Impact of different Cr contents on microstructural evolution and mechanical behaviour of CoCrxCuFeMnNiV high-entropy alloys

The CoCrxCuFeMnNiV (x = 0, 0.25, 0.5, 0.75, 1) high-entropy alloy was prepared via vacuum arc smelting, and the effect of different Cr contents on the microstructure evolution and mechanical properties of it was evaluated. The results show that the CoCuFeMnNiV alloy is composed of FCC1+FCC2 phases,...

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Main Authors: Wen He, Cong Zeng, Wei Yang, Weihua Chen, Yunlong Ai
Format: Article
Language:English
Published: Elsevier 2022-11-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785422017744
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author Wen He
Cong Zeng
Wei Yang
Weihua Chen
Yunlong Ai
author_facet Wen He
Cong Zeng
Wei Yang
Weihua Chen
Yunlong Ai
author_sort Wen He
collection DOAJ
description The CoCrxCuFeMnNiV (x = 0, 0.25, 0.5, 0.75, 1) high-entropy alloy was prepared via vacuum arc smelting, and the effect of different Cr contents on the microstructure evolution and mechanical properties of it was evaluated. The results show that the CoCuFeMnNiV alloy is composed of FCC1+FCC2 phases, while Cr-added CoCrxCuFeMnNiV alloy is composed of FCC1+FCC2+sigma phases; moreover, the amount of sigma phase increases with the Cr content. Through calculations, a phase formation criterion suitable for the CoCrxCuFeMnNiV alloy was established. It was observed that adding Cr does not affect the early solidification behaviour of the FCC1 and FCC2 phases; however, it affects the stability of the FCC1 phase and promotes the transformation of this phase into the sigma phase, as well as secondary precipitation of a nanoscale copper-rich phase on this phase. The formation of sigma phase has a significant strengthening effect on the alloy but reduces its plasticity. The CoCr0.5CuFeMnNiV alloy has favourable comprehensive properties; specifically, its yield strength, compressive strength, microhardness, and fracture strain are 820 MPa, 1050 MPa, 320 HV, and 22.5%, respectively. With an increase in Cr content, the alloy fracture mode changes from ductile to brittle.
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spelling doaj.art-c3b886e1b21646a8a318edbac194ab382022-12-22T04:23:15ZengElsevierJournal of Materials Research and Technology2238-78542022-11-012145774590Impact of different Cr contents on microstructural evolution and mechanical behaviour of CoCrxCuFeMnNiV high-entropy alloysWen He0Cong Zeng1Wei Yang2Weihua Chen3Yunlong Ai4School of Materials Science and Engineering, Nanchang Hangkong University, No. 696, Fenghenan Road, Nanchang, Jiangxi, 330063, China; Analysis and Testing Center, Nanchang Hangkong University, No. 696, Fenghenan Road, Nanchang, Jiangxi, 330063, China; Corresponding author.School of Materials Science and Engineering, Nanchang Hangkong University, No. 696, Fenghenan Road, Nanchang, Jiangxi, 330063, China; Aero-Engine Components Manufacturing Limited Company of Zhuzhou, No. 1018. Hangfei Avenue, Zhuzhou, Hunan, 412002, ChinaNational Defence Key Discipline Laboratory of Light Alloy Processing Science and Technology, Nangchang Hangkong University, No. 696, Fenghenan Road, Nanchang, Jiangxi, 330063, ChinaSchool of Materials Science and Engineering, Nanchang Hangkong University, No. 696, Fenghenan Road, Nanchang, Jiangxi, 330063, ChinaSchool of Materials Science and Engineering, Nanchang Hangkong University, No. 696, Fenghenan Road, Nanchang, Jiangxi, 330063, ChinaThe CoCrxCuFeMnNiV (x = 0, 0.25, 0.5, 0.75, 1) high-entropy alloy was prepared via vacuum arc smelting, and the effect of different Cr contents on the microstructure evolution and mechanical properties of it was evaluated. The results show that the CoCuFeMnNiV alloy is composed of FCC1+FCC2 phases, while Cr-added CoCrxCuFeMnNiV alloy is composed of FCC1+FCC2+sigma phases; moreover, the amount of sigma phase increases with the Cr content. Through calculations, a phase formation criterion suitable for the CoCrxCuFeMnNiV alloy was established. It was observed that adding Cr does not affect the early solidification behaviour of the FCC1 and FCC2 phases; however, it affects the stability of the FCC1 phase and promotes the transformation of this phase into the sigma phase, as well as secondary precipitation of a nanoscale copper-rich phase on this phase. The formation of sigma phase has a significant strengthening effect on the alloy but reduces its plasticity. The CoCr0.5CuFeMnNiV alloy has favourable comprehensive properties; specifically, its yield strength, compressive strength, microhardness, and fracture strain are 820 MPa, 1050 MPa, 320 HV, and 22.5%, respectively. With an increase in Cr content, the alloy fracture mode changes from ductile to brittle.http://www.sciencedirect.com/science/article/pii/S2238785422017744CoCrxCuFeMnNiV high-entropy alloyCr contentSigma phaseMicrostructure evolutionMechanical properties
spellingShingle Wen He
Cong Zeng
Wei Yang
Weihua Chen
Yunlong Ai
Impact of different Cr contents on microstructural evolution and mechanical behaviour of CoCrxCuFeMnNiV high-entropy alloys
Journal of Materials Research and Technology
CoCrxCuFeMnNiV high-entropy alloy
Cr content
Sigma phase
Microstructure evolution
Mechanical properties
title Impact of different Cr contents on microstructural evolution and mechanical behaviour of CoCrxCuFeMnNiV high-entropy alloys
title_full Impact of different Cr contents on microstructural evolution and mechanical behaviour of CoCrxCuFeMnNiV high-entropy alloys
title_fullStr Impact of different Cr contents on microstructural evolution and mechanical behaviour of CoCrxCuFeMnNiV high-entropy alloys
title_full_unstemmed Impact of different Cr contents on microstructural evolution and mechanical behaviour of CoCrxCuFeMnNiV high-entropy alloys
title_short Impact of different Cr contents on microstructural evolution and mechanical behaviour of CoCrxCuFeMnNiV high-entropy alloys
title_sort impact of different cr contents on microstructural evolution and mechanical behaviour of cocrxcufemnniv high entropy alloys
topic CoCrxCuFeMnNiV high-entropy alloy
Cr content
Sigma phase
Microstructure evolution
Mechanical properties
url http://www.sciencedirect.com/science/article/pii/S2238785422017744
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