Crystal and molecular structure of cis-Dichlorobis(triphenylphosphite) Platinum(II)
The single crystal structure of cis-dichlorobis(triphenyphosphite) platinum(II), [PtCl2(P(OPh)3)2] has been determined. This complex crystallises in the orthorhombic space group, P212121 with cell constant, a=10.4135(13), b=14.0635(16), c=23.505(3) Ǻ and v=3448.3(7) Ǻ 3. The Pt-Cl1 and Pt-Cl2...
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MDPI AG
2001-08-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/6/9/777/ |
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| author | Ali Naghipour Seyyed Javad Sabounchei |
| author_facet | Ali Naghipour Seyyed Javad Sabounchei |
| author_sort | Ali Naghipour |
| collection | DOAJ |
| description | The single crystal structure of cis-dichlorobis(triphenyphosphite) platinum(II), [PtCl2(P(OPh)3)2] has been determined. This complex crystallises in the orthorhombic space group, P212121 with cell constant, a=10.4135(13), b=14.0635(16), c=23.505(3) Ǻ and v=3448.3(7) Ǻ 3. The Pt-Cl1 and Pt-Cl2 distances are 2.3390(10) Ǻ and 2.3256 Ǻ, which are longer than Pt-P1 and Pt-P2 with 2.1985(12) Ǻ and 2.1998(10) Ǻ respectively. These data together with bond angles suggest a distorted square planar geometry for this complex with two chlorine ligands in a cis configuration. |
| first_indexed | 2024-12-20T12:27:11Z |
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| id | doaj.art-c3afa40e3f964d83b2b039e464c5c5bc |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-20T12:27:11Z |
| publishDate | 2001-08-01 |
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| series | Molecules |
| spelling | doaj.art-c3afa40e3f964d83b2b039e464c5c5bc2022-12-21T19:40:51ZengMDPI AGMolecules1420-30492001-08-016977778310.3390/60900777Crystal and molecular structure of cis-Dichlorobis(triphenylphosphite) Platinum(II)Ali NaghipourSeyyed Javad SabouncheiThe single crystal structure of cis-dichlorobis(triphenyphosphite) platinum(II), [PtCl2(P(OPh)3)2] has been determined. This complex crystallises in the orthorhombic space group, P212121 with cell constant, a=10.4135(13), b=14.0635(16), c=23.505(3) Ǻ and v=3448.3(7) Ǻ 3. The Pt-Cl1 and Pt-Cl2 distances are 2.3390(10) Ǻ and 2.3256 Ǻ, which are longer than Pt-P1 and Pt-P2 with 2.1985(12) Ǻ and 2.1998(10) Ǻ respectively. These data together with bond angles suggest a distorted square planar geometry for this complex with two chlorine ligands in a cis configuration.http://www.mdpi.com/1420-3049/6/9/777/Crystal structureMolecular structureTriphenylphosphite ligandsPlatinum complex |
| spellingShingle | Ali Naghipour Seyyed Javad Sabounchei Crystal and molecular structure of cis-Dichlorobis(triphenylphosphite) Platinum(II) Molecules Crystal structure Molecular structure Triphenylphosphite ligands Platinum complex |
| title | Crystal and molecular structure of cis-Dichlorobis(triphenylphosphite) Platinum(II) |
| title_full | Crystal and molecular structure of cis-Dichlorobis(triphenylphosphite) Platinum(II) |
| title_fullStr | Crystal and molecular structure of cis-Dichlorobis(triphenylphosphite) Platinum(II) |
| title_full_unstemmed | Crystal and molecular structure of cis-Dichlorobis(triphenylphosphite) Platinum(II) |
| title_short | Crystal and molecular structure of cis-Dichlorobis(triphenylphosphite) Platinum(II) |
| title_sort | crystal and molecular structure of cis dichlorobis triphenylphosphite platinum ii |
| topic | Crystal structure Molecular structure Triphenylphosphite ligands Platinum complex |
| url | http://www.mdpi.com/1420-3049/6/9/777/ |
| work_keys_str_mv | AT alinaghipour crystalandmolecularstructureofcisdichlorobistriphenylphosphiteplatinumii AT seyyedjavadsabounchei crystalandmolecularstructureofcisdichlorobistriphenylphosphiteplatinumii |