3β-Acetoxy-5α-cholestan-6-one 2-cyanoacetylhydrazone
The asymmetric unit of the title compound, C32H51N3O3, consists of two crystallographically independent molecules, A and B; the 2-methylpentane group of molecule A and the propane group of molecule B are each disordered over two sets of sites, with refined site-occupancies of 0.825 (5)...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812001432 |
| _version_ | 1818500185707249664 |
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| author | Samina Khan Yusufzai Hasnah Osman Othman Sulaiman Suhana Arshad Ibrahim Abdul Razak |
| author_facet | Samina Khan Yusufzai Hasnah Osman Othman Sulaiman Suhana Arshad Ibrahim Abdul Razak |
| author_sort | Samina Khan Yusufzai |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, C32H51N3O3, consists of two crystallographically independent molecules, A and B; the 2-methylpentane group of molecule A and the propane group of molecule B are each disordered over two sets of sites, with refined site-occupancies of 0.825 (5):0.175 (5) and 0.630 (18):0.370 (18), respectively. In both molecules, the three cyclohexane rings in the steroid fused ring systems adopt chair conformations while the cyclopentane rings adopt envelope and twist conformations in molecules A and B, respectively. In the crystal, N—H...O and C—H...O hydrogen bonds link the two independent molecules together, generating R21(7) and R22(8) ring motifs. |
| first_indexed | 2024-12-10T20:39:25Z |
| format | Article |
| id | doaj.art-c3cdf82086a447069e2567094f63171c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T20:39:25Z |
| publishDate | 2012-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-c3cdf82086a447069e2567094f63171c2022-12-22T01:34:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682o473o47410.1107/S16005368120014323β-Acetoxy-5α-cholestan-6-one 2-cyanoacetylhydrazoneSamina Khan YusufzaiHasnah OsmanOthman SulaimanSuhana ArshadIbrahim Abdul RazakThe asymmetric unit of the title compound, C32H51N3O3, consists of two crystallographically independent molecules, A and B; the 2-methylpentane group of molecule A and the propane group of molecule B are each disordered over two sets of sites, with refined site-occupancies of 0.825 (5):0.175 (5) and 0.630 (18):0.370 (18), respectively. In both molecules, the three cyclohexane rings in the steroid fused ring systems adopt chair conformations while the cyclopentane rings adopt envelope and twist conformations in molecules A and B, respectively. In the crystal, N—H...O and C—H...O hydrogen bonds link the two independent molecules together, generating R21(7) and R22(8) ring motifs.http://scripts.iucr.org/cgi-bin/paper?S1600536812001432 |
| spellingShingle | Samina Khan Yusufzai Hasnah Osman Othman Sulaiman Suhana Arshad Ibrahim Abdul Razak 3β-Acetoxy-5α-cholestan-6-one 2-cyanoacetylhydrazone Acta Crystallographica Section E |
| title | 3β-Acetoxy-5α-cholestan-6-one 2-cyanoacetylhydrazone |
| title_full | 3β-Acetoxy-5α-cholestan-6-one 2-cyanoacetylhydrazone |
| title_fullStr | 3β-Acetoxy-5α-cholestan-6-one 2-cyanoacetylhydrazone |
| title_full_unstemmed | 3β-Acetoxy-5α-cholestan-6-one 2-cyanoacetylhydrazone |
| title_short | 3β-Acetoxy-5α-cholestan-6-one 2-cyanoacetylhydrazone |
| title_sort | 3 amp 946 acetoxy 5 amp 945 cholestan 6 one 2 cyanoacetylhydrazone |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812001432 |
| work_keys_str_mv | AT saminakhanyusufzai 3amp946acetoxy5amp945cholestan6one2cyanoacetylhydrazone AT hasnahosman 3amp946acetoxy5amp945cholestan6one2cyanoacetylhydrazone AT othmansulaiman 3amp946acetoxy5amp945cholestan6one2cyanoacetylhydrazone AT suhanaarshad 3amp946acetoxy5amp945cholestan6one2cyanoacetylhydrazone AT ibrahimabdulrazak 3amp946acetoxy5amp945cholestan6one2cyanoacetylhydrazone |