčík B. Thimme Gowda N-(3-Chlorophenyl)benzamide Acta Crystallographica Section E |
| title | N-(3-Chlorophenyl)benzamide |
| title_full | N-(3-Chlorophenyl)benzamide |
| title_fullStr | N-(3-Chlorophenyl)benzamide |
| title_full_unstemmed | N-(3-Chlorophenyl)benzamide |
| title_short | N-(3-Chlorophenyl)benzamide |
| title_sort | n 3 chlorophenyl benzamide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808001311 |
| work_keys_str_mv | AT hartmutfuess n3chlorophenylbenzamide AT bpsowmya n3chlorophenylbenzamide AT jozefko382237353ek n3chlorophenylbenzamide AT miroslavtokar269237k n3chlorophenylbenzamide AT bthimmegowda n3chlorophenylbenzamide |