Strain Engineering of Intrinsic Ferromagnetism in 2D van der Waals Materials

Since the discovery of the low-temperature, long-range ferromagnetic order in monolayers Cr<sub>2</sub>Ge<sub>2</sub>Te<sub>6</sub> and CrI<sub>3</sub>, many efforts have been made to achieve a room temperature (RT) ferromagnet. The outstanding deforma...

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Main Authors: Hongtao Ren, Gang Xiang
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/13/16/2378
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author Hongtao Ren
Gang Xiang
author_facet Hongtao Ren
Gang Xiang
author_sort Hongtao Ren
collection DOAJ
description Since the discovery of the low-temperature, long-range ferromagnetic order in monolayers Cr<sub>2</sub>Ge<sub>2</sub>Te<sub>6</sub> and CrI<sub>3</sub>, many efforts have been made to achieve a room temperature (RT) ferromagnet. The outstanding deformation ability of two-dimensional (2D) materials provides an exciting way to mediate their intrinsic ferromagnetism (FM) with strain engineering. Here, we summarize the recent progress of strain engineering of intrinsic FM in 2D van der Waals materials. First, we introduce how to explain the strain-mediated intrinsic FM on Cr-based and Fe-based 2D van der Waals materials through ab initio Density functional theory (DFT), and how to calculate magnetic anisotropy energy (MAE) and Curie temperature (<i>T<sub>C</sub></i>) from the interlayer exchange coupling J. Subsequently, we focus on numerous attempts to apply strain to 2D materials in experiments, including wrinkle-induced strain, flexible substrate bending or stretching, lattice mismatch, electrostatic force and field-cooling. Last, we emphasize that this field is still in early stages, and there are many challenges that need to be overcome. More importantly, strengthening the guideline of strain-mediated FM in 2D van der Waals materials will promote the development of spintronics and straintronics.
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spelling doaj.art-c3c51c8ebe4040a6a1d6b31b96d55b162023-11-19T02:28:17ZengMDPI AGNanomaterials2079-49912023-08-011316237810.3390/nano13162378Strain Engineering of Intrinsic Ferromagnetism in 2D van der Waals MaterialsHongtao Ren0Gang Xiang1School of Materials Science and Engineering, Liaocheng University, Hunan Road No. 1, Liaocheng 252000, ChinaCollege of Physics, Sichuan University, Wangjiang Road No. 29, Chengdu 610064, ChinaSince the discovery of the low-temperature, long-range ferromagnetic order in monolayers Cr<sub>2</sub>Ge<sub>2</sub>Te<sub>6</sub> and CrI<sub>3</sub>, many efforts have been made to achieve a room temperature (RT) ferromagnet. The outstanding deformation ability of two-dimensional (2D) materials provides an exciting way to mediate their intrinsic ferromagnetism (FM) with strain engineering. Here, we summarize the recent progress of strain engineering of intrinsic FM in 2D van der Waals materials. First, we introduce how to explain the strain-mediated intrinsic FM on Cr-based and Fe-based 2D van der Waals materials through ab initio Density functional theory (DFT), and how to calculate magnetic anisotropy energy (MAE) and Curie temperature (<i>T<sub>C</sub></i>) from the interlayer exchange coupling J. Subsequently, we focus on numerous attempts to apply strain to 2D materials in experiments, including wrinkle-induced strain, flexible substrate bending or stretching, lattice mismatch, electrostatic force and field-cooling. Last, we emphasize that this field is still in early stages, and there are many challenges that need to be overcome. More importantly, strengthening the guideline of strain-mediated FM in 2D van der Waals materials will promote the development of spintronics and straintronics.https://www.mdpi.com/2079-4991/13/16/2378strain engineeringferromagnetismtransition metal trihalidestransition metal chalcogenidestransition metal phosphorous chalcogenideswrinkle
spellingShingle Hongtao Ren
Gang Xiang
Strain Engineering of Intrinsic Ferromagnetism in 2D van der Waals Materials
Nanomaterials
strain engineering
ferromagnetism
transition metal trihalides
transition metal chalcogenides
transition metal phosphorous chalcogenides
wrinkle
title Strain Engineering of Intrinsic Ferromagnetism in 2D van der Waals Materials
title_full Strain Engineering of Intrinsic Ferromagnetism in 2D van der Waals Materials
title_fullStr Strain Engineering of Intrinsic Ferromagnetism in 2D van der Waals Materials
title_full_unstemmed Strain Engineering of Intrinsic Ferromagnetism in 2D van der Waals Materials
title_short Strain Engineering of Intrinsic Ferromagnetism in 2D van der Waals Materials
title_sort strain engineering of intrinsic ferromagnetism in 2d van der waals materials
topic strain engineering
ferromagnetism
transition metal trihalides
transition metal chalcogenides
transition metal phosphorous chalcogenides
wrinkle
url https://www.mdpi.com/2079-4991/13/16/2378
work_keys_str_mv AT hongtaoren strainengineeringofintrinsicferromagnetismin2dvanderwaalsmaterials
AT gangxiang strainengineeringofintrinsicferromagnetismin2dvanderwaalsmaterials